N-methyl-1,12-dodecandiamine | 226892-89-3

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: N-methyl-1,12-dodecandiamine
• 英文别名: N'-methyldodecane-1,12-diamine
• CAS: 226892-89-3
• 化学式: C₁₃H₃₀N₂
• 分子量: 214.395
• InChiKey: OUTVWSBTUSNVFH-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.5
• 重原子数：
  15
• 可旋转键数：
  12
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  38
• 氢给体数：
  2
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  N-methyl-1,12-dodecandiamine 以 乙腈 为溶剂， 反应 12.0h， 生成 1,5-diaza-1-methylcycloheptadec-3-en-2-one
  参考文献：
  名称：

  大烯胺内酰胺的快速合成，一类新型的大环化合物

  摘要：

  摘要 报道了使用基于 Meldrum 酸衍生物热分解的原始合成方法有效制备烯氨基内酰胺的方法。关键步骤涉及 ω-氨基烷基-氨基甲基烯酮的分子内加成。

  DOI：

  10.1080/00397919908086167
• 作为产物：
  描述：

  N-(12-bromododecyl)phthalimide 在 sodium hydroxide 、 potassium carbonate 、 potassium iodide 作用下， 以 乙醇 、 水 为溶剂， 反应 14.0h， 生成 N-methyl-1,12-dodecandiamine
  参考文献：
  名称：

  大烯胺内酰胺的快速合成，一类新型的大环化合物

  摘要：

  摘要 报道了使用基于 Meldrum 酸衍生物热分解的原始合成方法有效制备烯氨基内酰胺的方法。关键步骤涉及 ω-氨基烷基-氨基甲基烯酮的分子内加成。

  DOI：

  10.1080/00397919908086167

文献信息

• Thermoplastic resin composition
  申请人：IDEMITSU PETROCHEMICAL COMPANY LIMITED

  公开号：EP0558048A1

  公开（公告）日：1993-09-01

  There is disclosed a thermoplastic resin composition comprising as principal components a [A] thermoplastic resin having a functional group reactive with an amino group, a [B] olefinic polymer and/or styrenic polymer, the subtotal of the above [A]+[B] being 100 parts by weight, and 0.05 to 20 parts by weight of a [C] copolymer having in a molecule thereof a formamide group and/or an amino group or a salt thereof, said copolymer having the repeating unit I, II, III or IV represented by the general formula (I), (II), (III) or (IV), respectively, wherein Y is a group selected from the general formula         -NH-R¹³   (VII) and other symbols are as defined in the specification. The above composition is excellent in impact characteristics, especially surface impact characteristics and appearance, minimized in coloration and free from delamination and peeling.

  本发明公开了一种热塑性树脂组合物，其主要成分包括具有与氨基反应的官能团的[A]热塑性树脂、[B]烯烃聚合物和/或苯乙烯聚合物，上述[A]+[B]的小计为100份（重量），以及0.05 至 20 重量份的[C]共聚物，其分子中含有甲酰胺基和/或氨基或其盐，所述共聚物具有分别由通式(I)、(II)、(III)或(IV)表示的重复单元 I、II、III 或 IV、 其中 Y 是选自通式的基团 -NH-R¹³（VII） 和其他符号在说明书中定义。上述组合物具有优异的抗冲击特性，尤其是表面抗冲击特性和外观，着色少，无分层和剥落。
• Copolymer having amino group and process for production thereof
  申请人：DAI-ICHI KOGYO SEIYAKU Co., Ltd.

  公开号：EP0558047A2

  公开（公告）日：1993-09-01

  There are disclosed a copolymer having a secondary amino group such as an alkylpiperazino group or having a formamide group which is introduced via imide group in the side chains of various high polymers and a process for producing the above copolymer by reacting a starting copolymer having the repeating unit originating from an acid anhydride (e.g. maleic anhydride) with a salt of a specific amine (e.g. piperazine derivative) in the presence or absence of a formyl group-containing compound (e.g. formamide) to imidize the starting copolymer and further removing the acid with a base, or by imidizing the starting copolymer with the reaction product between the specific amine and the formyl group-containing compound. The above copolymer is usable for high molecular amino reagents, raw materials for functional high polymers, raw materials for additives, compatibilizers for polymers, resin dyeing improvers, epoxy resin curing agent, resin modifiers, etc.

  本发明公开了一种具有烷基哌嗪基等仲氨基或具有甲酰胺基的共聚物，该共聚物通过酰亚胺基引入到各种高聚物的侧链中，并公开了一种生产上述共聚物的工艺，该工艺是将具有源自酸酐（如马来酸酐）的重复单元的起始共聚物与特定胺盐（如哌嗪衍生物）在存在或不存在含甲酰基化合物（如甲酰胺）的情况下进行反应，使其酰亚胺化，从而生产出上述共聚物。马来酸酐）与特定胺（如哌嗪衍生物）的盐在含甲酰基化合物（如甲酰胺）存在或不存在的情况下进行反应，使起始共聚物酰亚胺化，并用碱进一步除去酸，或用特定胺与含甲酰基化合物的反应产物使起始共聚物酰亚胺化。上述共聚物可用于高分子氨基试剂、功能性高聚物原料、添加剂原料、聚合物相容剂、树脂染色改良剂、环氧树脂固化剂、树脂改性剂等。
• CHARGE RETENTION MEDIUM
  申请人：Asahi Glass Company, Limited

  公开号：EP2648196A1

  公开（公告）日：2013-10-09

  To provide a charge retention medium having a surface potential at a practical level, although it is obtained from a composition containing a fluorinated copolymer having repeating units based on tetrafluoroethylene and repeating units based on ethylene. A charge retention medium (electret 30) which is obtained from a composition containing a fluorinated copolymer (A) having repeating units based on tetrafluoroethylene and repeating units based on ethylene; and at least one charge aid (B) selected from the group consisting of a compound having at least one amino group and at least one reactive functional group (excluding an amino group) and a compound having at least two amino groups and having no reactive functional group (excluding an amino group).

  提供一种电荷保持介质，尽管它是由一种含有氟化共聚物的组合物获得的，该共聚物具有以四氟乙烯为基础的重复单元和以乙烯为基础的重复单元，但它的表面电位达到实用水平。 一种电荷保持介质（驻极体 30），由含有氟化共聚物（A）的组合物获得，该共聚物具有以四氟乙烯为基础的重复单元和以乙烯为基础的重复单元；以及至少一种电荷助剂（B），该助剂选自具有至少一个氨基和至少一个反应性官能团（不包括氨基）的化合物和具有至少两个氨基且不具有反应性官能团（不包括氨基）的化合物组成的组。
• METHOD FOR PRODUCING CHARGE RETENTION MEDIUM
  申请人：Asahi Glass Company, Limited

  公开号：EP2648197A1

  公开（公告）日：2013-10-09

  To provide a process for producing a charge retention medium, with which a coating film (precursor of a charge retention medium) containing a fluorinated copolymer having repeating units based on tetrafluoroethylene and repeating units based on ethylene can easily be formed on the surface of a substrate, even in a case where the surface of the substrate has a complicated shape. A process for producing a charge retention medium (electret 30), which comprises a step of applying a coating composition containing a fluorinated copolymer (A) having repeating units based on tetrafluoroethylene and repeating units based on ethylene, and an organic solvent (C), to a substrate (first substrate 10) to form a coating film.

  提供一种电荷保持介质的生产工艺，通过该工艺，即使在基材表面形状复杂的情况下，也能容易地在基材表面形成含有氟化共聚物的涂膜（电荷保持介质的前体），该氟化共聚物具有以四氟乙烯为基础的重复单元和以乙烯为基础的重复单元。 一种电荷保持介质（驻极体 30）的生产工艺，包括将含有氟化共聚物（A）的涂层组合物（A）（A）具有基于四氟乙烯的重复单元和基于乙烯的重复单元）和有机溶剂（C）涂敷到基底（第一基底 10）上以形成涂膜的步骤。
• MODIFIED BLOCK COPOLYMER, METHOD FOR PRODUCING MODIFIED BLOCK COPOLYMER, AND RESIN COMPOSITION
  申请人：Asahi Kasei Kabushiki Kaisha

  公开号：EP3623398A1

  公开（公告）日：2020-03-18

  A modified block copolymer according to the present invention is a modified block copolymer comprising a polymer block comprising a vinyl aromatic compound as a main constituent (A), a polymer block comprising a conjugate diene compound as a main constituent (B), and an atomic group having NHx (x = 0 to 2) (C). In the modified block copolymer, the polymer block comprising a conjugate diene compound as a main constituent (B) is a hydrogenated product, the atomic group having NHx (x = 0 to 2) (C) is contained in a side chain, and a compound forming the atomic group having NHx (x = 0 to 2) (C) satisfies the following condition: Condition: when the compound forming the atomic group having NHx (x = 0 to 2) (C) is reacted with a maleic anhydride-modified group in a maleic anhydride-modified block copolymer, a MFR value at 230°C under a load of 2.16 kg of the modified block copolymer after the reaction is 0.1 times or more a MFR value at 230°C under a load of 2.16 kg of the maleic anhydride-modified block copolymer before the reaction.

  根据本发明，改性嵌段共聚物是一种改性嵌段共聚物，包括以乙烯基芳香族化合物为主要成分的聚合物嵌段（A）、以共轭二烯化合物为主要成分的聚合物嵌段（B）和具有 NHx（x = 0 至 2）的原子团（C）。在改性嵌段聚合物中，由共轭二烯化合物作为主要成分（B）的聚合物嵌段是氢化产物，具有 NHx（x = 0 至 2）（C）的原子团包含在侧链中，形成具有 NHx（x = 0 至 2）（C）的原子团的化合物满足以下条件： 条件：当形成具有 NHx（x = 0 至 2）(C)的原子团的化合物与马来酸酐改性嵌段共聚物中的马来酸酐改性基团反应时，反应后在 230℃、负载 2.16 千克改性嵌段共聚物时的 MFR 值是反应前在 230℃、负载 2.16 千克马来酸酐改性嵌段共聚物时的 MFR 值的 0.1 倍或以上。