1-(2-methyl-5-phenyl-3-thienyl)perfluorocyclopentene | 885051-73-0

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 噻吩类
• 英文名称: 1-(2-methyl-5-phenyl-3-thienyl)perfluorocyclopentene
• 英文别名: 3-(3,3,4,4,5,5-Hexafluorocyclopenten-1-yl)-2-methyl-5-phenylthiophene；3-(3,3,4,4,5,5-hexafluorocyclopenten-1-yl)-2-methyl-5-phenylthiophene
• CAS: 885051-73-0
• 化学式: C₁₆H₁₀F₆S
• 分子量: 348.312
• InChiKey: HDYBEWSYWGMPQX-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.3
• 重原子数：
  23
• 可旋转键数：
  2
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.25
• 拓扑面积：
  28.2
• 氢给体数：
  0
• 氢受体数：
  7

反应信息

• 作为反应物：
  描述：

  1-(2-methyl-5-phenyl-3-thienyl)perfluorocyclopentene 在 吡啶 、 正丁基锂 、 对甲苯磺酸 作用下， 以 四氢呋喃 、 乙醇 、 水 、 丙酮 为溶剂， 反应 29.0h， 生成
  参考文献：
  名称：

  多功能肼基苯并噻唑基二芳基乙烯衍生物：高效区分锌离子中的镉离子和近红外吸收法检测氢氧根离子

  摘要：

  合成了一种新的具有肼基苯并噻唑单元的二芳基乙烯衍生物1O，并对其在紫外/可见光和化学刺激（Cd 2 +，Zn 2+和酸/碱）的诱导下的多可控转换行为进行了研究。1O可以作为肉眼探针来区分Cd 2+和Zn 2+，在荧光和吸收光谱上有明显不同的行为。当受Cd 2+刺激时，其溶液颜色变为浅黄色，荧光颜色从深黄色变为亮黄色。同样，当由Zn 2+触发时，其溶液颜色变为深黄色，并伴随着荧光颜色从暗到橙色的变化。。由于1O与Cd 2+的配位能力比与Zn 2+的配位能力要强得多，因此添加Cd 2+后，观察到明显的蓝移（约51 nm），同时可见荧光颜色从橙色变为亮黄色。进入1O-Zn 2+，这意味着1O还可以逐步检测Zn 2+和Cd 2+。此外，1O表现出明显的溶剂依赖性酸致变色现象。加碱后，闭环吸收峰为1C显示出明显的红移向近红外区域的转变，伴随着从蓝色到绿色的明显颜色变化。此外，构建了一个逻辑电路，以紫外线/可见光，Cd

  DOI：

  10.1016/j.dyepig.2017.07.018

文献信息

• New photochromic diarylethenes with a six-membered aryl unit
  作者：Shouzhi Pu、Congbin Fan、Wenjuan Miao、Gang Liu

  DOI：10.1016/j.tet.2008.07.073

  日期：2008.9

  A new class of photochromic diarylethenes bearing a six-membered aryl unit has been developed. They underwent reversible cyclization and cycloreversion reactions upon alternating irradiation with UV and visible light both in solution and in PMMA film. However, diarylethenes 1, 2, and 4 showed no photochromism in the crystalline phase although they packed with an anti-parallel conformation and the distances between the two reactive carbon atoms were both less than 4.2 angstrom. (C) 2008 Elsevier Ltd. All rights reserved.
• [EN] A METHOD OF REMOVING MAKEUP AND A MAKEUP REMOVER<br/>[FR] PROCÉDÉ DE DÉMAQUILLAGE ET DÉMAQUILLANT
  申请人：OREAL

  公开号：WO2010095116A1

  公开（公告）日：2010-08-26

  The present invention relates to a method of removing makeup from keratinous materials that have been made up with a thermally stable photochromic composition that is developed by irradiation at least at a wavelength λ, in which method at least one optical agent forming a screen at least at the wavelength λ is applied during or after makeup removal.
• [EN] A COSMETIC TREATMENT METHOD INCLUDING THE PROJECTION OF AN IMAGE ONTO THE ZONE TO BE TREATED<br/>[FR] PROCÉDÉ APPLICABLE À UN TRAITEMENT COSMÉTIQUE IMPLIQUANT LA PROJECTION D'UNE IMAGE SUR LA ZONE À TRAITER
  申请人：OREAL

  公开号：WO2010095118A2

  公开（公告）日：2010-08-26

  The present inventions relates to a treatment method for treating human keratinous material, the method comprising: a) projecting an image onto a zone to be treated; b) modifying the content and/or adjusting the projected image; and c) cosmetically treating the zone as a function of the image as modified and/or adjusted in this way.
• [EN] A METHOD OF MAKING UP USING AN ADDRESSABLE MATRIX LIGHT SOURCE<br/>[FR] PROCEDE DE MAQUILLAGE METTANT EN OEUVRE UNE SOURCE DE LUMIERE A MATRICE ADRESSABLE
  申请人：OREAL

  公开号：WO2010095120A1

  公开（公告）日：2010-08-26

  The invention provides a method of making up a zone of a subject with light-sensitive makeup, said zone being coated with a thermally stable photochromic composition, in which method an image is formed on the thermally stable photochromic composition using an electronic addressable matrix imager.
• [EN] A METHOD OF MAKING UP WITH LIGHT-SENSITIVE MAKEUP USING A PHOTOCHROMIC COMPOSITION IN THE ALREADY-DEVELOPED STATE<br/>[FR] PROCÉDÉ DE MAQUILLAGE AVEC UN MAQUILLAGE PHOTOSENSIBLE AU MOYEN D'UNE COMPOSITION PHOTOCHROME À L'ÉTAT DÉJÀ DÉVELOPPÉ
  申请人：OREAL

  公开号：WO2010095117A1

  公开（公告）日：2010-08-26

  The present invention provides a method of making up keratinous material with light-sensitive makeup, the method comprising: • applying on keratinous material a photochromic composition including a thermally stable photochromic agent in the already at least partially developed state.