trans-3-<2-(3-carbomethoxyquinoxalinyl)>propenenitrile | 136721-37-4

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 二氮杂萘
• 英文名称: trans-3-<2-(3-carbomethoxyquinoxalinyl)>propenenitrile
• 英文别名: methyl 3-[(E)-2-cyanoethenyl]quinoxaline-2-carboxylate
• CAS: 136721-37-4
• 化学式: C₁₃H₉N₃O₂
• 分子量: 239.233
• InChiKey: IXZLTMOFXQLOFE-QPJJXVBHSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.6
• 重原子数：
  18
• 可旋转键数：
  3
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.08
• 拓扑面积：
  75.9
• 氢给体数：
  0
• 氢受体数：
  5

反应信息

• 作为产物：
  描述：

  2-azido-1-methoxyphenazine 、 苯 以3%的产率得到
  参考文献：
  名称：

  ALBINI A.; BETTINETTI G.; MINOLI G., J. ORG. CHEM., 52,(1987) N 7, 1245-1251

  摘要：

  DOI：

文献信息

• Photochemical decomposition of 1-alkoxy-2-azidophenazines. Addition of nitrenes to azides
  作者：A. Albini、G. Bettinetti、G. Minoli

  DOI：10.1021/jo00025a010

  日期：1991.12

  The photolysis of 2-azido-1-methoxyphenazine (1a) and its ethoxy homologue (1b) takes an unusual course. It involves the addition of a singlet nitrene or one of its cyclic tautomers to the ground-state azide to form the N-phenazinyl iminoether 9a (from 1a) and a 2-oxazolo[5,4-a]phenazinyl derivative of a quinoxalinylpropenenitrile (10, from both 1a and 1b). Products derived from the triplet nitrene are formed as well. The effects of varying some of the experimental conditions were determined. A mechanism for the photolysis is proposed.
• Inter- and intramolecular reactions of nitrenes and their cyclic isomers in the photodecomposition of some substituted 2-azidophenazines
  作者：Angelo Albini、Gianfranco Bettinetti、Giovanna Minoli

  DOI：10.1021/jo00383a013

  日期：1987.4
• ALBINI A.; BETTINETTI G.; MINOLI G., J. ORG. CHEM., 52,(1987) N 7, 1245-1251
  作者：ALBINI A.、 BETTINETTI G.、 MINOLI G.

  DOI：——

  日期：——