2-(1-Propenyl)-6-methylphenol | 124268-23-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 酚类
• 英文名称: 2-(1-Propenyl)-6-methylphenol
• 英文别名: 2-methyl-6-[(Z)-prop-1-enyl]phenol
• CAS: 124268-23-1
• 化学式: C₁₀H₁₂O
• 分子量: 148.205
• InChiKey: QXHZECWIBHLKMB-HYXAFXHYSA-N

物化性质

• 沸点：
  243.2±9.0 °C(Predicted)
• 密度：
  1.021±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  2.9
• 重原子数：
  11
• 可旋转键数：
  1
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.2
• 拓扑面积：
  20.2
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  2-烯丙基-6-甲基苯酚 在 C₂₁H₂₃Cl₂O₄PRu 、 potassium carbonate 作用下， 以 水 为溶剂， 反应 4.0h， 以76%的产率得到
  参考文献：
  名称：

  亲水性（η 6 -Arene） -钌（II）配合物的P-OH配体作为催化剂用于Allylbenzenes的异构化和C-H键反应芳基化在水

  摘要：

  含η半夹心钌（II）配合物6配位的3-苯基丙醇和亚膦酸基型配体，即，将[RuCl 2（η 6 -C 6 H ^ 5 CH 2 CH 2 CH 2 OH）{P（OH） R 2 }]（R = Me（2a），Ph（2b），4-C 6 H 4 CF 3（2c），4-C 6 H 4 OMe（2d），OMe（2e），OEt（2f），和OPh（2克），已在44-88％的产率通过反应而合成将[RuCl 2 {η 6：κ 1（Ò）-C 6 H ^ 5 CH 2 CH 2 CH 2 OH}]（1）与适当的五价磷氧化物R 2 P（＝ O）H。的结构将[RuCl 2（η 6 -C 6 H ^ 5 CH 2 CH 2 CH 2 OH）{P（OH）Me 2 }]（2A）通过X射线衍射方法进行了明确地证实。化合物2a – g被证明是催化活性在allylbenzenes的异构化为相应的（1-丙烯基）采用水作为唯一的反应溶剂，用将[RuCl苯衍生物2（η

  DOI：

  10.1021/acs.organomet.9b00463

文献信息

• A new rearrangement of alkoxybenzyl anions
  作者：Robert B. Bates、Teruna J. Siahaan、Kessara Suvannachut

  DOI：10.1021/jo00291a044

  日期：1990.2
• BATES, ROBERT B.;SIAHAAN, TERUNA J.;SUVANNACHUT, KESSARA, J. ORG. CHEM., 55,(1990) N, C. 1328-1334
  作者：BATES, ROBERT B.、SIAHAAN, TERUNA J.、SUVANNACHUT, KESSARA

  DOI：——

  日期：——
• COMPOSITIONS OF VOLATILE ORGANIC COMPOUNDS AND METHODS OF USE THEREOF
  申请人：Synthetic Genomics, Inc.

  公开号：EP2413692B1

  公开（公告）日：2018-08-29
• ENDOPHYTIC FUNGUS AND USES THEREFOR
  申请人：Green Wayne A.

  公开号：US20110182862A1

  公开（公告）日：2011-07-28

  The present invention provides novel microorganisms, compositions and methods of use thereof, for treating, inhibiting or preventing the developing of a plant pathogenic disease and for killing or inhibiting growth of a variety of pests or pathogens. Provided are compositions comprising a novel endophytic fungal organism effective to inhibit the growth of or kill pests and pathogenic microbes, including Ganoderma boninense . Invention compositions are especially useful in preventing and treating basal stem rot in the oil palm, and can be applied on or in the vicinity of the plant or used to sterilize the plant growth medium prior to or concurrent with plant growth therein. The disclosure further provides substantially purified polynucleotides and polypeptides encoded thereby, together with methods of using those products, for example for making transgenic organism.
• Compositions of Volatile Organic Compounds and Methods of User Thereof
  申请人：Synthetic Genomics, Inc.

  公开号：US20130224315A1

  公开（公告）日：2013-08-29

  The present invention provides compositions and methods for treating, inhibiting or preventing the developing of a plant pathogenic disease. The compositions comprise volatile organic compounds effective to inhibit the growth of, or kill pathogenic microbes, including Ganoderma boninense . Invention compositions are especially useful in preventing and treating basal stem rot in the oil palm, and can be applied in the vicinity of the plant or used to sterilize the plant growth medium prior to or concurrent with plant growth therein.