1,10-bis(triethylammonium)decane dibromide | 51523-41-2

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: 1,10-bis(triethylammonium)decane dibromide
• 英文别名: 1,10-bis(triethylammonio)decane dibromide；hexa-N-ethyl-N,N'-decanediyl-di-ammonium; dibromide；Hexa-N-aethyl-N,N'-decandiyl-di-ammonium; Dibromid；N,N,N,N',N',N'-hexaethyl-1,10-decanediaminium dibromide；triethyl-[10-(triethylazaniumyl)decyl]azanium;bromide
• CAS: 51523-41-2
• 化学式: 2Br*C₂₂H₅₀N₂
• 分子量: 502.46
• InChiKey: DDBZPDDMMQMTCI-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  2.86
• 重原子数：
  25
• 可旋转键数：
  17
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  1,10-二溴癸烷 、 三乙胺 以 乙腈 为溶剂， 反应 12.0h， 生成 1,10-bis(triethylammonium)decane dibromide
  参考文献：
  名称：

  两亲性分子对SAPO-34分子筛微观结构和中/宏观结构的影响

  摘要：

  SAPO-34是分子筛家族中的重要成员，它在MTO反应中显示出出色的催化活性，但存在扩散瓶颈。为克服扩散问题，添加了致孔剂以在SAPO-34沸石中产生细孔/大孔。在这项工作中，将两亲性分子设计为CSDA，以合成三级层次多孔SAPO-34，并且CSDA的引入可以促进Si原子掺入AlPO 4骨架，改变颗粒的形态并降低所制备的酸度。 SAPO-34沸石。制备的SAPO-34催化剂对C 2 H 4和C 3 H 6的选择性更高在MTO反应中比传统的SAPO-34沸石要好。由于两亲分子与CHA的拓扑结构之间的匹配，所制备样品的形态和微观结构随两亲分子的碳链而变化。

  DOI：

  10.1002/cctc.202000794

文献信息

• Barlow; Ing, British Journal of Pharmacology and Chemotherapy, 1948, vol. 3, p. 300
  作者：Barlow、Ing

  DOI：——

  日期：——
• Host−Guest Complexes and Pseudorotaxanes of Cucurbit[7]uril with Acetylcholinesterase Inhibitors
  作者：Ian W. Wyman、Donal H. Macartney

  DOI：10.1021/jo901861e

  日期：2009.11.6

  Pseudorotaxanes may be assembled in aqueous solution using dicationic acetylcholinesterase inhibitors, such as succinylcholine, BW284c51, and alpha,omega-bis(trialkylammonium)alkane dications (or their phosphonium analogues), its bolaform axles and cucurbit[7]uril (CB[7]) as the wheel. With the exceptions of the shorter [(CH3)(3)N(CH2)(n)N(CH3)(3)](2+) (n = 6, 8) dications, the addition of it second CB[7] results in the translocation of the First CB[7], Such that the hydrophobic -NR3+ and -PR3+ end groups (R = Me or Et) are located in the cavities of the wheels, while the central portion of the axles extend through the CB[7] portals into the bulk solvent. In the case of the [Quin(CH2)(10)Quin](2+) (Quin = quinuclidinium) dication, the CB[7] host(s) resides only on the quinuclidinium end group(s). The 1.1 host-guest stability constants range from 8 x 10(6) to 3 x 10(10) M-1 and are dependent oil both the nature of the end group as well its the length and hydrophobicity of the central linker. The magnitude of the stability constants for the 2.1 complexes closely follow the trend observed previously for CB[7] binding with the NR4+ and PR4+ cations.
• Affecting the Formation of the Micro‐structure and Meso/macro‐structure of SAPO‐34 zeolite by Amphipathic Molecules
  作者：Xuefeng Shen、Yujue Du、Jiajia Ding、Chuanming Wang、Hongxing Liu、Weimin Yang、Zaiku Xie

  DOI：10.1002/cctc.202000794

  日期：2020.10.6

  SAPO‐34 is an important member in the family of zeolites, which shows excellent catalytic activity in MTO reaction, but suffers from the diffusion bottleneck. To overcome the diffusion problem, porogen was added to generate meso/macro pores in SAPO‐34 zeolite. In this work, amphipathic molecules were designed as CSDA to synthesize a tri‐level hierarchically porous SAPO‐34, and the introduction of CSDA

  SAPO-34是分子筛家族中的重要成员，它在MTO反应中显示出出色的催化活性，但存在扩散瓶颈。为克服扩散问题，添加了致孔剂以在SAPO-34沸石中产生细孔/大孔。在这项工作中，将两亲性分子设计为CSDA，以合成三级层次多孔SAPO-34，并且CSDA的引入可以促进Si原子掺入AlPO 4骨架，改变颗粒的形态并降低所制备的酸度。 SAPO-34沸石。制备的SAPO-34催化剂对C 2 H 4和C 3 H 6的选择性更高在MTO反应中比传统的SAPO-34沸石要好。由于两亲分子与CHA的拓扑结构之间的匹配，所制备样品的形态和微观结构随两亲分子的碳链而变化。