4-chloro-4-methyl-1-pentetne | 53875-83-5

• 分子结构分类: 有机化合物 - 有机卤素化合物 - 有机氯化物
• 英文名称: 4-chloro-4-methyl-1-pentetne
• 英文别名: 4-chloro-4-methyl-1-pentene；4-chloro-4-methyl-pent-1-ene；4-Chlor-4-methyl-pent-1-en；Dimethyl-allyl-chlormethan；4-Chloro-4-methylpent-1-ene
• CAS: 53875-83-5
• 化学式: C₆H₁₁Cl
• 分子量: 118.606
• InChiKey: LMQOCFOGQMCFNK-UHFFFAOYSA-N

物化性质

• 溶解度：
  氯仿（微溶）、己烷（微溶）

计算性质

• 辛醇/水分配系数(LogP)：
  2.5
• 重原子数：
  7
• 可旋转键数：
  2
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.67
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  4-chloro-4-methyl-1-pentetne 在 氧气 、 三乙胺 、 三氯化磷 作用下， 生成 4-chloro-4-methylpentene-2-phosphonic acid dichloride
  参考文献：
  名称：

  Gurevich, I. E.; Dogadina, A. V.; Sokolov, V. V., Journal of general chemistry of the USSR, 1992, vol. 62, # 1.1, p. 47 - 55

  摘要：

  DOI：
• 作为产物：
  描述：

  2-甲-4-戊烯-2-醇 在 五氯化磷 作用下， 生成 4-chloro-4-methyl-1-pentetne
  参考文献：
  名称：

  Saizew; Saizew, Justus Liebigs Annalen der Chemie, 1877, vol. 185, p. 156

  摘要：

  DOI：

文献信息

• Reactivities of Stable Rotamers. XXII. Lewis Acid-Catalyzed Reactions of 3-(1,4-Disubstituted 9-Triptycyl)-3-methylbutanoyl Chloride: Isolation of Rotameric Ketones and Competition between Cyclizations to Substituted and to Unsubstituted Benzene Rings
  作者：Toshimasa Tanaka、Katsumi Yonemoto、Yasufumi Nakai、Gaku Yamamoto、Michinori Oki

  DOI：10.1246/bcsj.61.3239

  日期：1988.9

  1,4-dimethyl compound afforded a ketone which was expected from cyclization to the unsubstituted benzene ring and another ketone that was derived from the ipso attack of the acylium ion followed by 1,2-methide migration. In both cases, the ketone derived from the ap form of the acid chloride was different from that obtained from the sc. The barriers to isomerization of the ap-ketone to the sc-...

  已经制备了 3-(1,4-二取代 9-三苯乙烯基)-3-甲基丁酸的旋转异构体，其中取代基是甲氧基或甲基，从 1,4-二取代 9-(1,1-二甲基-3-丁烯基）三苯乙烯。ap-酰氯的路易斯酸催化反应提供了相应的酮，这些酮是分子内弗里德尔-克拉夫茨反应所预期的。1,4-二甲氧基化合物的 sc 形式产生酮，该酮是通过未取代的苯环和内酯反应形成的，内酯是通过酰基离子对甲氧基氧的攻击，然后去甲基化而衍生的。1,4-二甲基化合物的 sc 形式提供预期来自环化到未取代苯环的酮和衍生自酰基离子的 ipso 攻击，然后是 1,2-甲基化物迁移的另一种酮。在这两种情况下，由 p 形式的酰氯衍生的酮不同于从 sc 获得的酮。ap-酮异构化为sc-的障碍
• [EN] SELECTIVE DEHYDROHALOGENATION OF TERTIARY HALOGENATED HYDROCARBONS AND REMOVAL OF TERTIARY HALOGENATED HYDROCARBON IMPURITIES<br/>[FR] DÉSHYDROHALOGÉNATION SÉLECTIVE D'HYDROCARBURES HALOGÉNÉS TERTIAIRES ET ÉLIMINATION DES IMPURETÉS CONTENUES DANS DES HYDROCARBURES HALOGÉNÉS TERTIAIRES
  申请人：DOW AGROSCIENCES LLC

  公开号：WO2010151342A1

  公开（公告）日：2010-12-29

  A process for converting a tertiary halogenated hydrocarbons in a tertiary halogenated hydrocarbon-containing stream to a corresponding unhalogenated or less-halogenated unsaturated hydrocarbon product with the release of hydrogen halide involves contacting the tertiary halogenated hydrocarbon with a sorbent- type dehydrohalogenation catalyst in a reaction zone and optionally passing a stripping gas through the reaction zone to remove vapor phase reaction products from the reaction zone. A process for removing a tertiary chlorinated hydrocarbon impurity from 1,3-dichloro-l-propene involves contacting a mixture containing the 1,3-dichloro-l -propene and the tertiary chlorinated hydrocarbon impurity with a dehydrochlorination catalyst effective to catalyze a conversion of the tertiary chlorinated hydrocarbon impurity to a corresponding unchlorinated or less- chlorinated unsaturated hydrocarbon and hydrogen chloride and distilling the 1,3- dichloro-l-propene to produce a purified cis-l,3-dichloro-l-propene fraction and a purified trans- 1,3-dichloro-l-propene fraction.

  一种将含有三级卤代碳氢化合物的流体中的三级卤代碳氢化合物转化为相应的非卤代或低卤代不饱和碳氢化合物产物，并释放氢卤素的方法涉及在反应区中将三级卤代碳氢化合物与吸附型脱卤催化剂接触，并可选择性地通过反应区通入剥离气体以从反应区中去除气相反应产物。一种从1,3-二氯-1-丙烯中去除三级氯代碳氢化合物杂质的方法涉及将含有1,3-二氯-1-丙烯和三级氯代碳氢化合物杂质的混合物与脱氯催化剂接触，以催化将三级氯代碳氢化合物杂质转化为相应的非氯代或低氯代不饱和碳氢化合物和氢氯酸，并蒸馏1,3-二氯-1-丙烯以产生纯化的顺式-1,3-二氯-1-丙烯分数和纯化的反式-1,3-二氯-1-丙烯分数。
• RESIN COMPOSITION FOR INK-JET RECORDING SHEET AND RECORDING SHEET MADE WITH THE SAME
  申请人：DAICEL CHEMICAL INDUSTRIES, Ltd.

  公开号：EP1114734A1

  公开（公告）日：2001-07-11

  The present invention Nos. I-VII are a resin composition for an ink-jet recording sheet for constructing an image-receiving layer which is formed on at least one surface of a base material for an ink-jet recording sheet. The present invention No. I relates to a resin composition for an ink-jet recording sheet which comprises (1) 2-80% by mass of a cationic acrylic copolymer (A) having a crosslinkable group, (2) 5-80% by mass of a saponified product (B) of a vinyl acetate-based copolymer having a polymerization degree of 200-1000, and (3) 0-80% by mass of a modifier (R), the present invention No. II relates to a resin composition for an ink-jet recording sheet which contains (1) 2-80 wt% of a cationic acrylic copolymer (A) having a crosslinkable group, (2) 5-80 wt% of a saponified product (B) of a vinyl acetate-based copolymer, (3) (n1-80) wt% of a water-based polyurethane resin (C), (4) (n2-60) wt% of a polyurethane-based graft polymer mixture (D), and (5) (n3-60) wt% of a polyester-based graft polymer mixture (E) in a solid content-based ratio, and total is 100 wt%, in which there are satisfied conditions that a minimum value in n1, n2, and n3 is 0, and (n1+n2+n3) is ≥5, the present invention No. III relates to a resin composition for an ink-jet recording sheet which comprises, [1] 2-80% by weight of a cationic acrylic copolymer (A) having a crosslinkable group, [2] 5-60% by weight of a saponified product (B) of a vinyl acetate-based copolymer, and [3] 0-80% by weight of a water-based polyurethane resin (C) total of the (A), (B), and (C) is 100% by weight}, and [4] 0.05-10 parts by weight of a block isocyanate compound (F) based on 100 parts by weight of the saponified product (B) of a vinyl acetate-based copolymer, the present invention No. IV relates to a resin composition for an ink-jet recording sheet which comprises the use of 2-100% by weight of a cationic acrylic copolymer (A) composed of a monomer having an alkylene oxide group, a monomer having a hydrophilic group, a monomer having a crosslinkable group, a monomer containing cationic group, 0-90% by weight of a saponified product (B) of a vinyl acetate-based copolymer, and 5-60% by weight of a modifier (R), and an image-receiving layer is formed over at least one surface, the present invention No. V relates to a resin composition for an ink-jet recording sheet which comprises formulating 70-100% by weight of a cationic (meth)acrylic polymer (A) in which there are copolymerized a cationic (meth)acrylate monomer having a polyalkylene oxide group, a monomer having a hydrophilic group, a monomer having a crosslinkable group, a monomer containing cationic group, and a cationic monomer, 0-30% by weight of a saponified product (B) of a vinyl acetate-based copolymer (total thereof is 100% by weight), and 0-15 parts by weight of a modifier (R) based on 100 parts by weight of the (A) and the (B), the present invention No. VI relates to an ink-jet recording sheet which comprises being constructed by a composition containing a (meth)acrylic-based copolymer having a hydrolyzable silyl group in which a polymerizable unsaturated monomer having a hydrolyzable silyl group is copolymerized with monomers containing a (meth)acrylate-based polymerizable unsaturated monomer, and inorganic compound fine particles, the present invention No. VII relates to a resin composition for an ink-jet recording sheet characterized by containing 100 parts by weight of a resin composition composed of (1) 1-30% by weight of a cellulose derivative (A) and (2) 70-99% by weight of a good solvent (B) for the cellulose derivative (total is 100% by weight), (3) 0.1-20 parts by weight of an organic acid (C) which can dissolve in the good solvent (B) or a weak solvent (D) for the cellulose derivative, and optionally, (4) 0-150 parts by weight of a weak solvent (D) for the cellulose derivative, and relates to a recording sheet in which an image-receiving layer is formed on a body to be recorded composed of the resin composition. the present invention No. VIII is to provide a heat transfer sheet which is excellent in an ink-absorbing ability, an ink-fixing ability, and a printing ability in the case of molding into the heat transfer sheet, and which is high in a water resistance, durability, particularly, micro cracks resistance of a recorded picture, and in which an ink-receiving layer is formed on an elastic material, and micro cracks are not caused even though the recorded picture is expanded and shrunk, and a resin composition for constructing thereof, a resin composition containing a polymer (A) containing a monomer unit shown by a specified formula (1) and a hot-melt adhesive resin (B), a heat transfer sheet comprised the resin composition, and a method for the preparation thereof.

  本发明第I-VII号是一种喷墨记录薄片用树脂组合物，用于在喷墨记录薄片基材的至少一个表面上形成图像接收层。 本发明 I 涉及一种用于喷墨记录薄片的树脂组合物，该树脂组合物包括：(1) 2-80% （质量百分比）具有可交联基团的阳离子丙烯酸共聚物 (A)；(2) 5-80% （质量百分比）聚合度为 200-1000 的醋酸乙烯酯基共聚物的皂化产物 (B)；(3) 0-80% （质量百分比）改性剂 (R)、 本发明第II 涉及一种用于喷墨记录片材的树脂组合物，它含有 (1) 2-80 wt%的具有可交联基团的阳离子丙烯酸共聚物 (A)，(2) 5-80 wt%的醋酸乙烯酯基共聚物的皂化产物 (B)，(3) (n1-80) wt%的水基聚氨酯树脂 (C)、(4)(n2-60)重量％的聚氨酯基接枝聚合物混合物(D)，和(5)(n3-60)重量％的聚酯基接枝聚合物混合物(E)，以固含量为基础的比例，总计为100重量％，其中满足的条件是n1、n2和n3中的最小值为0，且(n1+n2+n3)≥5、 本发明 III 号涉及一种用于喷墨记录片材的树脂组合物，它包括：[1] 2-80% （重量比）具有可交联基团的阳离子丙烯酸共聚物 (A)、 [2] 5-60% （重量百分比）醋酸乙烯共聚物的皂化产品 (B)，以及 [3] 0-80%（重量）的水性聚氨酯树脂（C）(A)、(B)和(C)的总和为 100%（重量）}，以及 [4] 以 100 份醋酸乙烯酯基共聚物的皂化产物（B）为基数，加入 0.05-10 份 （重量）的嵌段异氰酸酯化合物（F）、 本发明 No.IV涉及一种用于喷墨记录片材的树脂组合物，它包括使用 2-100%（重量）的阳离子丙烯酸共聚物（A），该共聚物由具有环氧烷基的单体、具有亲水基团的单体、具有可交联基团的单体、含有阳离子基团的单体、0-90%（重量）的醋酸乙烯酯基共聚物的皂化产物（B）和 5-60%（重量）的改性剂（R）组成，并在至少一个表面上形成图像接收层、 本发明第V 涉及一种用于喷墨记录片材的树脂组合物，它包括配制 70-100% （重量）的阳离子（甲基）丙烯酸聚合物 (A)，其中共聚有一个具有聚氧化亚烷基的阳离子（甲基）丙烯酸酯单体、一个具有亲水基团的单体、具有可交联基团的单体、含有阳离子基团的单体和阳离子单体，0-30%（重量）的醋酸乙烯酯基共聚物的皂化产物（B）（其总重量为 100%（重量）），以及 0-15 份（重量）的改性剂（R）（以 100 份（重量）的（A）和（B）为基准）、 本发明之六涉及一种喷墨记录片材，其包括由含有可水解硅烷基的(甲基)丙烯酸基共聚物的组合物构成，在该组合物中，具有可水解硅烷基的可聚合不饱和单体与含有(甲基)丙烯酸基可聚合不饱和单体的单体共聚，以及无机化合物细颗粒、 本发明第 VII 号涉及一种用于喷墨记录片材的树脂组合物，其特征在于含有 100 份(重量)的树脂组合物，其组成为(1)1-30%(重量)的纤维素衍生物(A)和(2)70-99%(重量)的纤维素衍生物的良好溶剂(B)(总计为 100%(重量))，(3)0.1-20份(重量)能溶解在纤维素衍生物的良好溶剂(B)或弱溶剂(D)中的有机酸(C)，以及任选地，(4)0-150份(重量)纤维素衍生物的弱溶剂(D)，并涉及一种在由树脂组合物构成的待记录体上形成图像接收层的记录片材。 本发明的第VIII 是要提供一种热转印片材，它在模压成热转印片材的情况下具有优异的吸墨能力、固墨能力和印刷能力，并具有较高的耐水性、耐久性，特别是记录图像的抗微裂纹能力，而且其中的受墨层是在弹性材料上形成的、以及用于构建这种材料的树脂组合物、含有指定式（1）所示单体单元的聚合物（A）和热熔粘合剂树脂（B）的树脂组合物、由该树脂组合物构成的热转印片材及其制备方法。
• COATING COMPOSITION FOR INK-JET RECORDING MEDIUM AND INK-JET RECORDING MEDIUM
  申请人：Clariant International Ltd.

  公开号：EP1470928A1

  公开（公告）日：2004-10-27

  The present invention relates to a coating composition for an ink jet recording medium comprising a synthetic resin emulsion having a particle diameter of 100 nm or less and colloidal silica, said synthetic resin emulsion being obtained by, in the presence of (A) an emulsifier containing a radical-polymerizable emulsifier having a sulfonic acid group, emulsion-polymerizing (B) an unsaturated monomer having a silyl group and (C) an unsaturated monomer having a six-membered ring as a side chain and, optionally, (D) another radical-polymerizable unsaturated monomer which is copolymerizable with (B) and (C).

  本发明涉及一种用于喷墨记录介质的涂料组合物，该组合物包含粒径为 100 nm 或更小的合成树脂乳液和胶体二氧化硅，所述合成树脂乳液是通过以下方法获得的：(A) 含有磺酸基团的可自由基聚合乳化剂的乳化剂、乳液聚合(B) 具有硅基的不饱和单体和(C) 具有六元环作为侧链的不饱和单体，以及(D) 可与(B)和(C)共聚的另一种可自由基聚合的不饱和单体。
• Selective dehydrohalogenation of tertiary halogenated hydrocarbons and removal of tertiary halogenated hydrocarbon impurities
  申请人：Dow AgroSciences LLC

  公开号：EP2789599A1

  公开（公告）日：2014-10-15

  A method for removing a tertiary halogenated hydrocarbon impurity from a target hydrocarbon compound, comprising: providing a first mixture comprising the target hydrocarbon compound and a tertiary halogenated hydrocarbon impurity; contacting the first mixture containing the tertiary halogenated hydrocarbon impurity with a dehydrohalogenation catalyst effective to catalyze a conversion of the tertiary halogenated hydrocarbon impurity to a corresponding unhalogenated or less-halogenated unsaturated hydrocarbon and hydrogen halide, thereby providing a modified mixture, the dehydrohalogenation catalyst comprising a sorbent that includes silicon oxide, aluminum oxide or both silicon oxide and aluminum oxide; and distilling the modified mixture to separate and recover a purified target hydrocarbon compound.

  一种从目标烃化合物中去除叔卤代烃杂质的方法，包括提供包含目标烃化合物和叔卤代烃杂质的第一混合物；将含有三级卤代烃杂质的第一混合物与一种脱氢卤化催化剂接触，该催化剂能有效催化三级卤代烃杂质向相应的非卤代或少卤代不饱和烃和卤化氢的转化，从而提供一种改性混合物，脱氢卤化催化剂包括一种吸附剂，该吸附剂包括氧化硅、氧化铝或同时包括氧化硅和氧化铝；以及蒸馏改性混合物以分离和回收纯化的目标烃化合物。