1-Formyl-naphthalin-(N-methyl-phenylhydrazon) | 24090-99-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: 1-Formyl-naphthalin-(N-methyl-phenylhydrazon)
• 英文别名: [1]naphthaldehyde-(methyl-phenyl-hydrazone)；[1]Naphthaldehyd-(methyl-phenyl-hydrazon)；1-Naphthaldehyde 1-methyl-1-phenylhydrazone；N-methyl-N-(naphthalen-1-ylmethylideneamino)aniline
• CAS: 24090-99-1
• 化学式: C₁₈H₁₆N₂
• 分子量: 260.338
• InChiKey: XONSRLHXNRNRLZ-UHFFFAOYSA-N

物化性质

• 沸点：
  418.8±28.0 °C(Predicted)
• 密度：
  1.03±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  4.9
• 重原子数：
  20
• 可旋转键数：
  3
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.06
• 拓扑面积：
  15.6
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  1-萘二硫代羧酸 、 1-甲基-1-苯肼 生成 1-Formyl-naphthalin-(N-methyl-phenylhydrazon)
  参考文献：
  名称：

  Wuyts; Goldstein, Bulletin des Societes Chimiques Belges, 1931, vol. 40, p. 497,500

  摘要：

  DOI：

文献信息

• Novel hydrazone compounds and process for preparing the same
  申请人：Ricoh Company, Ltd.

  公开号：US04332948A1

  公开（公告）日：1982-06-01

  Hydrazone compounds having the general formula ##STR1## wherein Ar is selected from the group consisting of a naphthalene ring radical, substituted naphthalene ring radicals, an anthracene ring radical, substituted anthracene ring radicals, styryl, substituted styryls, a pyridine radical, a furan ring radical and a thiophene ring radical. The hydrazone compounds can be prepared by allowing 1-methyl-1-phenylhydrazine having the formula ##STR2## to react with an aldehyde represented by the general formula Ar-CHO, wherein Ar is the same as mentioned above at a substantially equal molar ratio in an organic solvent selected from the group consisting of lower alcohols, cyclic ethers, cellosolves, N,N-dimethylforamide and acetic acid, in the presence of an acid catalyst, by heating and refluxing the reaction mixture. The hydrazone compounds are extremely useful as charge transport materials for use in electrophotographic photoconductors of the type comprising an electroconductive support material and a photosensitive layer containing a charge generation material and a charge transport material.

  具有一般式##STR1##的腙酮化合物，其中Ar选自以下组中的一组：萘环基，取代萘环基，蒽环基，取代蒽环基，苯乙烯基，取代苯乙烯基，吡啶基，呋喃环基和噻吩环基。可以通过在有机溶剂中的存在下，通过加热和回流反应混合物，让具有式##STR2##的1-甲基-1-苯基肼与通式Ar-CHO表示的醛反应，其中Ar与上述相同，反应物的摩尔比几乎相等，存在酸催化剂。这些腙酮化合物非常有用，可用作电子照相导电层的电荷传输材料，该电子照相导电层包含电导支撑材料和含有电荷发生材料和电荷传输材料的感光层。
• Imaging members with charge transport layers containing high performance polymer blends
  申请人：Xerox Corporation

  公开号：EP0918258A2

  公开（公告）日：1999-05-26

  Disclosed is an imaging member which comprises a conductive substrate, a photogenerating material, a charge transport material, and a polymeric binder comprising (a) a first polymer comprising a polycarbonate, and (b) a second polymer of the formulae I, II, III, IV, V, VI, VII, VIII, IX, or X as further defined herein.

  本发明公开了一种成像元件，它包括导电基板、光生成材料、电荷传输材料和聚合物粘合剂，聚合物粘合剂包括(a)由聚碳酸酯组成的第一种聚合物和(b)本文进一步定义的式 I、II、III、IV、V、VI、VII、VIII、IX 或 X 中的第二种聚合物。
• Branched polyarylene ethers and processes for the preparation thereof
  申请人：Bender P. Timothy

  公开号：US20050208416A1

  公开（公告）日：2005-09-22

  Disclosed is a process for preparing branched polyarylene ether polymers by (A) providing a reaction mixture comprising (i) a polyfunctional phenol compound of the formula Ar(OH) x wherein x≧3 and wherein Ar is an aryl moiety or an alkylaryl moiety, provided that when Ar is an alkylaryl moiety at least three of the —OH groups are bonded to an aryl portion thereof, (ii) a compound of the formula wherein m is 0 or 1, Y and Y′ each, independently of the other, is fluorine or chlorine, and A is as defined herein, (iii) a compound of the formula wherein B is as defined herein, and (iv) a carbonate base; and (B) heating the reaction mixture and removing generated water from the reaction mixture, thereby effecting a polymerization reaction. Also disclosed are polymers prepared by this process and imaging members containing these polymers.

  本发明公开了一种用于制备支化聚芳醚聚合物的工艺，其方法是 (A) 提供一种反应混合物，该混合物包含 (i) 式为 Ar(OH)的多官能团苯酚化合物 x 式中 x≧3，Ar 为芳基或烷基芳基，条件是当 Ar 为烷基芳基时，至少有三个 -OH 基团与芳基部分键合，(ii) 式中化合物 其中 m 为 0 或 1，Y 和 Y′各自独立地为氟或氯，A 如本文所定义，(iii) 式化合物 其中 B 如本文所定义，和 (iv) 碳酸碱；和 (B) 加热反应混合物并从反应混合物中除去生成的水，从而实现聚合反应。还公开了通过该工艺制备的聚合物和含有这些聚合物的成像部件。
• PROCESS OF MAKING HYDROPHOBIC METAL OXIDE NANOPARTICLES
  申请人：Qi Yu

  公开号：US20060171870A1

  公开（公告）日：2006-08-03

  A process of treating metal oxide nanoparticles that includes mixing metal oxide nanoparticles, a solvent, and a surface treatment agent that is preferably a silane or siloxane is described. The treated metal oxide nanoparticles are rendered hydrophobic by the surface treatment agent being surface attached thereto, and are preferably dispersed in a hydrophobic aromatic polymer binder of a charge transport layer of a photoreceptor, whereby π-π interactions can be formed between the organic moieties on the surface of the nanoparticles and the aromatic components of the binder polymer to achieve a stable dispersion of the nanoparticles in the polymer that is substantially free of large sized agglomerations.

  描述了一种处理金属氧化物纳米颗粒的工艺，包括混合金属氧化物纳米颗粒、溶剂和表面处理剂（最好是硅烷或硅氧烷）。经过处理的金属氧化物纳米颗粒通过表面处理剂的表面附着变得疏水，最好分散在光感受器电荷传输层的疏水芳香族聚合物粘合剂中，这样纳米颗粒表面的有机分子和粘合剂聚合物的芳香族成分之间可以形成π-π相互作用，实现纳米颗粒在聚合物中的稳定分散，基本上没有大尺寸团聚。
• Wuyts; Goldstein, Bulletin des Societes Chimiques Belges, 1931, vol. 40, p. 497,500
  作者：Wuyts、Goldstein

  DOI：——

  日期：——