3,3'-(1,2-phenylene)bis-1,5,3-dithiazepinane | 1408077-08-6

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: 3,3'-(1,2-phenylene)bis-1,5,3-dithiazepinane
• 英文别名: 3,3'-(1,2-phenylene)bis-1,5,3-dithiazepane；3,3'-(1,2-Phenylene)bis-1,5,3-dithiazepane；3-[2-(1,5,3-dithiazepan-3-yl)phenyl]-1,5,3-dithiazepane
• CAS: 1408077-08-6
• 化学式: C₁₄H₂₀N₂S₄
• 分子量: 344.59
• InChiKey: LTOZBIRLNZVASS-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.7
• 重原子数：
  20
• 可旋转键数：
  2
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.57
• 拓扑面积：
  108
• 氢给体数：
  0
• 氢受体数：
  6

反应信息

• 作为产物：
  描述：

  邻苯二胺 、 3-(tert-butyl)perhydro-1,5,3-dithiazepine 在 samarium(III) nitrate hexahydrate 作用下， 以 氯仿 为溶剂， 反应 3.5h， 以43%的产率得到3,3'-(1,2-phenylene)bis-1,5,3-dithiazepinane
  参考文献：
  名称：

  Effective synthesis of N-aryl-substituted 1,5,3-dithiazepinanes and 1,5,3-dithiazocinanes

  摘要：

  Selective methods were developed for the synthesis of N-aryl-1,5,3-dithiazepinanes and N-aryl-1,5,3-dithiazocinanes by transamination of N-tert-butyl-1,5,3-dithiazepinane or recyclization of 1-oxa-3,6-dithiacycloheptane and 1-oxa-3,7-dithiacyclooctane by the action of aniline derivatives in the presence of Sm(NO3)(3)center dot 6H(2)O catalyst.

  DOI：

  10.1007/s10593-012-1098-8

文献信息

• Multicomponent cyclothiomethylation of phenylenediamines and 4,4'-diaminodiphenyls with formaldehyde and 1,2-ethanedithiol
  作者：G. R. Khabibullina、E. S. Fedotova、G. R. Anpilogova、V. R. Akhmetova、A. G. Ibragimov

  DOI：10.1134/s1070363216070124

  日期：2016.7

  o-phenylenediamine, 4,4'-diaminodiphenyl, 4,4'-diaminodiphenyl oxide, and 4,4'-diaminodiphenylmethane with formaldehyde and 1,2- ethanedithiol was performed. Sorption properties of the newly synthesized bis[4-(1,5,3-dithiazepan-3-yl)-phenyl] oxide were investigated by the batch technique. High efficiency of the recovery of palladium(II) with this reagent from hydrochloric acid solutions at room temperature

  通过邻苯二胺，4,4'-二氨基二苯基，4,4'-二氨基二苯甲烷和4,4'-二氨基二苯甲烷与甲醛和1,2-的环硫甲基化一锅合成bis-1,5,3-二硫杂二氮卓进行乙二硫醇。通过分批技术研究了新合成的双[4-（1,5,3-二硫杂庚烷-3-基）-苯基]氧化物的吸附性能。在室温下用该试剂从盐酸溶液中回收钯（II）的效率很高。
• Effective synthesis of N-aryl-substituted 1,5,3-dithiazepinanes and 1,5,3-dithiazocinanes
  作者：E. B. Rakhimova、I. V. Vasil’yeva、L. M. Khalilov、A. G. Ibragimov、U. M. Dzhemilev

  DOI：10.1007/s10593-012-1098-8

  日期：2012.10

  Selective methods were developed for the synthesis of N-aryl-1,5,3-dithiazepinanes and N-aryl-1,5,3-dithiazocinanes by transamination of N-tert-butyl-1,5,3-dithiazepinane or recyclization of 1-oxa-3,6-dithiacycloheptane and 1-oxa-3,7-dithiacyclooctane by the action of aniline derivatives in the presence of Sm(NO3)(3)center dot 6H(2)O catalyst.