1,1-Diallyl-2,5-bis-(chloromethyl-dimethyl-silanyl)-3,4-diphenyl-1H-silole | 213009-78-0

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 二苯乙烯类
• 英文名称: 1,1-Diallyl-2,5-bis-(chloromethyl-dimethyl-silanyl)-3,4-diphenyl-1H-silole
• CAS: 213009-78-0
• 化学式: C₂₈H₃₆Cl₂Si₃
• 分子量: 527.756
• InChiKey: RMONAWDAWHUMFP-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  8.86
• 重原子数：
  33.0
• 可旋转键数：
  10.0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.29
• 拓扑面积：
  0.0
• 氢给体数：
  0.0
• 氢受体数：
  0.0

反应信息

• 作为反应物：
  描述：

  1,1-Diallyl-2,5-bis-(chloromethyl-dimethyl-silanyl)-3,4-diphenyl-1H-silole 在 偶氮二异丁腈 、 三正丁基氢锡 、 sodium iodide 作用下， 以 丁酮 、 苯 为溶剂， 反应 38.0h， 生成 6,6,11,11-Tetramethyl-8,9-diphenyl-1,6,11-trisila-tricyclo[8.5.0.0^1,7]pentadeca-7,9-diene
  参考文献：
  名称：

  A bridged spiro[6.6]silatridecane via double 7-endo radical cyclisation

  摘要：

  The double intramolecular radical induced reaction of 5 gives in a highly regioselective reaction via a 7-endo mode the tricyclic silaalkane 7 in 42% yield. In addition. The bicyclic trisilane 8 also formed by a 7-endo cyclisation, is obtained in 33% yield. The structure of 7 has been confirmed by X-ray structure analysis. (C) 1998 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0040-4020(98)00620-6
• 作为产物：
  描述：

  氯甲基二甲基氯硅烷 、 di-phenylethynyl-diallylsilane 在 LiC₁₀H₈ 作用下， 生成 1,1-Diallyl-2,5-bis-(chloromethyl-dimethyl-silanyl)-3,4-diphenyl-1H-silole
  参考文献：
  名称：

  A bridged spiro[6.6]silatridecane via double 7-endo radical cyclisation

  摘要：

  The double intramolecular radical induced reaction of 5 gives in a highly regioselective reaction via a 7-endo mode the tricyclic silaalkane 7 in 42% yield. In addition. The bicyclic trisilane 8 also formed by a 7-endo cyclisation, is obtained in 33% yield. The structure of 7 has been confirmed by X-ray structure analysis. (C) 1998 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0040-4020(98)00620-6

文献信息

• A bridged spiro[6.6]silatridecane via double 7-endo radical cyclisation
  作者：Zhu Teng、Reinhart Keese、Helen Stoeckli-Evans

  DOI：10.1016/s0040-4020(98)00620-6

  日期：1998.9

  The double intramolecular radical induced reaction of 5 gives in a highly regioselective reaction via a 7-endo mode the tricyclic silaalkane 7 in 42% yield. In addition. The bicyclic trisilane 8 also formed by a 7-endo cyclisation, is obtained in 33% yield. The structure of 7 has been confirmed by X-ray structure analysis. (C) 1998 Elsevier Science Ltd. All rights reserved.