carbamic 1-phenylphenacylester | 116523-50-3

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 二苯乙烯类
• 英文名称: carbamic 1-phenylphenacylester
• 英文别名: 2-Oxo-1,2-diphenylethyl carbamate；(2-oxo-1,2-diphenylethyl) carbamate
• CAS: 116523-50-3
• 化学式: C₁₅H₁₃NO₃
• 分子量: 255.273
• InChiKey: POOPVHNTQVBUTR-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.6
• 重原子数：
  19
• 可旋转键数：
  5
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.07
• 拓扑面积：
  69.4
• 氢给体数：
  1
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  4,5-二苯基-1,3-二氧戊环烯-2-酮 在 氨 作用下， 20.0 ℃ 、80.0 kPa 条件下， 反应 24.0h， 以100%的产率得到carbamic 1-phenylphenacylester
  参考文献：
  名称：

  胺与羰基化合物和异硫氰酸酯的定量固相反应

  摘要：

  据报道，气态或固态胺与醛的一系列固相反应生成亚胺，固态酸酐生成二酰胺（由酰亚胺生成）或酰胺羧酸盐或酰亚胺，固态酰亚胺生成二酰胺，与固态内酯或碳酸盐生成固态反应。得到官能化的氨基甲酸酯，与聚碳酸酯得到降解的氨解，和与固体异硫氰酸酯得到硫脲。二酰胺通过固态热解或酸催化作用生成酰亚胺。据报道，各种双反应，两步反应，3级反应和顺序反应均处于固态而不熔化。在53个已报告的反应实例中，产率是定量的，并且在100％产率的反应中无需进行后处理（除了四次洗涤）。最初的三个固态反应但与液态产物的反应不是定量的。升至公斤级显示了该技术在大规模应用中的前景。原子力显微镜的超显微分析通过三步法中影响深远的各向异性分子运动阐明了固态机制。还使用AFM研究了聚碳酸酯的气固氨基分解酶。讨论了对可持续化学的影响。

  DOI：

  10.1016/s0040-4020(00)00511-1

文献信息

• COMPOSITION CONTAINING VINYL-GROUP-CONTAINING COMPOUND
  申请人：TOKYO OHKA KOGYO CO., LTD.

  公开号：US20160046552A1

  公开（公告）日：2016-02-18

  A composition containing a novel vinyl-group-containing compound. This composition contains a vinyl-group-containing compound represented by general formula (1). In the formula: W 1 and W 2 represent a group represented by general formula (2) (where a ring (Z) is an aromatic hydrocarbon ring, X is a single bond or —S—, R 1 is a single bond or a C1-4 alkylene group, R 2 is a specific substituent group such as a monovalent hydrocarbon, and m is an integer equal to 0 or higher), a group represented by general formula (4) (where the ring (Z), X, R 1 , R 2 , and m are as previously stated), a hydroxyl group, or a (meth)acryloyloxy group; rings (Y 1 , Y 2 ) are aromatic hydrocarbon rings; R represents a single bond or a specific divalent group; R 3a and R 3b represent a cyano group, a halogen atom, or a monovalent hydrocarbon group; and n1 and n2 are integers of 0-4.

  这个组合物包含一种含有新颖乙烯基团的化合物。该组合物包含一个由通式（1）表示的含有乙烯基团的化合物。在该式中：W1和W2代表由通式（2）表示的一个基团（其中环（Z）是芳香烃环，X是一个单键或—S—，R1是一个单键或C1-4烷基基团，R2是特定的取代基团，如一价碳氢化合物，m是大于或等于0的整数），一个由通式（4）表示的基团（其中环（Z）、X、R1、R2和m如前述），一个羟基，或一个（甲基）丙烯酰氧基团；环（Y1、Y2）是芳香烃环；R代表一个单键或一个特定的二价基团；R3a和R3b代表氰基、卤素原子或一价碳氢基团；n1和n2是0-4的整数。
• Processes for producing silane monomers and polymers and photoresist compositions comprising same
  申请人：Shipley Company, L.L.C.

  公开号：US20030219676A1

  公开（公告）日：2003-11-27

  The invention includes new Si-containing monomers, polymers containing such monomers and photoresists that contain the polymers. Synthetic methods of the invention include reacting a vinyl carbocyclic aryl ester compound with a reactive silane compound to provide the monomer.

  该发明包括新的含硅单体、含有这种单体的聚合物和含有聚合物的光刻胶。该发明的合成方法包括将乙烯基环烷基酯化合物与反应性硅烷化合物反应以提供单体。
• Method of producing a crosslinked coating in the manufacture of integrated circuits
  申请人：Hessell T. Edward

  公开号：US20050215713A1

  公开（公告）日：2005-09-29

  The present invention is directed to a method of providing a thermally curable coating composition for to provide positive photoresists layers, underlayers for multiple layer resists, antireflective coatings, bottom layer antireflective coatins, dielectric layers, photoresist layers, hard mask etch stops, in the manufacture of integrated circuits. More particularly, the present invention is directed to a method of using a thermally activable latent acid or a thermal acid generator, a N-benzylpyridinium or N-benzylanilinium salt of a strong acid, as a catalyst in a polymerizable composition suitable for preparing such coatings and layers. The present invention is also directed to novel compositions comprising benzylpyridinium and benzylanilinium salts of a strong acid, such as sulfonic acid or disulfonic acid as thermal acid generators.

  本发明涉及一种提供热固性涂层组合物的方法，用于提供正向光刻层、多层光刻底层、抗反射涂层、底层抗反射涂层、介电层、光刻层、硬膜层刻停等，用于集成电路的制造。更具体地，本发明涉及一种使用热活性潜酸或热酸发生剂、强酸的N-苄基吡啶或N-苄基苯胺盐作为催化剂的聚合物组合物的方法，适用于制备这种涂层和层。本发明还涉及一种新型组合物，包括苄基吡啶和苄基苯胺盐，作为热酸发生剂的强酸，如磺酸或二磺酸。
• CHANGING SURFACE PROPERTIES BY FUNCTIONALIZED NANOPARTICLES
  申请人：Giesenberg Thomas

  公开号：US20100178512A1

  公开（公告）日：2010-07-15

  A process for modifying the surface of an inorganic or organic substrate with strongly adherent nanoparticles is described, providing to the surface modified substrate durable effects like hydrophobicity, hydrophilicity, electrical conductivity, magnetic properties, flame retardance, color, adhesion, roughness, scratch resistance, UV-absorbance, antimicrobial properties, antifouling properties, antiprotein properties, antistatic properties, antifog properties, release properties. In this process, an optional first step a) a low-temperature plasma, ozonization, high energy irradiation, corona discharge or a flame is caused to act on the inorganic or organic substrate, and in a second step b) one or more defined nanoparticles or mixtures of defined nanoparticles with monomers, containing at least one ethylenically unsaturated group, or solutions, suspensions or emulsions of the afore-mentioned substances, are applied, preferably at normal pressure, to the inorganic or organic substrate. In a third step c) suitable methods are applied to dry or cure those afore-mentioned substances and, optionally, in a fourth step d) a further coating is applied on the substrate so pretreated.

  本文描述了一种用强附着力纳米颗粒改性无机或有机基底表面的方法，使表面改性后的基底具有耐久性效果，如疏水性、亲水性、电导性、磁性、防火性、颜色、附着力、粗糙度、抗刮擦性、UV吸收性、抗菌性、防污性、抗蛋白质性、抗静电性、防雾性和释放性。在此过程中，第一步（可选）是在无机或有机基底上施加低温等离子体、臭氧化、高能辐射、电晕放电或火焰，第二步（b）是将一个或多个定义的纳米颗粒或定义的纳米颗粒与至少一个乙烯基未饱和基团的单体，或上述物质的溶液、悬浮液或乳液，应用于无机或有机基底上，最好是在常压下进行。第三步（c）是应用适当的方法干燥或固化上述物质，可选地，在第四步（d）中在预处理的基底上施加进一步的涂层。
• CROSSLINKABLE COMPOSITION COMPRISING PHOTOBASE GENERATORS
  申请人：3M INNOVATIVE PROPERTIES COMPANY

  公开号：US20150232596A1

  公开（公告）日：2015-08-20

  The present disclosure provides an crosslinkable composition comprising a (meth)acrylate copolymer component having pendant photobase functional groups and a crosslinking agent that has amine-reactive functional groups. On exposure to light, the pendant photobase group photolyzes to provide a pendant amine group, that crosslinks the copolymer.

  本公开提供了一种可交联组合物，包括具有悬挂光碱基官能团的（甲基）丙烯酸酯共聚物组分和具有胺反应官能团的交联剂。在光照作用下，悬挂的光碱基官能团光解，形成悬挂的胺基团，这将交联共聚物。