N,N,N-tri-(4'-methoxy-1,1'-biphenyl)amine | 138796-59-5

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: N,N,N-tri-(4'-methoxy-1,1'-biphenyl)amine
• 英文别名: tris(4'methoxy[1,1′-biphenyl]-4-yl)amine；tris(4'-methoxybiphenyl-4-yl)amine；Tris-(4'-methoxybiphenyl-4-yl)-amine；4-(4-methoxyphenyl)-N,N-bis[4-(4-methoxyphenyl)phenyl]aniline
• CAS: 138796-59-5
• 化学式: C₃₉H₃₃NO₃
• 分子量: 563.696
• InChiKey: DWMVVARYAFLTHT-UHFFFAOYSA-N

物化性质

• 沸点：
  740.9±60.0 °C(Predicted)
• 密度：
  1.154±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  10
• 重原子数：
  43
• 可旋转键数：
  9
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.08
• 拓扑面积：
  30.9
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  N,N,N-tri-(4'-methoxy-1,1'-biphenyl)amine 在 copper(II) perchlorate 作用下， 以 乙腈 为溶剂， 生成
  参考文献：
  名称：

  Redox-controlled fluorescence modulation (electrofluorochromism) in triphenylamine derivatives

  摘要：

  报道了对一系列取代三苯胺衍生物的化学和电化学荧光开关特性进行研究。

  DOI：

  10.1039/c4ra02675f
• 作为产物：
  描述：

  三(4-溴苯基)胺 、 4-甲氧基苯硼酸 在 四丁基溴化铵 、 potassium carbonate 作用下， 以 水 为溶剂， 反应 3.0h， 以90%的产率得到N,N,N-tri-(4'-methoxy-1,1'-biphenyl)amine
  参考文献：
  名称：

  铃木-Miyaura水溶液偶联的钯-NHC复合物的便捷一锅纳米催化剂封装†

  摘要：

  使用水作为溶剂的有机转化已成为广泛研究的焦点。我们在此提出了一种策略，该策略使用简单的纳米颗粒封装来制造水溶性纳米催化剂（NC），以进行水交叉偶联反应。为了实现这一目标，三种类型的N-杂环卡宾的（NHC） -钯（Pd）的复合物（即，图1b，图2b，和图3b具有化学式）[PDL（CH 3 CN）CL] PF 6（其中L是含二齿吡啶或嘧啶的NHC配体）已被合成，并且它们的结构通过NMR光谱和X射线晶体学表征。利用一种简便的一锅封装方法，水不溶性Pd-NHC复合物可以整合到由两亲共聚物组成的胶束的疏水核中。这些水分散的纳米颗粒在Suzuki-Miyaura水溶液偶联中表现出出色的催化活性。在这些NC中，发现在其NHC配体上带有异氰酸酯部分的3b -NC在测试的反应条件下是活性最高的催化剂。更令人印象深刻的是，3b -NC可以重复使用至少五个循环而不会显着降低催化活性。

  DOI：

  10.1039/c7nj04836j

文献信息

• Facile one-pot nanocatalysts encapsulation of palladium–NHC complexes for aqueous Suzuki–Miyaura couplings
  作者：Chao Chen、Qing Zheng、Shengliang Ni、Hangxiang Wang

  DOI：10.1039/c7nj04836j

  日期：——

  nanoparticle encapsulation to fabricate water-soluble nanocatalysts (NCs) for aqueous cross-coupling reactions. To achieve this goal, three types of N-heterocyclic carbene (NHC)–palladium (Pd) complexes (i.e., 1b, 2b, and 3b) with the chemical formula [PdL(CH3CN)Cl]PF6 (where L is a bidentate pyridine- or pyrimidine-bearing NHC ligand) have been synthesized, and their structures were characterized by NMR spectroscopy

  使用水作为溶剂的有机转化已成为广泛研究的焦点。我们在此提出了一种策略，该策略使用简单的纳米颗粒封装来制造水溶性纳米催化剂（NC），以进行水交叉偶联反应。为了实现这一目标，三种类型的N-杂环卡宾的（NHC） -钯（Pd）的复合物（即，图1b，图2b，和图3b具有化学式）[PDL（CH 3 CN）CL] PF 6（其中L是含二齿吡啶或嘧啶的NHC配体）已被合成，并且它们的结构通过NMR光谱和X射线晶体学表征。利用一种简便的一锅封装方法，水不溶性Pd-NHC复合物可以整合到由两亲共聚物组成的胶束的疏水核中。这些水分散的纳米颗粒在Suzuki-Miyaura水溶液偶联中表现出出色的催化活性。在这些NC中，发现在其NHC配体上带有异氰酸酯部分的3b -NC在测试的反应条件下是活性最高的催化剂。更令人印象深刻的是，3b -NC可以重复使用至少五个循环而不会显着降低催化活性。
• Cross Linked Organic Conductive Layer
  申请人：Gough Neil

  公开号：US20110245429A1

  公开（公告）日：2011-10-06

  The present invention provides various compounds, compositions, methods, and processes for forming a cross-linked conductive polymeric layer in an electronic device.

  本发明提供了各种化合物、组合物、方法和过程，用于在电子设备中形成交联导电聚合层。
• Microporous Cyanate Resins: Synthesis, Porous Structure, and Correlations with Gas and Vapor Adsorptions
  作者：Hao Yu、Changjiang Shen、Mengzhe Tian、Jing Qu、Zhonggang Wang

  DOI：10.1021/ma3008652

  日期：2012.6.26

  Three silicon and nitrogen-centered cyanate monomers tetrakis(4-cyanatophenyl)silane, tetrakis(4-cyanato-biphenyl)silane, and tris(4-cyanatobiphenyl)amine were designed and synthesized, which were then polymerized via thermal cyclotrimerization reaction to create highly porous cyanate resin networks with systematically varied nodes and linking struts. The chemical structures of monomers and polymers were confirmed by H-1 NMR, FTIR, solid-state C-13 CP/MAS NMR spectra, and elemental analysis. The products are amorphous with 5% weight-loss temperatures over 428 degrees C. The results based on N-2 and CO2 adsorption isotherms show that the pores in these polymers mainly locate in the microporous region, and the BET surface areas are up to 960 m(2) g(-1), which is the highest value for the porous cyanate resin reported to date. The nitrogen- and oxygen-rich characteristics of cyanate resins lead to the networks strong affinity for CO2 and thereby high CO2 adsorption capacity of 11.1 wt % at 273 K and 1.0 bar. The adsorption behaviors of H-2, CO2, benzene, n-hexane, and water vapors were investigated by correlating with the chemical composition and porosity parameters of the networks as well as the physicochemical nature of adsorbates.
• COMPOSITION FOR USE IN ORGANIC DEVICE, POLYMER FILM, AND ORGANIC ELECTROLUMINESCENT ELEMENT
  申请人：Okabe Kazuki

  公开号：US20100045174A1

  公开（公告）日：2010-02-25

  A composition for use in an organic device, useful in producing an organic device, such as an organic electroluminescent element, having high operation stability, is a composition for use in an organic device that contains at least two cross-linking compounds, at least two of the cross-linking compounds having different numbers of cross-linking groups. A polymer film produced by forming a film of the composition for use in an organic device and then polymerizing the cross-linking compounds. An organic electroluminescent element that includes an anode and a cathode on a substrate and at least one organic layer disposed between the anode and the cathode, wherein at least one of the at least one organic layer is a layer that is produced by forming a film of the composition for use in an organic device and then polymerizing the cross-linking compounds.
• Redox-controlled fluorescence modulation (electrofluorochromism) in triphenylamine derivatives
  作者：Cassandre Quinton、Valérie Alain-Rizzo、Cécile Dumas-Verdes、Fabien Miomandre、Gilles Clavier、Pierre Audebert

  DOI：10.1039/c4ra02675f

  日期：——

  The study of the chemical and electrochemical fluorescence switching properties of a family of substituted triphenylamine derivatives is reported.

  报道了对一系列取代三苯胺衍生物的化学和电化学荧光开关特性进行研究。