2-chloro-3-nitro-naphthalene | 38396-21-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: 2-chloro-3-nitro-naphthalene
• 英文别名: 2-Chlor-3-nitro-naphthalin；2-Chlor-3-nitronaphthalin；2-Nitro-3-chlornaphthalin；3-Chlor-2-nitronaphthalin；2-Chloro-3-nitronaphthalene
• CAS: 38396-21-3
• 化学式: C₁₀H₆ClNO₂
• 分子量: 207.616
• InChiKey: BUJHUYMLGZRWQZ-UHFFFAOYSA-N

物化性质

• 熔点：
  94.5 °C
• 沸点：
  353.1±15.0 °C(Predicted)
• 密度：
  1.409±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3.7
• 重原子数：
  14
• 可旋转键数：
  0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  45.8
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  2-chloro-3-nitro-naphthalene 生成 3-氯-2-萘胺
  参考文献：
  名称：

  Jubault,M.; Peltier,D., Bulletin de la Societe Chimique de France, 1972, p. 1551 - 1561

  摘要：

  DOI：
• 作为产物：
  描述：

  2,3-二硝基萘 生成 2-chloro-3-nitro-naphthalene
  参考文献：
  名称：

  喹唑啉。12.在中心环上含有长链烷基或氯取代基的1，3-二氨基苯并（f）喹唑啉。合成和生物学评估作为候选抗叶酸剂和抗疟药。

  摘要：

  DOI：

  10.1021/jm00257a016

文献信息

• Linear crystalline alpha-alkylpolybenzyls and process for preparing them
  申请人：EXXON RESEARCH AND ENGINEERING COMPANY

  公开号：EP0017455A1

  公开（公告）日：1980-10-15

  Linear polybenzyls of high molecular weight and high crystallinity suitable for use in films or moulding compositions are obtained by polymerizing aralkyl halides in the presence of a Friedel-Crafts catalyst complexed with a nitroarene or a nitroalkane complexing agent in a halogenated solvent. The complex catalyst allows the polymerization to be run at higher rates. The polymerizable a-alkyl-benzyl halides which can be readily employed are represented by the following structural formula: wherein R1 is a C1-C4 alkyl group, R2 and R3 are the same or different and are each selected from the group consisting of I hydrogen and C1-C4 alkyl groups, and X is halogen.

  在弗里德尔-卡夫斯催化剂与硝基烯烃或硝基烷烃络合剂络合的情况下，在卤化溶剂中使芳基卤化物聚合，可获得适用于薄膜或模塑组合物的高分子量和高结晶度的线性聚苄基烯烃。 络合催化剂可使聚合反应以更高的速率进行。 可聚合的 a-烷基-苄基卤化物可用以下结构式表示： 其中 R1 是 C1-C4 烷基，R2 和 R3 相同或不同，且各自选自氢和 C1-C4 烷基组成的组，X 是卤素。
• Jubault,M.; Peltier,D., Bulletin de la Societe Chimique de France, 1972, p. 1551 - 1561
  作者：Jubault,M.、Peltier,D.

  DOI：——

  日期：——
• Bilateral coexistent calcaneonavicular and talocalcaneal tarsal coalition: A case report
  作者：V. Bhalaik、S. Chhabra、H.P.J. Walsh

  DOI：10.1016/s1067-2516(02)80038-2

  日期：2002.3

  Tarsal coalition refers to a union of two or more tarsal bones. The union may be fibrous, cartilaginous, or bony. The most common sites of tarsal coalition reported in the literature are the calcaneonavicular, the talocalcaneal, and, less commonly, the talonavicular areas. Bilateral coexistent multiple tarsal coalitions are a rare occurrence. The authors present a case report of a 17-year-old boy with bilateral coexistent calcaneonavicular and talonavicular bars. The diagnosis was established by radiographs and CT scanning. The patient was treated conservatively with immobilization of the foot in a below-knee walking plaster cast followed by the use of an orthosis with a lateral iron and a medial T strap. The patient was pain-free at 2-year follow-up.
• 241. The preparation of certain 2 : 3-naphthalene derivatives
  作者：Herbert H. Hodgson、Reginald L. Elliott

  DOI：10.1039/jr9360001151

  日期：——
• Ward et al., Journal of the Chemical Society, 1957, p. 4816,4819
  作者：Ward et al.

  DOI：——

  日期：——