1,7-Bis-(1-hydroxy-2,2,6,6-tetramethylpiperidin-4-yl)1,4,7-triazaheptane | 330445-35-7

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 哌啶类
• 英文名称: 1,7-Bis-(1-hydroxy-2,2,6,6-tetramethylpiperidin-4-yl)1,4,7-triazaheptane
• 英文别名: 1,7-Bis-(1-hydroxy-2,2,6,6-tetramethylpiperidin-4yl)1,4,7-triazaheptane；N'-(1-hydroxy-2,2,6,6-tetramethylpiperidin-4-yl)-N-[2-[(1-hydroxy-2,2,6,6-tetramethylpiperidin-4-yl)amino]ethyl]ethane-1,2-diamine
• CAS: 330445-35-7
• 化学式: C₂₂H₄₇N₅O₂
• 分子量: 413.647
• InChiKey: HPZAHJSROJUAMW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.6
• 重原子数：
  29
• 可旋转键数：
  8
• 环数：
  2.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  83
• 氢给体数：
  5
• 氢受体数：
  7

反应信息

• 作为产物：
  描述：

  4-氧-2,2,6,6-四甲基哌啶-1-氧自由基 、 二乙烯三胺 在 Pd on carbon 作用下， 以 甲醇 为溶剂， 生成 1,7-Bis-(1-hydroxy-2,2,6,6-tetramethylpiperidin-4-yl)1,4,7-triazaheptane
  参考文献：
  名称：

  CHLOROHYDRIN AND CATIONIC COMPOUNDS HAVING HIGH AFFINITY FOR PULP OR PAPER

  摘要：

  公开号：

  EP1212486B1

文献信息

• Chlorohydrin and cationic compounds having high affinity for pulp or paper
  申请人：Cunkle T. Glen

  公开号：US20050092452A1

  公开（公告）日：2005-05-05

  Selected chlorohydrin and cationic compounds containing nitroxide or hydroxylamine moieties are effective in stabilizing pulp or paper, especially pulp or paper containing lignin, against yellowing and discoloration due to the adverse effects of light. These compounds are added at various points in the paper-making process, especially at the wet ends, making the need for water soluble or water dispersible materials having high affinity for pulp or paper essential. This performance is often further enhanced by the presence of one or more coadditives selected from the group consisting of the UV absorbers, the polymeric inhibitors, the nitrones, the fluorescent whitening agents and metal chelating agents. Combinations of hydroxylamines or their salts, benzotriazole or benzophenone UV absorbers and a metal chelating agent are particularly effective.

  选择的含氮氧自由基或羟胺基团的氯水合物和阳离子化合物对于稳定纸浆或纸张，特别是含有木质素的纸浆或纸张，抵御光的不良影响导致的黄变和变色非常有效。这些化合物在造纸过程的各个阶段添加，特别是在湿端，需要具有高亲和力的水溶性或水分散材料是必不可少的。这种性能通常通过存在于紫外线吸收剂、聚合物抑制剂、亚硝基、荧光增白剂和金属螯合剂等组中选择一个或多个共添加剂来进一步增强。羟胺或其盐、苯并三唑或苯并酮紫外线吸收剂和金属螯合剂的组合特别有效。
• Polymeric stabilizers with high affinity to pulp
  申请人：Ciba Specialty Chemicals Corporation

  公开号：US06416627B1

  公开（公告）日：2002-07-09

  Selected polymeric stabilizers with pendant nitroxide, hydroxylamine or hydroxy-ammonium salt groups B are water soluble or water dispersible and have high affinity to pulp or paper. These stabilizers prevent the loss of brightness and enhance resistance to yellowing in pulp or paper, especially pulp or paper containing lignin. These compounds are added at various points in the paper-making process, especially at the wet ends, making the need for water soluble or water dispersible materials having high affinity for pulp or paper essential. This performance is often further enhanced by the presence of one or more coadditives selected from the group consisting of the UV absorbers, the polymeric inhibitors, the nitrones, the fluorescent whitening agents and metal chelating agents. Combinations of hydroxylamines or their salts, benzotriazole or benzophenone UV absorbers and a metal chelating agent are particularly effective.

  具有偏氮氧自由基、羟胺或羟基铵盐基团的聚合物稳定剂B是水溶性或水分散性的，并且具有高亲和力，可以防止漂白度的损失和增强含有木质素的纸浆或纸张的抗黄化性能。这些化合物可以在造纸过程的不同阶段添加，特别是在湿端，因此需要具有高亲和力的水溶性或水分散性材料是必不可少的。这种性能通常通过与紫外线吸收剂、聚合抑制剂、亚硝基化合物、荧光增白剂和金属螯合剂等共同添加剂之一或多个的存在而进一步增强。羟胺或其盐、苯并三唑或苯并酚紫外线吸收剂和金属螯合剂的组合特别有效。
• POLYMERIC STABILIZERS WITH HIGH AFFINITY TO PULP
  申请人：Ciba Specialty Chemicals Holding Inc.

  公开号：EP1216269B1

  公开（公告）日：2003-10-29
• US6416627B1
  申请人：——

  公开号：US6416627B1

  公开（公告）日：2002-07-09
• US6989449B1
  申请人：——

  公开号：US6989449B1

  公开（公告）日：2006-01-24