8-(methylsulfanyl)acenaphtho[1,2-j]fluoranthene-7-carbonitrile | 1225222-98-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: 8-(methylsulfanyl)acenaphtho[1,2-j]fluoranthene-7-carbonitrile
• 英文别名: 15-Methylsulfanylheptacyclo[15.7.1.14,8.02,16.03,13.021,25.012,26]hexacosa-1(24),2,4,6,8(26),9,11,13,15,17,19,21(25),22-tridecaene-14-carbonitrile
• CAS: 1225222-98-9
• 化学式: C₂₈H₁₅NS
• 分子量: 397.5
• InChiKey: ABQRZENBGXGDMA-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7.3
• 重原子数：
  30
• 可旋转键数：
  1
• 环数：
  7.0
• sp3杂化的碳原子比例：
  0.04
• 拓扑面积：
  49.1
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  10-(methylsulfanyl)-8-oxo-8H-7-oxafluoranthene-9-carbonitrile 、 1-苊酮 在 sodium hydride 作用下， 以 四氢呋喃 、 mineral oil 为溶剂， 反应 0.42h， 以54%的产率得到8-(methylsulfanyl)acenaphtho[1,2-j]fluoranthene-7-carbonitrile
  参考文献：
  名称：

  Synthesis, Electrochemical and Optical Properties of Stable Yellow Fluorescent Fluoranthenes

  摘要：

  A novel series of thermally stable yellow light emitting fluoranthenes with an amine donor and a nitrite acceptor was prepared from a ketene-S,S-acetal under mild conditions without using an organometal catalyst. The organic light emitting device of yellow fluoranthene 10b exhibited substantially low turn-on voltage (2.6 V) and maximum brightness of 470 Cd/m(2) with luminance efficiency of 2.0 Cd/A without using any dopant.

  DOI：

  10.1021/jo100420x

文献信息

• Synthesis, Electrochemical and Optical Properties of Stable Yellow Fluorescent Fluoranthenes
  作者：Atul Goel、Vijay Kumar、Sumit Chaurasia、Madhu Rawat、Ramesh Prasad、R. S. Anand

  DOI：10.1021/jo100420x

  日期：2010.6.4

  A novel series of thermally stable yellow light emitting fluoranthenes with an amine donor and a nitrite acceptor was prepared from a ketene-S,S-acetal under mild conditions without using an organometal catalyst. The organic light emitting device of yellow fluoranthene 10b exhibited substantially low turn-on voltage (2.6 V) and maximum brightness of 470 Cd/m(2) with luminance efficiency of 2.0 Cd/A without using any dopant.