(3,7-dimethyl-[2]naphthyl)-methyl ether | 408340-57-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: (3,7-dimethyl-[2]naphthyl)-methyl ether
• 英文别名: (3,7-Dimethyl-[2]naphthyl)-methyl-aether；3-Methoxy-2.6-dimethyl-naphthalin；3-Methoxy-2,6-dimethylnaphthalene；3-methoxy-2,6-dimethylnaphthalene
• CAS: 408340-57-8
• 化学式: C₁₃H₁₄O
• 分子量: 186.254
• InChiKey: SIVGMPQXFANAFL-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.9
• 重原子数：
  14
• 可旋转键数：
  1
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.23
• 拓扑面积：
  9.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  苯酐 、 (3,7-dimethyl-[2]naphthyl)-methyl ether 在 三氯化铝 、 1,1,2,2-四氯乙烷 作用下， 生成 2-(2-methoxy-3,7-dimethyl-[1]naphthoyl)-benzoic acid 、 alkaline earth salt of/the/ methylsulfuric acid
  参考文献：
  名称：

  Some Further Derivatives of Pleiadene¹

  摘要：

  DOI：

  10.1021/ja01339a043
• 作为产物：
  描述：

  甲醇 、 3,7-二甲基萘酚 在 对甲苯磺酸 作用下， 生成 (3,7-dimethyl-[2]naphthyl)-methyl ether
  参考文献：
  名称：

  The Structure of Naphthalene

  摘要：

  DOI：

  10.1021/ja01311a025

文献信息

• Method for the site-specific enzymatic labelling of nucleic acids in vitro by incorporation of unnatural nucleotides
  申请人：The Scripps Research Institute

  公开号：US10626138B2

  公开（公告）日：2020-04-21

  Provided herein are analogs of unnatural nucleotides bearing predominantly hydrophobic nucleobase analogs that form unnatural base pairs during DNA polymerase-mediated replication of DNA or RNA polymerase-mediated transcription of RNA. In this manner, the unnatural nucleobases can be introduced in a site-specific way into oligonucleotides (single or double stranded DNA or RNA), where they can provide for site-specific cleavage, or can provide a reactive linker than can undergo functionalization with a cargo-bearing reagent by means of reaction with a primary amino group or by means of click chemistry with an alkyne group of the unnatural nucleobase linker.

  本文提供的是非天然核苷酸类似物，它们主要带有疏水性核碱基，在 DNA 聚合酶介导的 DNA 复制或 RNA 聚合酶介导的 RNA 转录过程中形成非天然碱基对。通过这种方式，非天然核碱基可以以特定位点的方式引入寡核苷酸（单链或双链 DNA 或 RNA）中，从而实现特定位点的裂解，或者提供一种活性连接体，这种连接体可以通过与伯氨基反应或通过与非天然核碱基连接体的炔基发生点击化学反应，与载货试剂发生官能化反应。
• TRI-BLOCK COPOLYMER AND ELECTROLYTE MEMBRANE MADE FROM THE SAME
  申请人：Choi Seong Ho

  公开号：US20130273450A1

  公开（公告）日：2013-10-17

  Provided are a tri-block copolymer and an electrolyte membrane prepared therefrom. The tri-block copolymer has a structure of polar moiety-containing copolymer block/non-polar moiety-containing copolymer block/polar moiety-containing copolymer block, or non-polar moiety-containing copolymer block/polar moiety-containing copolymer block/non-polar moiety-containing copolymer block, and is useful for an electrolyte membrane for fuel cells. The electrolyte membrane for fuel cells prepared from the tri-block copolymer exhibits superior dimensional stability and excellent fuel cell performance.
• Tri-Block Copolymer and Electrolyte Membrane Made from the Same
  申请人：LG CHEM, LTD.

  公开号：US20140023949A1

  公开（公告）日：2014-01-23

  Provided are a tri-block copolymer and an electrolyte membrane prepared therefrom. The tri-block copolymer has a structure of polar moiety-containing copolymer block/non-polar moiety-containing copolymer block/polar moiety-containing copolymer block, or non-polar moiety-containing copolymer block/polar moiety-containing copolymer block/non-polar moiety-containing copolymer block, and is useful for an electrolyte membrane for fuel cells. The electrolyte membrane for fuel cells prepared from the tri-block copolymer exhibits superior dimensional stability and excellent fuel cell performance.
• US9048479B2
  申请人：——

  公开号：US9048479B2

  公开（公告）日：2015-06-02
• US9142850B2
  申请人：——

  公开号：US9142850B2

  公开（公告）日：2015-09-22