Specific hydrogenated block copolymer composition and process for producing the same
申请人:Asahi Kasei Kogyo Kabushiki Kaisha
公开号:EP0299499A2
公开(公告)日:1989-01-18
A composition comprising,
(a) 1 to 99 parts by weight of a specific hydrogenated product of a block copolymer having at least one polymer block composed mainly of a vinyl aromatic compound and at least one polymer block composed mainly of a conjugated diene compound, a modified product which comprises said product modified with an α,8-unsaturated carboxylic acid or a derivative thereof, or a mixture of said product and said modified product, wherein the content of the vinyl aromatic compound prior to hydrogenation is 5 to 95 % by weight and a content of vinyl linkages [V] prior to hydrogenation which originated from the conjugated diene compound is 10 to 80 %, said product satisfying the following conditions;
(1) the hydrogenated ratio [A] of the total of aliphatic double bonds which originated from the conjugated diene compound is not lower than 5 % and lower than 50 %, and
(2) [B]/[V]1/2 = 3 to 20,
wherein [B] is the hydrogenated ratio of the vinyl linkage portions which originated from the conjugated diene compound, and
(b) 99 to 1 parts by weight of at least one thermoplastic substance selected from the group consisting of tackifier resins, thermoplastic resins and bituminous materials, and a process for producing the same.
一种组合物,包括
(a) 1 至 99 份(重量)嵌段共聚物的特定氢化产物,该嵌段共聚物至少有一 个主要由乙烯基芳香族化合物组成的聚合物嵌段和至少有一个主要由共轭二 烯化合物组成的聚合物嵌段;改性产物,该改性产物包括用α,8-不饱和羧酸 或其衍生物改性的上述产物、或上述产品和上述改性产品的混合物,其中氢化前乙烯基芳香族化合物的含量为 5% 至 95%(重量百分比),氢化前源自共轭二烯化合物的乙烯基链节[V]的含量为 10% 至 80%,上述产品满足以下条件;
(1) 源自共轭二烯化合物的脂肪族双键总数的氢化比率[A]不低于 5%,也不低于 50%,以及
(2) [B]/[V]1/2 = 3 至 20、
其中[B]是源自共轭二烯化合物的乙烯基连接部分的氢化比率,以及
(b) 至少一种热塑性物质,其重量占 99 至 1 份,该热塑性物质选自增粘剂树脂、 热塑性树脂和沥青材料组成的组,以及生产该热塑性物质的工艺。