3-(2,2,2-trinitro-ethoxy)-propene | 41029-59-8

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 原羧酸衍生物
• 英文名称: 3-(2,2,2-trinitro-ethoxy)-propene
• 英文别名: allyl 2,2,2-trinitroethyl ether；Allyl trinitroethyl ether；3-(2,2,2-trinitroethoxy)prop-1-ene
• CAS: 41029-59-8
• 化学式: C₅H₇N₃O₇
• 分子量: 221.126
• InChiKey: RLTYEJCJHQDQFW-UHFFFAOYSA-N

物化性质

• 沸点：
  256.2±40.0 °C(Predicted)
• 密度：
  1.465±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  0.5
• 重原子数：
  15
• 可旋转键数：
  4
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.6
• 拓扑面积：
  147
• 氢给体数：
  0
• 氢受体数：
  7

反应信息

• 作为反应物：
  描述：

  3-(2,2,2-trinitro-ethoxy)-propene 在 间氯过氧苯甲酸 作用下， 以 氯仿 为溶剂， 反应 6.0h， 以60%的产率得到glycidyl 2,2,2-trinitroethyl ether
  参考文献：
  名称：

  Synthesis and polymerization of glycidyl ethers

  摘要：

  制备新型烯丙基醚的方法。新型环氧丙烯醚及其制备方法。多官能团聚合物（环氧丙烯醚）及其制备方法。基于多官能团环氧丙烯醚的新型聚氨酯及其制备方法。

  公开号：

  US08318959B1
• 作为产物：
  描述：

  triethylammonium trinitromethane salt 、 1-氯甲氧基-2-丙烯 以 乙腈 为溶剂， 反应 24.0h， 以48%的产率得到3-(2,2,2-trinitro-ethoxy)-propene
  参考文献：
  名称：

  Trinitroethyl ethers of substituted alcohols

  摘要：

  The influence of the trinitromethane salt cations and the substituents in the alkyl moiety of chloromethyl ethers of alcohols on the yields of trinitroethyl ethers of the substituted alcohols formed from them was established. On this basis a representative series of previously unavailable trinitroethanol ethers was synthesized.

  DOI：

  10.1007/bf00961040

文献信息

• Synthesis of some novel trifluoromethanesulfonates and their reactions with alcohols
  作者：Charles D. Beard、Kurt Baum、Vytautas Grakauskas

  DOI：10.1021/jo00961a003

  日期：1973.10
• (2,2,2-Trinitroethoxy)acetic acid and its derivatives
  作者：O. A. Luk'yanov、G. V. Pokhvisneva

  DOI：10.1007/bf00961041

  日期：1991.11

  Methods are developed for synthesizing (2,2,2-trinitroethoxy)acetic acid (TNEAA) by oxidation of the 2,2,2-trinitroethyl ethers of allylic alcohol or ethylene glycol; among the carboxyl group derivatives obtained were esters from the simplest alcohols and polynitro alcohols, the acid chloride, the amide, and the nitrile.
• 2,2,2-Trinitroethyl ethers of 2,2-dinitroalcohols
  作者：O. A. Luk'yanov、G. V. Pokhvisneva

  DOI：10.1007/bf00959717

  日期：1991.12

  2,2,2-Trinitroethyl ethers of 2,2-dinitroalcohols and some of their derivatives have been obtained for the first time by nitration of oximes of 2,2,2-trinitroethyl ethers of hydroxy ketones and aldehydes with a HNO3-Ac2O mixture, followed by oxidation with H2O2. Starting carbonyl derivatives were prepared by oxidation and hydrolysis of the propargylic and allylic ethers, respectively, of 2,2,2-trinitroethanol followed by further reactions of these compounds.
• Trinitroethyl ethers of substituted alcohols
  作者：O. A. Luk'yanov、G. V. Pokhvisneva

  DOI：10.1007/bf00961040

  日期：1991.11

  The influence of the trinitromethane salt cations and the substituents in the alkyl moiety of chloromethyl ethers of alcohols on the yields of trinitroethyl ethers of the substituted alcohols formed from them was established. On this basis a representative series of previously unavailable trinitroethanol ethers was synthesized.
• Synthesis and polymerization of glycidyl ethers
  申请人：Flurochem, Inc.

  公开号：US08318959B1

  公开（公告）日：2012-11-27

  The method of preparing novel allyl ethers. Novel glycidyl ethers and their preparation. Polyfunctional poly(glycidyl ethers) their methods of preparation. Novel polyurethanes based on the polyfunctional glycidyl ethers and their method of preparation.

  制备新型烯丙基醚的方法。新型环氧丙烯醚及其制备方法。多官能团聚合物（环氧丙烯醚）及其制备方法。基于多官能团环氧丙烯醚的新型聚氨酯及其制备方法。