copper(II)(iminodiacetato)(o-phenanthroline)*H2O | 749207-84-9

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 菲咯啉
• 英文名称: copper(II)(iminodiacetato)(o-phenanthroline)*H2O
• 英文别名: Copper;2-(carboxylatomethylamino)acetate;1,10-phenanthroline;hydrate
• CAS: 749207-84-9；118211-02-2
• 化学式: C₁₆H₁₅CuN₃O₅
• 分子量: 392.858
• InChiKey: ZWEPQGIOPIRBMX-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  -1.97
• 重原子数：
  25
• 可旋转键数：
  2
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.12
• 拓扑面积：
  119
• 氢给体数：
  2
• 氢受体数：
  8

反应信息

• 作为产物：
  描述：

  1,10-菲罗啉 、 copper diacetate 、 亚氨基二乙酸 以 乙醇 为溶剂， 生成 copper(II)(iminodiacetato)(o-phenanthroline)*H2O
  参考文献：
  名称：

  Studies on mixed-ligand complexes of some transition metals of biological interest

  摘要：

  A series of mixed-ligand complexes of Co(II), Ni(II), Cu(II) and Zn(II) with general formula M(IM)(L).H2O, where H2IM = iminodiacetic acid; L = 2,2'-bipyridyl and o-phenanthroline, have been studied and isolated in pure state. The metal chelates have been characterized by elemental analysis, IR and electronic spectra, conductivity and magnetic measurements. The octahedral environment around the metal ion has been proposed. The thermal properties of metal complexes in solid state have been studied under non-isothermal condition in nitrogen atmosphere by simultaneous TG and DTA. TG and DTA curves show that the decomposition took place in two steps. Thermodynamic parameters such as activation energy, E, order of reaction, n, entropy of activation, DELTA-S(double dagger), and free energy of activation, DELTA-G(double dagger), have been determined by standard methods. All the complexes are non-electrolytic in nature. The antimicrobial activity against fungi is critically examined. The difference in their site of action against various fungi has been explained on the basis of formation constants and liposolubility.

  DOI：

  10.1007/bf01975075

文献信息

• Studies on mixed-ligand complexes of some transition metals of biological interest
  作者：R. Nagar、G. Mohan

  DOI：10.1007/bf01975075

  日期：1992.6

  A series of mixed-ligand complexes of Co(II), Ni(II), Cu(II) and Zn(II) with general formula M(IM)(L).H2O, where H2IM = iminodiacetic acid; L = 2,2'-bipyridyl and o-phenanthroline, have been studied and isolated in pure state. The metal chelates have been characterized by elemental analysis, IR and electronic spectra, conductivity and magnetic measurements. The octahedral environment around the metal ion has been proposed. The thermal properties of metal complexes in solid state have been studied under non-isothermal condition in nitrogen atmosphere by simultaneous TG and DTA. TG and DTA curves show that the decomposition took place in two steps. Thermodynamic parameters such as activation energy, E, order of reaction, n, entropy of activation, DELTA-S(double dagger), and free energy of activation, DELTA-G(double dagger), have been determined by standard methods. All the complexes are non-electrolytic in nature. The antimicrobial activity against fungi is critically examined. The difference in their site of action against various fungi has been explained on the basis of formation constants and liposolubility.