6-chloro-N²,N⁴-didecyl-1,3,5-triazine-2,4-diamine | 1392400-99-5

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 三嗪类
• 英文名称: 6-chloro-N²,N⁴-didecyl-1,3,5-triazine-2,4-diamine
• 英文别名: 6-chloro-N,N'-didecyl-1,3,5-triazine-2,4-diamine；6-chloro-2-N,4-N-didecyl-1,3,5-triazine-2,4-diamine
• CAS: 1392400-99-5
• 化学式: C₂₃H₄₄ClN₅
• 分子量: 426.089
• InChiKey: JULXRGYRXVTOHS-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  10.6
• 重原子数：
  29
• 可旋转键数：
  20
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.87
• 拓扑面积：
  62.7
• 氢给体数：
  2
• 氢受体数：
  5

反应信息

• 作为反应物：
  描述：

  6-chloro-N²,N⁴-didecyl-1,3,5-triazine-2,4-diamine 在 ammonium hydroxide 作用下， 以 1,4-二氧六环 、 水 为溶剂， 反应 24.0h， 以66%的产率得到N²,N⁴-didecyl-1,3,5-triazine-2,4,6-triamine
  参考文献：
  名称：

  Non-covalently dendronized flavins as organocatalysts for aerobic reduction of olefins

  摘要：

  A variety of association complexes of synthetic flavin with diaminopyridine and melamine receptors are described in terms of synthesis, association properties, and catalytic activities for aerobic hydrogenation of olefins. The 1:1 association complex of lumiflavin 1 with 2,6-bis(acylamino)pyridine receptor bearing 3,4,5-trialkoxybenzyl ether dendron unit 2 acts as an efficient supramolecular organocatalyst for the aerobic reduction of styrene at ambient temperature under atmospheric air pressure. (C) 2013 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tet.2013.07.082
• 作为产物：
  描述：

  三聚氯氰 、 1-氨基癸烷 以 四氢呋喃 为溶剂， 反应 16.0h， 以75%的产率得到6-chloro-N²,N⁴-didecyl-1,3,5-triazine-2,4-diamine
  参考文献：
  名称：

  Triazine derivatives as organic phase change materials with inherently low flammability

  摘要：

  一系列基于三嗪的化合物（M1-M7）已从1,3,5-三嗪、2,4,6-三氨基-1,3,5-三嗪、2,4-二氯-6-甲氧基-1,3,5-三嗪和2-氯-4,6-二甲氧基-1,3,5-三嗪制备，并研究了它们的热相变性质。

  DOI：

  10.1039/d1ta07422a

文献信息

• Non-covalently dendronized flavins as organocatalysts for aerobic reduction of olefins
  作者：Yasushi Imada、Yudai Kugimiya、Shotaro Iwata、Naruyoshi Komiya、Takeshi Naota

  DOI：10.1016/j.tet.2013.07.082

  日期：2013.10

  A variety of association complexes of synthetic flavin with diaminopyridine and melamine receptors are described in terms of synthesis, association properties, and catalytic activities for aerobic hydrogenation of olefins. The 1:1 association complex of lumiflavin 1 with 2,6-bis(acylamino)pyridine receptor bearing 3,4,5-trialkoxybenzyl ether dendron unit 2 acts as an efficient supramolecular organocatalyst for the aerobic reduction of styrene at ambient temperature under atmospheric air pressure. (C) 2013 Elsevier Ltd. All rights reserved.
• Triazine derivatives as organic phase change materials with inherently low flammability
  作者：Zhuang Mao Png、Xiang Yun Debbie Soo、Ming Hui Chua、Pin Jin Ong、Jianwei Xu、Qiang Zhu

  DOI：10.1039/d1ta07422a

  日期：——

  A series of triazine-based compounds (M1–M7) have been prepared from 1,3,5-triazine, 2,4,6-triamino-1,3,5-triazine, 2,4-dichloro-6-methoxy-1,3,5-triazine and 2-chloro-4,6-dimethoxy-1,3,5-triazine, and their thermal phase change properties.

  一系列基于三嗪的化合物（M1-M7）已从1,3,5-三嗪、2,4,6-三氨基-1,3,5-三嗪、2,4-二氯-6-甲氧基-1,3,5-三嗪和2-氯-4,6-二甲氧基-1,3,5-三嗪制备，并研究了它们的热相变性质。