3-(1-imidazolyl)propylcarbamoyl-3'-aminopropyltriethoxysilane | 1095817-48-3

• 分子结构分类: 有机化合物 - 有机金属化合物 - 有机类金属化合物
• 英文名称: 3-(1-imidazolyl)propylcarbamoyl-3'-aminopropyltriethoxysilane
• 英文别名: 1-(3-Imidazol-1-ylpropyl)-3-(3-triethoxysilylpropyl)urea；1-(3-imidazol-1-ylpropyl)-3-(3-triethoxysilylpropyl)urea
• CAS: 1095817-48-3
• 化学式: C₁₆H₃₂N₄O₄Si
• 分子量: 372.54
• InChiKey: GMSANFVCLCCDNQ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.01
• 重原子数：
  25
• 可旋转键数：
  14
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.75
• 拓扑面积：
  86.6
• 氢给体数：
  2
• 氢受体数：
  5

反应信息

• 作为反应物：
  描述：

  2,4,6-三溴甲基三甲基苯 、 3-(1-imidazolyl)propylcarbamoyl-3'-aminopropyltriethoxysilane 以 乙腈 为溶剂， 以87%的产率得到
  参考文献：
  名称：

  离子桥接倍半硅氧烷的纳米结构

  摘要：

  已经研究了通过水解/缩合将四种新的基于异丁基（双或三）咪唑鎓的烷氧基硅烷前体转化为相应的桥联倍半硅氧烷的方法。这些前体具有脲基和亚烷基短链或长链，已知有利于自组装。最规则的纳米结构是通过三脚架前体与C 10 H 20亚烷基链的组合获得的，如粉末X射线衍射（PXRD）分析所示，与反应条件无关。

  DOI：

  10.1002/asia.201300538
• 作为产物：
  描述：

  异氰酸丙基三乙氧基硅烷 、 3-(1H-咪唑-2-基)-1-丙胺 以 二氯甲烷 为溶剂， 反应 5.0h， 以99%的产率得到3-(1-imidazolyl)propylcarbamoyl-3'-aminopropyltriethoxysilane
  参考文献：
  名称：

  离子桥接倍半硅氧烷的纳米结构

  摘要：

  已经研究了通过水解/缩合将四种新的基于异丁基（双或三）咪唑鎓的烷氧基硅烷前体转化为相应的桥联倍半硅氧烷的方法。这些前体具有脲基和亚烷基短链或长链，已知有利于自组装。最规则的纳米结构是通过三脚架前体与C 10 H 20亚烷基链的组合获得的，如粉末X射线衍射（PXRD）分析所示，与反应条件无关。

  DOI：

  10.1002/asia.201300538

文献信息

• Homogenous formation and quaternization of urea-functionalized imidazolyl silane and its immobilization on silica for surface-confined ionic liquid stationary phases
  作者：Mingliang Zhang、Jia Chen、Hongdeng Qiu、Abul K. Mallik、Makoto Takafuji、Hirotaka Ihara

  DOI：10.1039/c4ra04772a

  日期：——

  New strategy for surface modification of silica sphere was proposed on the basis of one-pot urea formation and quaternization of imidazole, resulting in sorbents of high tunability and controllable hydrophobicity.

  基于一锅法尿素形成和咪唑的季铵化，提出了一种新的二氧化硅球表面改性策略，结果是具有高可调性和可控疏水性的吸附剂。
• Oxidative Debromination and Degradation of Tetrabromo-bisphenol A by a Functionalized Silica-Supported Iron(III)-tetrakis(p-sulfonatophenyl)porphyrin Catalyst
  作者：Qianqian Zhu、Yusuke Mizutani、Shohei Maeno、Masami Fukushima

  DOI：10.3390/molecules18055360

  日期：——

  community. Iron(III)-porphyrin complexes are generally regarded as "green" catalysts and have been reported to catalyze the efficient degradation and dehalogenation of halogenated phenols in environmental wastewaters. However, they are quickly deactivated due to self-degradation in the presence of an oxygen donor, such as KHSO₅. In the present study, an iron(III)-tetrakis (p-sulfonatophenyl)-porphyrin

  四溴双酚 A (TBBPA) 是一种常用的溴化阻燃剂，也可作为内分泌干扰物。因此，TBBPA 的降解引起了科学界的极大兴趣。铁 (III)-卟啉配合物通常被认为是“绿色”催化剂，据报道可催化环境废水中卤代酚的有效降解和脱卤。然而，由于在供氧体（如 KHSO₅）存在下自降解，它们会迅速失活。在本研究中，铁 (III)-四 (对磺基苯基)-卟啉 (FeTPPS) 通过 Fe(III) 与咪唑中的氮原子配位固定在咪唑改性二氧化硅 (FeTPPS/IPS) 上以抑制自降解，从而提高催化剂的可重复使用性。研究了 TBBPA 的氧化降解和脱溴以及浸出液中的主要成分腐植酸 (HA) 对 TBBPA 氧化的影响。在不存在 HA 的情况下，超过 95% 的 TBBPA 在 3 到 8 的 pH 范围内被降解，而在 HA 存在下，反应的最佳 pH 值为 8。尽管在 HA 存在下降解率降低，但在 28 mg-C
• Zwitterionic Imidazole-Urea Derivative Framework Bridged Mesoporous Hybrid Silica: A Highly Efficient Heterogeneous Nanocatalyst for Carbon Dioxide Conversion
  作者：Mengshuai Liu、Xingyuan Lu、Yichen Jiang、Jianmin Sun、Masahiko Arai

  DOI：10.1002/cctc.201701492

  日期：2018.4.24

  spectroscopy, solid‐state NMR spectroscopy, X‐ray photoelectron spectroscopy, XRD, TEM, and thermogravimetric analysis. The new Im‐Si‐X‐ϕ materials possess a high surface area, hydrogen‐bond donor ability, and nucleophilicity. The material that contains iodine and is protonated by an inorganic acid shows an excellent catalytic activity for CO2 conversion into cyclic carbonates with good recyclability. Reaction

  负载型两性离子纳米颗粒的使用是开发具有增强的活性和选择性的新型CO 2转化催化剂的有趣且重要的策略。通过使用FTIR光谱，固态NMR光谱，X射线光电子能谱，XRD，TEM和热重分析，制备了几种两性离子咪唑-脲衍生物架桥的介孔杂化二氧化硅材料。新型的Im-Si-X-ϕ材料具有较高的表面积，氢键供体能力和亲核性。含有碘并被无机酸质子化的材料显示出出色的催化活性，可将CO 2转化为具有良好可回收性的环状碳酸酯。CO 2环加成反应的反应参数用环氧丙烷对碳酸亚丙酯进行了优化。单组分材料是用于CO 2环加成反应的高效多相催化剂，是常规负载型过渡金属催化剂的绿色替代品。还将其催化特性与先前报道的无载体的游离离子化合物和其他载体的催化剂进行了比较。
• A novel chelating organosilicone resin bearing long chain imidazolyl ligands: Preparation, characterization, and adsorption properties
  作者：Chunxiao Li、Jintao Dou、Jiaojie Cao、Zhengqiang Li、Weikai Chen、Qingzeng Zhu、Chenfu Zhu

  DOI：10.1016/j.jorganchem.2012.12.034

  日期：2013.3

  The imidazole ring is an important chemical component in nature that plays various critical roles. In this study, the imidazole used as a metal-chelating ligand was combined with a silicone resin structure by a long chain. The preparation, surface properties, thermal stability, complexation and adsorption properties with respect to Cu2+ ions, and multiple use cycles of the synthesized organosilicone resin bearing long chain imidazolyl ligands (ImSR) were studied using Fourier transform infrared spectroscopy (FTIR), H-1, C-13 and Si-29 nuclear magnetic resonance (NMR), a contact angle goniometer, thermogravimetric analysis (TGA) and UV-visible spectrophotometry methods. ImSR is a hydrophilic material with a water contact angle of 56 degrees on a flat surface. It possesses good thermal stability and exhibits rapid weight loss above 230 degrees C. ImSR was evaluated as a promising adsorbing material for Cu2+ ions. It exhibited a high affinity for Cu2+ ions, with a maximum adsorption ability of 66.1 mg/g. Langmuir, Freundlich and Dubinin-Radushkevich isotherm models were used to analyze the experimental data. The results showed that the ImSR absorbent exhibited chemisorption and monolayer distribution on homogeneous active sites. The equilibrium adsorption capacity remained relatively constant after 5 use cycles. (C) 2013 Elsevier B.V. All rights reserved.
• Imidazole versus pyridine as ligands for metalloporphine immobilization in ligninolytic peroxidases-like biomimetic catalysts
  作者：Paolo Zucca、Gianmarco Cocco、Stefania Manca、Daniela Steri、Enrico Sanjust

  DOI：10.1016/j.molcata.2014.07.013

  日期：2014.11

  This paper describes the immobilization of 5,10,15,20-tetrakis(2,6-dichlorophenyl)porphine-manganese(III) through coordinative bond onto imidazolyl- and pyridyl-grafted silica, emulating the active site of ligninolytic peroxidases. To this purpose, plain silica gel was functionalized with two organosilanes: the first bearing an imidazolyl functionality, the other one bearing a pyridyl functionality. Manganese-porphine was then immobilized onto the two modified silicas. The two catalytic adducts have been fully characterized to point out the effect of the ligands on their catalytic features. Pyridine-immobilized metalloporphine was found to be a much more performant catalyst, giving significantly higher conversion rates with all the tested substrates: a lignin-model compound such as veratryl alcohol, the lignin peroxidase well-known substrate azure B, and recalcitrant textile dyes such as alizarin red S, phenosafranine, methylene blue, methyl green, xylenol orange, and methyl orange. Imidazole-immobilized metalloporphine on the contrary has proved to be more stable than its pyridine-based counterpart. Besides, the ligands seem to promote different catalytic pathways in the two adducts. These results allow giving rational and rigorous insights about the effect of the ligands during the immobilization of metalloporphines, thus helping in the design of catalysts with specific feature (i.e. stability, reactivity). (C) 2014 Elsevier B.V. All rights reserved.