N-Methyl-N,N-dipentylpentan-1-aminium | 45200-25-7

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: N-Methyl-N,N-dipentylpentan-1-aminium
• 英文别名: methyl(tripentyl)azanium
• CAS: 45200-25-7
• 化学式: C16H36N+
• 分子量: 242.46
• InChiKey: NDNHNDHVEAHYRC-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.7
• 重原子数：
  17
• 可旋转键数：
  12
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

文献信息

• IONIC LIQUID CONTAINING ALLYLSULFONATE ANION
  申请人：Watahiki Tsutomu

  公开号：US20120157680A1

  公开（公告）日：2012-06-21

  PROBLEM: Providing a novel ionic liquid, which is low-cost, environment-friendly, and has low viscosity and melting point. MEANS FOR SOLVING THE PROBLEM: The present invention is the invention of the ionic liquid represented by the general formula [1]: wherein, R 1 to R 3 and n pieces of R 4 each independently represent hydrogen atom or alkyl group having 1 to 4 carbon atoms, R 5 to R 7 each independently represent alkyl group, aralkyl group, or aryl group, R 8 represents alkyl group, aralkyl group, aryl group, or the one represented by the general formula [2]: (wherein T represents alkylene chain having 1 to 8 carbon atoms, n represents 1 or 2, and R 1 to R 7 are the same as the above-described), X represents nitrogen atom or phosphorus atom, n represents 1 or 2. When n is 1, R 3 and R 4 are bound and may form cyclohexene ring together with the adjacent carbon atoms. In addition, when X is nitrogen atom, R 5 to R 7 or R 5 to R 6 may form hetero ring with nitrogen atom binding thereto}.

  问题：提供一种新型离子液体，成本低、环保，并具有低粘度和熔点。 解决问题的方法：本发明是一种由通式[1]表示的离子液体的发明：其中，R1到R3和n个R4分别独立表示氢原子或具有1到4个碳原子的烷基基团，R5到R7分别独立表示烷基基团、芳基烷基基团或芳基基团，R8表示烷基基团、芳基烷基基团、芳基基团或由通式[2]表示的基团：（其中T表示具有1到8个碳原子的烷基链，n表示1或2，R1到R7与上述相同），X表示氮原子或磷原子，n表示1或2。当n为1时，R3和R4结合并且可能与相邻碳原子一起形成环己烯环。此外，当X为氮原子时，R5到R7或R5到R6可能与结合在一起的氮原子形成杂环}。
• PROCESS FOR THE PREPARATION OF PERFLUOROALKYLCYANO- OR PERFLUOROALKYLCYANOFLUOROBORATES
  申请人：Ignatyev Nikolai (Mykola)

  公开号：US20120309981A1

  公开（公告）日：2012-12-06

  The invention relates to a process for the preparation of salts having perfluoroalkyltricyano- or perfluoroalkylcyanofluoroborate anions, ((per)fluoro)phenyltricyano- or ((per)fluoro)phenylcyanofluoroborate anions, phenyltricyanoborate anions which are mono- or disubstituted by perfluoroalkyl groups having 1 to 4 C atoms or phenylcyanofluoroborate anions which are mono- or disubstituted by perfluoroalkyl groups having 1 to 4 C atoms, by reaction of alkali metal trifluoroperfluoroalkylborate with trialkylsilyl cyanide and a subsequent salt-exchange reaction or by direct reaction of an organic trifluoroperfluoroalkyl borate with trialkylsilyl cyanide.

  该发明涉及一种制备具有全氟烷基三氰酸盐或全氟烷基氰氟硼酸盐阴离子，((全氟)苯基)三氰酸盐或((全氟)苯基)氰氟硼酸盐，被全氟烷基取代的具有1至4个碳原子的苯基三氰硼酸盐或被全氟烷基取代的具有1至4个碳原子的苯基氰氟硼酸盐的方法，通过碱金属三氟全氟烷基硼酸盐与三烷基硅氰酸酯的反应和随后的盐交换反应或通过有机三氟全氟烷基硼酸盐与三烷基硅氰酸酯的直接反应。
• COMPOUNDS WITH (PERFLUOROALKYL) FLUOROHYDROGENPHOSPHATE ANIONS
  申请人：Ignatyev Nikolai (Mykola)

  公开号：US20120264946A1

  公开（公告）日：2012-10-18

  The present invention relates to a process for the preparation of compounds with (perfluoroalkyl)fluorohydrogenphosphate anion, and to compounds containing (perfluoroalkyl)fluorohydrogenphosphate anion and to the use thereof.

  本发明涉及一种制备含有（全氟烷基）氟氢磷酸盐阴离子的化合物的方法，以及含有（全氟烷基）氟氢磷酸盐阴离子的化合物及其用途。
• CLEAR COAT FORMULATIONS FOR USE OVER NAIL POLISH
  申请人：Elementis Specialties, Inc.

  公开号：US20180353421A1

  公开（公告）日：2018-12-13

  A clear coating composition for use over nail polish. The clear coating composition comprises (a) a crosslinkable coating composition comprising: ingredient A that has at least two protons that can be activated to form a Michael carbanion donor; ingredient B that functions as a Michael acceptor having at least two ethylenically unsaturated functionalities each activated by an electron-withdrawing group; and a dormant carbamate initiator of Formula (1) wherein R 1 and R 2 can be independently selected from hydrogen, a linear or branched substituted or unsubstituted alkyl group having 1 to 22 carbon atoms; 1 to 8 carbon atoms; 1 to 3 carbon atoms; and A n+ is a cationic species or polymer and n is an integer equal or greater than 1 with the proviso that A n+ is not an acidic hydrogen; an ingredient D having one or more reactive protons that are more acidic than the two protons of ingredient A, with respect to pKa; at least one organic solvent; with the proviso that the clear coating composition is free of FD&C or D&C dyes, lakes or pigments. The clear coating composition optionally further comprising ammonium carbamate (H 2 NR 1 R 2 +− OC═ONR 1 R 2 ).

  一种用于在指甲油上使用的清漆组合物。该清漆组合物包括(a) 交联性涂层组合物，包括：成分A，其具有至少两个质子，可被激活形成Michael碳负离子给体；成分B，其作为Michael受体，具有至少两个由电子吸引基激活的烯丙基未饱和官能团；以及式（1）的休眠氨甲酸酯引发剂，其中R1和R2可以独立地选择为氢、具有1至22个碳原子的线性或支链取代或未取代的烷基基团；1至8个碳原子；1至3个碳原子；以及An+是阳离子物种或聚合物，n是大于等于1的整数，但An+不是酸性氢；成分D具有比成分A的两个质子更酸性的一个或多个反应性质子，相对于pKa；至少一种有机溶剂；前提是，该清漆组合物不含FD＆C或D＆C染料、颜料或颜料。该清漆组合物可以进一步包括氨甲酸铵（H2NR1R2 +−OC═ONR1R2）。
• [EN] CROSSLINKABLE COATING COMPOSITIONS FORMULATED WITH DORMANT CARBAMATE INITIATOR<br/>[FR] COMPOSITIONS DE REVÊTEMENT RÉTICULABLES FORMULÉES AVEC INITIATEUR DE CARBAMATE DORMANT
  申请人：ELEMENTIS SPECIALTIES INC

  公开号：WO2018005077A1

  公开（公告）日：2018-01-04

  A crosslinkable coating composition comprising: ingredient A that has at least two protons that can be activated to form a Michael carbanion donor; ingredient B that functions as a Michael acceptor having at least two ethylenically unsaturated functionalities each activated by an electron -withdrawing group; and a dormant carbamate initiator of Formula (1) wherein R1 and R2 can be independently selected from hydrogen, a linear or branched substituted or unsubstituted alkyl group having 1 to 22 carbon atoms; 1 to 8 carbon atoms; and An+ is a cationic species or polymer and n is an integer equal or greater than 1 with the proviso that An+ is not an acidic hydrogen; and optionally further comprising ammonium carbamate (H2NR1R2+ OC=ONR1R2). The crosslinkable coating composition can be used for a variety of coating applications including nail coating compositions.

  一种可交联的涂层组成物，包括：成分A，其具有至少两个质子，可被激活形成Michael的碳负离子给体；成分B，其作为Michael受体，具有至少两个乙烯基不饱和官能团，每个官能团由一个电子吸引基激活；以及公式（1）中的休眠氨基甲酸酯引发剂，其中R1和R2可以独立地选择为氢，具有1至22个碳原子的线性或支链取代或未取代的烷基基团；1至8个碳原子；An+是阳离子物种或聚合物，n是大于或等于1的整数，前提是An+不是酸性氢；并且可选择进一步包括氨基甲酸铵（H2NR1R2+OC=ONR1R2）。该可交联的涂层组成物可用于各种涂层应用，包括指甲涂层组成物。