2-dipropoxyphosphinothioylsulfanylacetic acid | 31224-81-4

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 有机二硫代磷酸及其衍生物
• 英文名称: 2-dipropoxyphosphinothioylsulfanylacetic acid
• CAS: 31224-81-4
• 化学式: C₈H₁₇O₄PS₂
• 分子量: 272.326
• InChiKey: UWWOIXUOJDPLCV-UHFFFAOYSA-N

物化性质

• 沸点：
  359.6±44.0 °C(Predicted)
• 密度：
  1.272±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  2.88
• 重原子数：
  15.0
• 可旋转键数：
  9.0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.88
• 拓扑面积：
  55.76
• 氢给体数：
  1.0
• 氢受体数：
  5.0

反应信息

• 作为反应物：
  描述：

  2-dipropoxyphosphinothioylsulfanylacetic acid 、 3,3-dimethyl-1-(1,2,4-triazol-1-yl)-1-bromo-2-butanone 在 三乙胺 作用下， 以 丙酮 为溶剂， 以65.6%的产率得到[3,3-Dimethyl-2-oxo-1-(1,2,4-triazol-1-yl)butyl] 2-dipropoxyphosphinothioylsulfanylacetate
  参考文献：
  名称：

  Synthesis and Biological Activities of O, O-Dialkyl-dithiophosphoryl-S-acetoxy Triazolo Compounds

  摘要：

  In this article, we introduce organic phosphorus moiety into triazole ring to prepare O-dialkyl-dithiophosphoryl-S-acetoxy triazolo compounds and characterize their structures by elementary analysis and (HNMR)-H-1 and IR spectral data. From the results of biological activity screening, we found that the O-dialkyl-dithiophosphoryl-S-acetoxy triazolo compounds show lower fungicidal activities and their structures need to be optimized for the better.

  DOI：

  10.1080/10426500307939
• 作为产物：
  描述：

  potassium O,O'-dipropyl dithiophosphate 、 氯乙酸 以 丙酮 为溶剂， 以86.9%的产率得到2-dipropoxyphosphinothioylsulfanylacetic acid
  参考文献：
  名称：

  Synthesis and Biological Activities of O, O-Dialkyl-dithiophosphoryl-S-acetoxy Triazolo Compounds

  摘要：

  In this article, we introduce organic phosphorus moiety into triazole ring to prepare O-dialkyl-dithiophosphoryl-S-acetoxy triazolo compounds and characterize their structures by elementary analysis and (HNMR)-H-1 and IR spectral data. From the results of biological activity screening, we found that the O-dialkyl-dithiophosphoryl-S-acetoxy triazolo compounds show lower fungicidal activities and their structures need to be optimized for the better.

  DOI：

  10.1080/10426500307939

文献信息

• Substitution Reactions of Mono- and Trichloro Acetic Acids with Ammonium Dialkyl (Alkylene) Dithiophosphates
  作者：Neelam Harkut、Padam N. Nagar

  DOI：10.1080/10426500600892693

  日期：2007.1.1

  A reaction of mono- and trichloro acetic acid with ammonium salts of alkylene ( dialkyl) dithiophosphate; [ OGOPS(2)NH(4); G=-CH2CH2CHMe-, -C( Me)(2)C( Me)(2)-, -CH2C( Me)(2)CH2-, and -C( Me)(2)CH2CHMe-; ( RO)(2)PS2-NH4; and R=C2H5, C3H7, i-C3H7;] in a 1: 1 molor ratio in refluxing benzene solution yields low melting solids and light-yellow oily liquids of the type [( RO)(2)PS2R' and OGOPS(2)R', where R' = CH2COOH and Cl2CCOOH], which are hygroscopic in nature. These newly synthesized complexes have been characterized by physicochemical and spectroscopic techniques ( MW, IR, H-1, and (PNMR)-P-31) On the basis of the previously discussed studies, the formation of a P-S-C chemical bond has been established.
• SOLOZHENKIN, P. M.;YUNUSOV, M. M.;VOLOVICH, T. R.;ZAXAROVA, R. M.;MAXORTO+, DOKL. AN TADZHSSR, 32,(1989) N, S. 251-255
  作者：SOLOZHENKIN, P. M.、YUNUSOV, M. M.、VOLOVICH, T. R.、ZAXAROVA, R. M.、MAXORTO+

  DOI：——

  日期：——
• Synthesis and Biological Activities of O, O-Dialkyl-dithiophosphoryl-S-acetoxy Triazolo Compounds
  作者：Wen-Bin Chen、Gui-Yu Jin

  DOI：10.1080/10426500307939

  日期：2003.2.1

  In this article, we introduce organic phosphorus moiety into triazole ring to prepare O-dialkyl-dithiophosphoryl-S-acetoxy triazolo compounds and characterize their structures by elementary analysis and (HNMR)-H-1 and IR spectral data. From the results of biological activity screening, we found that the O-dialkyl-dithiophosphoryl-S-acetoxy triazolo compounds show lower fungicidal activities and their structures need to be optimized for the better.