tert-Butylsulfenyl isopropylsulfinyl thioanhydride | 164266-59-5

• 分子结构分类: 有机化合物 - 有机硫化合物 - 硫基化合物
• 英文名称: tert-Butylsulfenyl isopropylsulfinyl thioanhydride
• 英文别名: 2-Methyl-2-(propan-2-ylsulfinyldisulfanyl)propane
• CAS: 164266-59-5
• 化学式: C₇H₁₆OS₃
• 分子量: 212.401
• InChiKey: NOYNQIMKCCHNQM-UHFFFAOYSA-N

物化性质

• 沸点：
  308.7±25.0 °C(Predicted)
• 密度：
  1.167±0.06 g/cm3(Temp: 20 °C; Press: 760 Torr)(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  2.1
• 重原子数：
  11
• 可旋转键数：
  4
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  86.9
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  tert-Butylsulfenyl isopropylsulfinyl thioanhydride 以 氘代氯仿 为溶剂， 反应 96.0h， 以15%的产率得到tert-Butylsulfenyl isopropylsulfonyl thioanhydride
  参考文献：
  名称：

  The Chemistry of Alkylsulfenyl Alkylsulfinyl Thioanhydrides. The Mechanism of Decomposition

  摘要：

  The decomposition mechanism of alkylsulfenyl alkylsulfinyl thioanhydrides has been investigated. Although the product mixture is complex in most cases, a detailed decomposition study as well as a careful analysis of the products allows for a proposal for a general mechanism which is interesting and not simple. We find, however, that the decomposition process is consistent with that of related systems.

  DOI：

  10.1021/jo00119a025
• 作为产物：
  描述：

  tert-butylsulfenic tert-butylsulfinic dithioanhydride 在 isopropylsulfinyl chloride 作用下， 以 氯仿 为溶剂， 反应 12.0h， 生成 叔丁基亚磺酰氯 、 tert-Butylsulfenyl isopropylsulfinyl thioanhydride
  参考文献：
  名称：

  The Chemistry of Alkylsulfenyl Alkylsulfinyl Thioanhydrides. The Mechanism of Decomposition

  摘要：

  The decomposition mechanism of alkylsulfenyl alkylsulfinyl thioanhydrides has been investigated. Although the product mixture is complex in most cases, a detailed decomposition study as well as a careful analysis of the products allows for a proposal for a general mechanism which is interesting and not simple. We find, however, that the decomposition process is consistent with that of related systems.

  DOI：

  10.1021/jo00119a025

文献信息

• The Chemistry of Alkylsulfenyl Alkylsulfinyl Thioanhydrides. The Mechanism of Decomposition
  作者：Gerard Derbesy、David N. Harpp

  DOI：10.1021/jo00119a025

  日期：1995.7

  The decomposition mechanism of alkylsulfenyl alkylsulfinyl thioanhydrides has been investigated. Although the product mixture is complex in most cases, a detailed decomposition study as well as a careful analysis of the products allows for a proposal for a general mechanism which is interesting and not simple. We find, however, that the decomposition process is consistent with that of related systems.