N,N,N'-Trimethyl-N'-hexadecylethylene diamine | 150433-28-6

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: N,N,N'-Trimethyl-N'-hexadecylethylene diamine
• 英文别名: N,N,N'-trimethyl-N'-hexadecylethylenediamine；N,N,N'-trimethyl-N'-cetylethylenediamine；N-hexadecyl-N,N',N'-trimethyl-ethylenediamine；N-Hexadecyl-N,N',N'-trimethyl-aethylendiamin；N~1~-hexadecyl-N~1~,N~2~,N~2~-trimethyl-1,2-ethanediamine；N'-hexadecyl-N,N,N'-trimethylethane-1,2-diamine
• CAS: 150433-28-6
• 化学式: C₂₁H₄₆N₂
• 分子量: 326.61
• InChiKey: NHVAOQDNTIYRSX-UHFFFAOYSA-N

物化性质

• 沸点：
  379.5±10.0 °C(Predicted)
• 密度：
  0.838±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  8.1
• 重原子数：
  23
• 可旋转键数：
  18
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  6.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  双(乙腈)氯化钯(II) 、 N,N,N'-Trimethyl-N'-hexadecylethylene diamine 以 二氯甲烷 为溶剂， 以45.9%的产率得到[PdCl2(N,N,N'-trimethyl-N'-cetylethylenediamine)]
  参考文献：
  名称：

  Preparation of palladium(II) complexes with long alkyl chain ligand incorporated in micelle

  摘要：

  Three palladium(II) complexes with a bidentate nitrogen ligand having a long alkyl chain (1, [PdCl2(C-8-tmen)], C-8-tmen = N,N,N'-trimethyl-N'-octylethylenediamine; 2, [PdCl2(C-16-tmen)], C-16-tmen = N,N,N'-trimethyl-N'-cetylethylenediamine; 3, [PdCl2(C-8-bpy)], C-8-bpy = 4-octyl-2,2'-bipyridine) were prepared. Addition of 1 to an aqueous solution of cetyltrimethylammonium bromide gave a metallomicelle containing the Pd(II) complex (1A). The other palladium complexes (2 and 3) were not incorporated into the CTABr micelle due to the unsuitable matching between the ligand and the micelle. 1A showed good catalytic performance for Suzuki and Heck coupling reactions in water. The catalyst system for the Heck reaction in water was reusable. (C) 2012 Elsevier B. V. All rights reserved.

  DOI：

  10.1016/j.ica.2012.05.015
• 作为产物：
  描述：

  N-甲基-1-十六烷胺 、 2-氯-N,N-二甲基乙胺 在 xylene 作用下， 生成 N,N,N'-Trimethyl-N'-hexadecylethylene diamine
  参考文献：
  名称：

  Derivatives of Dimethylaminoethanol and Dimethylaminoethylamine

  摘要：

  DOI：

  10.1021/ja01125a050
• 作为试剂：
  描述：

  十六烷基(4-硝基苯基)磷酸氢盐 在 uranyl N,N,N'-Trimethyl-N'-hexadecylethylene diamine 、 水 作用下， 生成 对硝基苯酚 、 1-十六烷醇
  参考文献：
  名称：

  Actinide (uranyl) hydrolysis of phosphodiesters

  摘要：

  在弱酸性水溶液（pH 值为 4.9）中，铀（UO 2 2+ ）阳离子介导聚合和非聚合对硝基苯磷二酯的水解，在 37 °C条件下，速率增强大于 1000。

  DOI：

  10.1039/a700260b

文献信息

• Adamantylamine/long chain alkylamine catalysts and use in paraffin-olefin alkylation process
  申请人：EXXON RESEARCH AND ENGINEERING COMPANY

  公开号：EP0139504A1

  公开（公告）日：1985-05-02

  A process and new surfactant/hydride transfer catalyst compositions are described for paraffin-olefin alkylation under strong acid conditions in which a mixture of one or more adamantane derivatives and one or more surfactants are used to substantially improve the efficiency of reaction while significantly minimizing cracking side reactions.

  描述了一种在强酸条件下进行石蜡-烯烃烷基化的工艺和新型表面活性剂/氢转移催化剂组合物，其中使用了一种或多种金刚烷衍生物和一种或多种表面活性剂的混合物，以大幅提高反应效率，同时显著减少裂解副反应。
• METHODS FOR REDUCING VOID FORMATION UPON CURING OF ADHESIVE FORMULATIONS AND COMPOSITIONS USEFUL THEREFOR
  申请人：——

  公开号：US20020062923A1

  公开（公告）日：2002-05-30

  In accordance with the present invention, adhesive formulations have been developed which enable curing of adhesively bonded assemblies (i.e., assemblies which comprise devices which have been adhesively bonded to substrates) with dramatically reduced occurrence of void formation upon curing. In many instances, void formation can be eliminated employing invention compositions. In accordance with another aspect of the present invention, methods employing the above-described adhesive formulations are also provided, as are substantially void-free articles produced thereby.

  根据本发明，已开发出粘合剂配方，可使粘合剂粘合的组件（即由已粘合到基底的装置组成的组件）在固化时显著减少空隙的形成。在许多情况下，使用本发明组合物可以消除空隙形成。根据本发明的另一个方面，还提供了采用上述粘合剂配方的方法，以及由此生产的基本上无空隙的制品。
• Broxton, Trevor J.; Cox, Robin A., Canadian Journal of Chemistry, 1993, vol. 71, # 5, p. 670 - 673
  作者：Broxton, Trevor J.、Cox, Robin A.

  DOI：——

  日期：——
• US4560825A
  申请人：——

  公开号：US4560825A

  公开（公告）日：1985-12-24
• US5646241A
  申请人：——

  公开号：US5646241A

  公开（公告）日：1997-07-08