4-(S,S-dimethylsulfoximino)-1,2,4-triazoline-3,5-dione | 190509-89-8

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: 4-(S,S-dimethylsulfoximino)-1,2,4-triazoline-3,5-dione
• 英文别名: 4-(SS-dimethylsulfoximino)-1,2,4-triazoline-3,5-dione；4-[[Dimethyl(oxo)-lambda6-sulfanylidene]amino]-1,2,4-triazole-3,5-dione；4-[[dimethyl(oxo)-λ6-sulfanylidene]amino]-1,2,4-triazole-3,5-dione
• CAS: 190509-89-8
• 化学式: C₄H₆N₄O₃S
• 分子量: 190.183
• InChiKey: AUAAAOMBYFKPHT-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.6
• 重原子数：
  12
• 可旋转键数：
  1
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  99.9
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  1,4-二苯基-1,3丁二烯 、 4-(S,S-dimethylsulfoximino)-1,2,4-triazoline-3,5-dione 以 二氯甲烷 为溶剂， 生成 2,5-diphenyl-8-(S,S-dimethylsulfoximino)-1,6,8-triaza[4.3.0]bicyclonon-3-en-7,9-dione
  参考文献：
  名称：

  A New Synthesis of Diazenes (Azoalkanes) Using 4-(S,S-Dimethylsulfoximino)- 1,2,4-triazoline-3,5-dione. The Construction of Diazenes from Amino Nitrenes via Base-Induced Sulfoximine Cleavage

  摘要：

  DOI：

  10.1021/jo970011j
• 作为产物：
  描述：

  4-[[Dimethyl(oxo)-lambda6-sulfanylidene]amino]-1,2,4-triazolidine-3,5-dione 在 碘苯二乙酸 作用下， 以 乙腈 为溶剂， 反应 1.0h， 生成 4-(S,S-dimethylsulfoximino)-1,2,4-triazoline-3,5-dione
  参考文献：
  名称：

  A New Synthesis of Diazenes (Azoalkanes) Using 4-(S,S-Dimethylsulfoximino)- 1,2,4-triazoline-3,5-dione. The Construction of Diazenes from Amino Nitrenes via Base-Induced Sulfoximine Cleavage

  摘要：

  DOI：

  10.1021/jo970011j

文献信息

• Photocurable hard and porous biomaterials from ROMP precursors cross-linked with diyl radicals
  作者：Eric Enholm、Aarti Joshi、Dennis L. Wright

  DOI：10.1016/j.bmcl.2005.08.060

  日期：2005.12

  A combination of (ROMP) ring-opening metathesis polymerization and diradical (diyl) cross-linking provides a new access to hard biomaterials and potential artificial bone replacements. ROMP was used to construct soft and pliable linear polymers bearing photolabile diazene functions. After treatment with light, a nitrogen aerosol is released throughout the polymer to create desirable porosity, cross-linking, and hardening in a single step. Nonpolymeric mechanistic work supporting these studies was also examined. (c) 2005 Elsevier Ltd. All rights reserved.
• A New Synthesis of Diazenes (Azoalkanes) Using 4-(<i>S</i>,<i>S</i>-Dimethylsulfoximino)- 1,2,4-triazoline-3,5-dione. The Construction of Diazenes from Amino Nitrenes <i>via</i> Base-Induced Sulfoximine Cleavage
  作者：Scott Meehan、R. Daniel Little

  DOI：10.1021/jo970011j

  日期：1997.5.1