3-[4-(9-phenanthryl)-phenyl]-9-phenyl-9H-carbazole | 1369431-19-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: 3-[4-(9-phenanthryl)-phenyl]-9-phenyl-9H-carbazole
• 英文别名: 3-(4-phenanthren-9-ylphenyl)-9-phenylcarbazole
• CAS: 1369431-19-5
• 化学式: C₃₈H₂₅N
• 分子量: 495.623
• InChiKey: WQRYZOAFWABMBD-UHFFFAOYSA-N

物化性质

• 沸点：
  725.7±58.0 °C(Predicted)
• 密度：
  1.16±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  10.7
• 重原子数：
  39
• 可旋转键数：
  3
• 环数：
  8.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  4.9
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  N-苯基-3-咔唑硼酸 在 palladium diacetate 、 三(邻甲基苯基)磷 potassium carbonate 作用下， 以 四氢呋喃 、 乙醇 、 水 、 甲苯 为溶剂， 反应 39.0h， 生成 3-[4-(9-phenanthryl)-phenyl]-9-phenyl-9H-carbazole
  参考文献：
  名称：

  ORGANIC COMPOUND, LIGHT-EMITTING ELEMENT, LIGHT-EMITTING DEVICE, ELECTRONIC DEVICE, AND LIGHTING DEVICE

  摘要：

  提供一种新型物质，可以实现发光元件寿命和发射效率的提高。提供一种具有通用式（G1）表示的结构的咔唑化合物。请注意，在通用式（G1）中，使取代基的HOMO能级和LUMO能级分别变深和变浅的取代基被用作每个取代基（R1、R2、Ar3和α3）。此外，在通用式（G1)中，使取代基的带隙（Bg）和T1能级分别变宽和变高的取代基被用作每个取代基（R1、R2、Ar3和α3）。

  公开号：

  US20120077987A1

文献信息

• [EN] ORGANIC COMPOUND, LIGHT-EMITTING ELEMENT, LIGHT-EMITTING DEVICE, ELECTRONIC DEVICE, AND LIGHTING DEVICE<br/>[FR] COMPOSÉ ORGANIQUE, ÉLÉMENT ÉLECTROLUMINESCENT, DISPOSITIF ÉLECTROLUMINESCENT, DISPOSITIF ÉLECTRONIQUE ET DISPOSITIF D'ÉCLAIRAGE
  申请人：SEMICONDUCTOR ENERGY LAB

  公开号：WO2018167606A1

  公开（公告）日：2018-09-20

  A novel organic compound is provided. That is, a novel organic compound that is effective in improving reliability of a light-emitting element is provided. The organic compound includes a condensed ring including a pyrimidine ring and is represented by General Formula (G1). In General Formula (G1), A represents a group having 6 to 100 carbon atoms and includes at least one of an aromatic ring and a heteroaromatic ring. The aromatic ring and the heteroaromatic ring may each include a substituent. Furthermore, Q represents oxygen or sulfur. A ring X represents a substituted or unsubstituted naphthalene ring or a substituted or unsubstituted phenanthrene ring.

  提供了一种新的有机化合物。也就是说，提供了一种能够提高发光元件可靠性的新型有机化合物。该有机化合物包括一个包含嘧啶环的缩合环，并由通用式（G1）表示。在通用式（G1）中，A代表含有6至100个碳原子的基团，并且至少包括一个芳香环和一个杂芳环中的一个。芳香环和杂芳环中每个都可以包括一个取代基。此外，Q代表氧或硫。环X代表取代或未取代的萘环或取代或未取代的菲环。
• [EN] LIGHT-EMITTING DEVICE, LIGHT-EMITTING APPARATUS, ELECTRONIC DEVICE, AND LIGHTING DEVICE<br/>[FR] ÉLÉMENT ÉLECTROLUMINESCENT, APPAREIL ÉLECTROLUMINESCENT, DISPOSITIF ÉLECTRONIQUE ET DISPOSITIF D'ÉCLAIRAGE
  申请人：SEMICONDUCTOR ENERGY LAB

  公开号：WO2020053689A1

  公开（公告）日：2020-03-19

  To provide a light-emitting device not only including a light-emitting layer in which energy is efficiently transferred from a host material to a guest material but also having high reliability. The light-emitting device not only includes a light-emitting layer in which the T1 levels and the S1 levels of a host material and a guest material fall within certain ranges so that energy can be efficiently transferred from the host material to the guest material and but also has improved reliability.

  为了提供一种发光装置，不仅包括一个发光层，其中能量从主体材料有效地转移到客体材料，而且具有很高的可靠性。这种发光装置不仅包括一个发光层，其中主体材料和客体材料的T1能级和S1能级落在一定范围内，以便能量可以有效地从主体材料转移到客体材料，而且还具有改善的可靠性。
• Benzotriphenylene Compound, Light-Emitting Element, Light-Emitting Device, Electronic Device, and Lighting Device
  申请人：Semiconductor Energy Laboratory Co., Ltd.

  公开号：US20170062735A1

  公开（公告）日：2017-03-02

  A novel benzotriphenylene compound that can be suitably used as a host material in the case where a light-emitting substance is a fluorescent material. The benzotriphenylene compound is represented by General Formula (G1-1). In General Formula (G1-1), A represents a condensed ring. Each of R 1 to R 9 and R 11 to R 14 independently represents any of hydrogen, an alkyl group having 1 to 6 carbon atoms, a cycloalkyl group having 3 to 6 carbon atoms, and a substituted or unsubstituted aryl group having 6 to 13 carbon atoms. Ar represents an arylene group having 6 to 13 carbon atoms.

  一种新型苯并三苯基化合物，可适当用作发光物质为荧光物质的主体材料。该苯并三苯基化合物由通用式（G1-1）表示。在通用式（G1-1）中，A代表一个融合环。R1至R9和R11至R14中的每一个独立地代表氢、具有1至6个碳原子的烷基基团、具有3至6个碳原子的环烷基基团，以及具有6至13个碳原子的取代或未取代芳基团中的任何一种。Ar代表具有6至13个碳原子的芳烃基团。
• [EN] ORGANOMETALLIC COMPLEX, LIGHT-EMITTING ELEMENT, LIGHT-EMITTING DEVICE, ELECTRONIC DEVICE, AND LIGHTING DEVICE<br/>[FR] COMPLEXE ORGANOMÉTALLIQUE, ÉLÉMENT ÉLECTROLUMINESCENT, DISPOSITIF ÉLECTROLUMINESCENT, DISPOSITIF ÉLECTRONIQUE ET DISPOSITIF D'ÉCLAIRAGE
  申请人：SEMICONDUCTOR ENERGY LAB

  公开号：WO2018109621A1

  公开（公告）日：2018-06-21

  A novel organometallic complex with high emission efficiency is provided. The organometallic complex, which is represented by General Formula (G1), includes iridium and a ligand including an aryl group including a cyano group at the 1-position of a benzimidazole skeleton and a phenyl group at the 2-position of the benzimidazole skeleton. (In the formula, Ar1 represents an aryl group having one or more substituents and 6 to 13 carbon atoms, and Arl includes at least one cyano group as the substituent. Each of R1 to R8 separately represents any of hydrogen, a substituted or unsubstituted alkyl group having 1 to 6 carbon atoms, a substituted or unsubstituted cycloalkyl group having 3 to 6 carbon atoms, a substituted or unsubstituted aryl group having 6 to 13 carbon atoms, a substituted or unsubstituted heteroaryl group having 3 to 12 carbon atoms, and a cyano group.)

  提供了一种具有高发射效率的新型有机金属配合物。该有机金属配合物由通用公式（G1）表示，包括铱和一种配体，其中该配体包括一个芳基团，在苯并咪唑骨架的1-位置带有一个氰基团和在苯并咪唑骨架的2-位置带有一个苯基团。（在公式中，Ar1代表具有一个或多个取代基和6到13个碳原子的芳基团，Arl至少包括一个氰基作为取代基。R1至R8中的每一个分别代表氢、具有1到6个碳原子的取代或未取代烷基基团、具有3到6个碳原子的取代或未取代环烷基基团、具有6到13个碳原子的取代或未取代芳基基团、具有3到12个碳原子的取代或未取代杂环芳基基团和一个氰基。）
• Light-Emitting Element, Display Device, Electronic Device, and Lighting Device
  申请人：Semiconductor Energy Laboratory Co., Ltd.

  公开号：US20170025615A1

  公开（公告）日：2017-01-26

  Provided is a light-emitting element including a first organic compound, a second organic compound, and a guest material. The LUMO level of the first organic compound is lower than that of the second organic compound. The HOMO level of the first organic compound is lower than that of the second organic compound. The LUMO level of the guest material is higher than that of the first organic compound. The HOMO level of the guest material is higher than that of the second organic compound. An energy difference between the LUMO level and the HOMO level of the guest material is larger than an energy difference between the LUMO level of the first organic compound and the HOMO level of the second organic compound. The guest material can convert triplet excitation energy into light emission. The combination of first organic compound and the second organic compound can form an exciplex.

  提供的是一个包括第一有机化合物、第二有机化合物和客体材料的发光元件。第一有机化合物的LUMO能级低于第二有机化合物的LUMO能级。第一有机化合物的HOMO能级低于第二有机化合物的HOMO能级。客体材料的LUMO能级高于第一有机化合物的LUMO能级。客体材料的HOMO能级高于第二有机化合物的HOMO能级。客体材料的LUMO能级和HOMO能级之间的能量差大于第一有机化合物的LUMO能级和第二有机化合物的HOMO能级之间的能量差。客体材料可以将三重激发能量转化为光发射。第一有机化合物和第二有机化合物的组合可以形成一个激基复合物。