(E)-5-methyl-1-(1-naphthylseleno)-1-hexene | 1454270-84-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: (E)-5-methyl-1-(1-naphthylseleno)-1-hexene
• 英文别名: 1-[(E)-5-methylhex-1-enyl]selanylnaphthalene
• CAS: 1454270-84-8
• 化学式: C₁₇H₂₀Se
• 分子量: 303.306
• InChiKey: ZANPFTZPKLRXNA-AWNIVKPZSA-N

物化性质

• 沸点：
  391.0±15.0 °C(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  4.12
• 重原子数：
  18
• 可旋转键数：
  5
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.29
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  5-甲基-1-已炔 、 二硒化,二-1-萘基 在 Diphenylphosphine oxide 作用下， 以 氯仿 为溶剂， 反应 15.0h， 以76%的产率得到
  参考文献：
  名称：

  Highly regioselective hydroselenation of inactivated terminal alkynes using diselenide–Ph2P(O)H mixed systems under visible-light irradiation

  摘要：

  Upon visible-light irradiation, we could achieve a highly regioselective hydroselenation of inactivated terminal alkynes to give 1-(organylseleno)-1-alkenes by using diselenide-Ph2P(O)H mixed systems. The photoinduced hydroselenation presented in this study is advantageous as it does not involve the handling of oxygen-sensitive and foul-smelling selenols. (C) 2013 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2013.07.127

文献信息

• Highly regioselective hydroselenation of inactivated terminal alkynes using diselenide–Ph2P(O)H mixed systems under visible-light irradiation
  作者：Yohsuke Kobiki、Shin-ichi Kawaguchi、Akiya Ogawa

  DOI：10.1016/j.tetlet.2013.07.127

  日期：2013.10

  Upon visible-light irradiation, we could achieve a highly regioselective hydroselenation of inactivated terminal alkynes to give 1-(organylseleno)-1-alkenes by using diselenide-Ph2P(O)H mixed systems. The photoinduced hydroselenation presented in this study is advantageous as it does not involve the handling of oxygen-sensitive and foul-smelling selenols. (C) 2013 Elsevier Ltd. All rights reserved.