N,N',N''-trimethyl-N,N',N''-triphenyl-[1,3,5]triazine-2,4,6-triamine | 17377-14-9

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: N,N',N''-trimethyl-N,N',N''-triphenyl-[1,3,5]triazine-2,4,6-triamine
• 英文别名: N²,N⁴,N⁶-trimethyl-N²,N⁴,N⁶-triphenyl-[1,3,5]triazine-2,4,6-triyltriamine；N²,N⁴,N⁶-Trimethyl-N²,N⁴,N⁶-triphenyl-[1,3,5]triazin-2,4,6-triyltriamin；2,4,6-Tris--1,3,5-triazin；2.4.6-Tris--1.3.5-triazin；2,3,6-Tris--s-triazin；2-N,4-N,6-N-trimethyl-2-N,4-N,6-N-triphenyl-1,3,5-triazine-2,4,6-triamine
• CAS: 17377-14-9
• 化学式: C₂₄H₂₄N₆
• 分子量: 396.495
• InChiKey: LGSUGIFRAVRFNM-UHFFFAOYSA-N

物化性质

• 熔点：
  117.5 °C
• 沸点：
  575.3±33.0 °C(Predicted)
• 密度：
  1.228±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  6
• 重原子数：
  30
• 可旋转键数：
  6
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.12
• 拓扑面积：
  48.4
• 氢给体数：
  0
• 氢受体数：
  6

反应信息

• 作为产物：
  描述：

  methyl(phenyl)cyanamide 以77%的产率得到
  参考文献：
  名称：

  KORSHAK V. V.; PANKRATOV V. A.; SHUKUROV G. I.; KUTEPOV D. F., IZV. AN CCCP. CEP. XIM., 1981, HO 3, 681-682

  摘要：

  DOI：

文献信息

• The umpolung of substituent effect in nucleophilic aromatic substitution. A new approach to the synthesis of N,N-disubstituted melamines (triazine triskelions) under mild reaction conditions
  作者：Beata Kolesinska、Zbigniew J. Kaminski

  DOI：10.1016/j.tet.2009.03.017

  日期：2009.5

  By the umpolung of substituent effect 1,3,5-triazines substituted with three dialkylamino groups were prepared under mild reaction conditions by treatment of cyanuric chloride with tertiary amines. Quaternary N-triazinylammonium salts were identified as reactive intermediates activating the triazine ring and strongly promoting the persubstitution of all chlorine atoms. The final degradation of intermediate

  通过取代基作用的增强，在温和的反应条件下，通过用叔胺处理氰尿酰氯，制备了被三个二烷基氨基取代的1,3,5-三嗪。季Ñ -triazinylammonium盐被鉴定为活性中间体活化三嗪环，并强烈促进所有氯原子的persubstitution。在适当的氯烷烃不可逆转的释放过程中，中间体N-三叠氮基氯化铵的最终降解在室温下或在沸腾的二氯甲烷中自发进行。
• Rigid thermoplastic halopolymer compounds and method for reduction of heat release
  申请人：THE B.F. GOODRICH COMPANY

  公开号：EP0568922A1

  公开（公告）日：1993-11-10

  Disclosed are rigid and semi-rigid, impact modified halopolymer compositions and methods for reducing the heat release on exposure to an incident flux by the incorporation of an organo-amine molybdate and antimony oxide. Articles made including extruded sheets, non-sheet profiles and injection molded articles exhibit a total heat release rate of less than 65 kW/m² and a peak heat release rate of 65 kW-min/m² measured by means of the OSU rate of heat release calorimeter according to FAR 25.853. The preferred compound embodiments comprise post-chlorinated polyvinyl chloride, impact modifier, stabilizer, lubricant, melamine molybdate, antimony trioxide, pigment and colorant.

  本发明公开了硬质和半硬质抗冲击改性卤聚合物组合物，以及通过加入有机胺钼酸盐和氧化锑来减少暴露于入射流量时的热释放的方法。包括挤压板材、非板材型材和注塑制品在内的物品的总热释放率低于 65 kW/m²，根据 FAR 25.853，通过 OSU 热释放率量热器测量的峰值热释放率为 65 kW-min/m²。优选的化合物实施例包括后氯化聚氯乙烯、抗冲改性剂、稳定剂、润滑剂、三聚氰胺钼酸盐、三氧化二锑、颜料和着色剂。
• Improved rigid smoke supressed polyvinyl chloride compounds
  申请人：The Geon Company

  公开号：EP0587104A2

  公开（公告）日：1994-03-16

  Improved PVC compounds formulated for exhibiting low smoke generation and having high processing stability and impact resistance comprising polyvinyl chloride, an effective amount of at least one smoke suppressant selected from the group consisting of molybdenum, iron, copper, zinc, vanadium, lithium, sodium, potassium, magnesium, calcium, barium, zirconium, manganese, phosphorous, aluminum, chromium, boron, tin and titanium based smoke suppressants, including mixtures, and a lubricant system comprising an ester of a long chain carboxylic acid, a chemically modified paraffin wax, and alkyl ester of an alkyl polyol, and optionally a C₈ to C₃₀ substituted or unsubstituted carboxylic acid and a hydrocarbon wax. The compounds disclosed exhibit an improved combination of properties for a rigid compound exhibiting a heat distortion temperature of at least 60°C, including dynamic thermal stability, impact strength and reduced smoke density in both the flaming and non-flaming mode per NFPA 258. Preferably, an impact modifier system is included and is selected from the group consisting of an acrylic polymeric impact modifier, an MBS impact modifier, and an ABS impact modifier. A primary stabilizer is included and a preferred stabilizer system comprises a tin compound and a co-stabilizer selected from epoxidized materials. The compounds are useful substitutes for engineering thermoplastics in large and/or intricate shaped articles including shower stalls, wall panels, tub enclosures, refrigerator panels, appliance housings, electrical housings, sporting equipment, plumbing ware, automotive components, business machine components and housings.

  一种改良聚氯乙烯化合物，配制成具有低发烟性、高加工稳定性和抗冲击性，包括聚氯乙烯、至少一种有效量的烟雾抑制剂，该抑制剂选自钼、铁、铜、锌、钒、锂、钠、钾、镁、钙、钡、锆、锰、磷、铝、铬、硼、锡和钛组成的组、以钼、铁、铜、锌、钒、锂、钠、钾、镁、钙、钡、锆、磷、铝、铬、硼、锡和钛为基础的烟雾抑制剂（包括混合物），以及润滑剂系统，该润滑剂系统包括长链羧酸酯、化学改性石蜡、烷基多元醇烷基酯，以及可选的 C₈至 C₃₀取代或未取代的羧酸和烃蜡。对于热变形温度至少为 60°C 的硬质化合物来说，所公开的化合物具有更好的综合性能，包括动态热稳定性、抗冲击强度以及在 NFPA 258 规定的燃烧和非燃烧模式下降低烟密度。最好包括抗冲击改性剂系统，该系统选自丙烯酸聚合物抗冲击改性剂、MBS 抗冲击改性剂和 ABS 抗冲击改性剂组成的组。此外，还包括一种主稳定剂，优选的稳定剂体系包括一种锡化合物和一种选自环氧 化材料的辅助稳定剂。这些化合物可以替代工程热塑性塑料，用于大型和/或复杂形状的物品，包括淋浴间、墙板、浴缸外壳、冰箱面板、电器外壳、电气外壳、运动器材、水暖器材、汽车部件、商业机器部件和外壳。
• v.Meyer,E.; Naebe, Journal fur praktische Chemie (Leipzig 1954), 1910, vol. <2>82, p. 536
  作者：v.Meyer,E.、Naebe

  DOI：——

  日期：——
• IMPROVED RIGID VINYL CHLORIDE POLYMER COMPOSITIONS
  申请人：The B.F. GOODRICH Company

  公开号：EP0031839B1

  公开（公告）日：1985-11-13