silver(I) naphthalene-2-sulfonate | 46315-10-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: silver(I) naphthalene-2-sulfonate
• 英文别名: (naphthalene-2-sulfonato-κO)silver；silver(I) 2-naphthalenesulfonate；silver 2-naphthalenesulfonate；silver naphthalene sulfonate；naphthalene-2-sulfonic acid ; silver salt；Naphthalin-2-sulfonsaeure; Silbersalz；Silver beta-naphthalene sulfonate；silver;naphthalene-2-sulfonate
• CAS: 46315-10-0
• 化学式: Ag*C₁₀H₇O₃S
• 分子量: 315.098
• InChiKey: KZCVJSZYZCRFQL-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  1.74
• 重原子数：
  15
• 可旋转键数：
  0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  65.6
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  4-(4-(bis(2-hydroxyethyl)amino)styryl)-1-(2-hydroxyethyl)pyridin-1-ium bromide 、 silver(I) naphthalene-2-sulfonate 以 甲醇 为溶剂， 以65%的产率得到4-(4-(bis(2-hydroxyethyl)amino)styryl)-1-(2-hydroxyethyl)pyridin-1-ium naphthalene-2-sulfonate
  参考文献：
  名称：

  Aminostilbazolium Derivatives Substituted by Hydroxyethyl Groups for Second-Order Nonlinear Optics

  摘要：

  As DAST (1-methyl-4-{2-[4-(dimethylamino)phenyl]ethenyl}pyridinium p-toluenesulfonate) derivatives for improved crystal stability and inhibition of crystal water inclusion, 1-(2-hydroxyethyl)-4-(2-{4-[bis(2-hydroxyethyl)amino]phenyl}ethenyl)pyridinium salts 2 (2a-2l) and 1-(2-hydroxyethyl)-4-{2-[4-(diethylamino)phenyl]ethenyl}pyridinium salts 3 (3a-3l) were synthesized and their properties were investigated. Salts 3 were found to have no crystal water, and the cation with one hydroxyethyl group was effective to eliminate water inclusion in the crystals. Although the melting points of 2 were lower than those of the corresponding 3, decomposition temperatures of these chromophores were above 250 degrees C indicating their good thermal stability. Crystals of m-nitrobenzenesulfonate salt 3f was obtained without crystal water and showed SHG activity.

  DOI：

  10.1080/15421406.2011.566081
• 作为产物：
  描述：

  2-naphthalenesulfonic acid sodium salt 、 silver carbonate 在 H⁽¹⁺⁾ 作用下， 以 甲醇 、 乙腈 为溶剂， 以89%的产率得到silver(I) naphthalene-2-sulfonate
  参考文献：
  名称：

  Silver(I) Arylsulfonates:  A Systematic Study of “Softer” Hybrid Inorganic−Organic Solids

  摘要：

  The present study represents the first systematic examination of the effects on the layered structure of simple silver aryl-monosulfonates as the breadth of the pendant aryl group is increased beyond that where a simple "phosphonate-like" motif is sustainable. Five new silver arenesulfonates are reported. On the basis of comparison with Ag benzenesulfonate, a threshold of similar to6.4 Angstrom is proposed and confirmed as the critical breadth of an aryl group for a simple layered motif to be observed in silver sulfonates. Ag 1,1'-biphenyl-4-sulfonate (1) and Ag 2-naphthalenesulfonate (2) are below this threshold and so form simple layered networks, termed type 1 solids. When the pendant group is broadened to a 1-naphthyl group, the layer incorporates coordinated water to maintain a layered structure giving Ag 1-naphthalenesulfonate hemihydrate (3a). This more diffuse structure is termed a type 2 solid. For anhydrous Ag 1-naphthalenesulfonate (3) and Ag 1-pyrenesulfonate (4), the additional breadth is compensated for by the formation of Ag-pi interactions and the formation of type 3 solids. Interactions between the pendant groups are observed to play a significant role in the packing of the solid. All frameworks are characterized by single crystal and powder X-ray diffraction, IR, DSC-TGA, and elemental analysis. The significance of this adaptable framework is discussed along with implications for design of stacked arene arrays.

  DOI：

  10.1021/ic0491229

文献信息

• Hydrogen‐Bonding‐Assisted Cationic Aqua Palladium(II) Complex Enables Highly Efficient Asymmetric Reactions in Water
  作者：Taku Kitanosono、Tomoya Hisada、Yasuhiro Yamashita、Shū Kobayashi

  DOI：10.1002/anie.202009989

  日期：2021.2.15

  Metal‐bound water molecules have recently been recognized as a new facet of soft Lewis acid catalysis. Herein, a chiral palladium aqua complex was constructed that enables carbon–hydrogen bonds of indoles to be functionalized efficiently. We embraced a chiral 2,2′‐bipyridine as both ligand and hydrogen‐bond donor to configure a robust, yet highly Lewis acidic, chiral aqua complex in water. Whereas the

  金属结合的水分子最近被认为是软路易斯酸催化的一个新方面。本文中，构建了手性钯水络合物，该化合物使吲哚的碳氢键有效地被官能化。我们采用手性2,2'-联吡啶作为配体和氢键供体，以在水中构筑坚固而高度路易斯酸的手性水络合物。尽管在有机溶剂中或在无溶剂条件下无法控制对映选择性，但在水性环境中使用可使σ-吲哚基钯中间体以高度对映选择性的方式有效地反应。因此，这项工作描述了在温和的反应条件下以高度对映选择性的方式转化有机金属中间体的潜在强大的新方法。
• N-Methylquinolinium derivatives for photonic applications: Enhancement of electron-withdrawing character beyond that of the widely-used N-methylpyridinium
  作者：Jae-Hyeok Jeong、Ji-Soo Kim、Jochen Campo、Seung-Heon Lee、Woo-Yong Jeon、Wim Wenseleers、Mojca Jazbinsek、Hoseop Yun、O-Pil Kwon

  DOI：10.1016/j.dyepig.2014.07.016

  日期：2015.2

  styryl quinolinium push–pull chromophores have been designed and synthesized in order to examine the electron-withdrawing strength of various quinolinium electron acceptor groups, and their influence on the photophysical properties and in particular on the second-order nonlinear optical response. The static molecular first hyperpolarizabilities measured by long-wavelength hyper-Rayleigh scattering are

  为了研究各种喹啉电子受体基团的吸电子强度及其对光物理性质的影响，特别是对二阶非线性光学的影响，设计并合成了一系列π共轭苯乙烯基喹啉鎓推挽生色团。回复。发现通过长波超瑞利散射测量的静态分子第一超极化率遵循由NMR分析确定的其受体基团的吸电子强度的顺序。基于最强电子受体基团（1,2-和1,4-二甲基喹啉鎓）的喹啉鎓发色团显示出非常大的233和256×10 -30的第一超极化率 分别高于著名的和广泛使用的吡啶鎓类似物4-甲基苯磺酸的4-（4-（二甲氨基）苯乙烯基）-1-甲基吡啶鎓4-甲基苯磺酸盐的Esu值，其第一超极化率为183×10 -30  esu。与4-（4-（二甲基氨基）苯乙烯基）-1-甲基吡啶-4-甲基苯磺酸盐中使用的二甲基吡啶基相比，二甲基喹啉鎓电子受体基团表现出更高的吸电子强度，因此在光子应用中具有很高的潜力。
• [EN] ACID ADDITION SALTS OF 5-AMINOLEVULINIC ACID OR ITS DERIVATIVES<br/>[FR] SELS D'ADDITION ACIDE D'ACIDE 5-AMINOLEVULINIQUE OU DE SES DERIVES
  申请人：PHOTOCURE ASA

  公开号：WO2005092838A1

  公开（公告）日：2005-10-06

  The present invention provides an acid addition salt of 5-aminolevulinic acid (5-ALA) or of a 5-ALA derivative (e.g. a 5-ALA ester) with an acid which has a pKa of about 5 or less, preferably about 3 or less, with the proviso that the acid is other than hydrochloric acid. Particularly preferred salts are those derived from acids selected from the group comprising sulphonic acid and its derivatives, hydrobromic acid, sulfuric acid, nitric acid and phosphoric acid. The salts in accordance with the invention are particularly suitable for use as photosensitizing agents in diagnosis and photochemotherapy of disorders or abnormalities of external or internal surfaces of the body.

  本发明提供了一种5-氨基戊酸（5-ALA）或5-ALA衍生物（例如5-ALA酯）的酸加成盐，所述酸具有大约5或更低的pKa值，优选大约3或更低的pKa值，但该酸不包括盐酸。特别优选的盐是来源于选自磺酸及其衍生物，氢溴酸，硫酸，硝酸和磷酸组成的酸的盐。根据本发明的盐特别适用于用作诊断和光化疗治疗身体内外表面的疾病或异常的光敏剂。
• Acid Addition Salts Of-5-Aminolevulinic Acid Or Its Derivatives
  申请人：Braenden Jon Erik

  公开号：US20080064752A1

  公开（公告）日：2008-03-13

  The present invention provides an acid addition salt of 5-aminolevulinic acid (5-ALA) or of a 5-ALA derivative (e.g. a 5-ALA ester) with an acid which has a pKa of about 5 or less, preferably about 3 or less, with the proviso that the acid is other than hydrochloric acid. Particularly preferred salts are those derived from acids selected from the group comprising sulphonic acid and its derivatives, hydrobromic acid, sulfuric acid, nitric acid and phosphoric acid. The salts in accordance with the invention are particularly suitable for use as photosensitizing agents in diagnosis and photochemotherapy of disorders or abnormalities of external or internal surfaces of the body.

  本发明提供了5-氨基戊酸（5-ALA）或5-ALA衍生物（例如5-ALA酯）与具有pKa约为5或更低的酸（优选约为3或更低），但该酸不是盐酸的酸加成盐。特别优选的盐是由选自磺酸及其衍生物、氢溴酸、硫酸、硝酸和磷酸的酸所衍生的盐。本发明的盐特别适用于作为诊断和光化学治疗身体内部或外部表面的疾病或异常的光敏剂。
• ACID ADDITION SALTS OF 5-AMINOLEVULINIC ACID OR ITS DERIVATIVES
  申请人：BRAENDEN Jon Erik

  公开号：US20110125012A1

  公开（公告）日：2011-05-26

  The present invention provides an acid addition salt of 5-aminolevulinic acid (5-ALA) or of a 5-ALA derivative (e.g. a 5-ALA ester) with an acid which has a pKa of about 5 or less, preferably about 3 or less, with the proviso that the acid is other than hydrochloric acid. Particularly preferred salts are those derived from acids selected from the group comprising sulphonic acid and its derivatives, hydrobromic acid, sulfuric acid, nitric acid and phosphoric acid. The salts in accordance with the invention are particularly suitable for use as photosensitizing agents in diagnosis and photochemotherapy of disorders or abnormalities of external or internal surfaces of the body.

  本发明提供了一种5-氨基戊酸（5-ALA）或5-ALA衍生物（例如5-ALA酯）与pKa约为5或更低（优选约为3或更低）的酸的酸加成盐，但该酸不是盐酸。特别优选的盐是从磺酸及其衍生物、氢溴酸、硫酸、硝酸和磷酸组成的酸中选择的。根据本发明的盐特别适用于作为诊断和光化学治疗身体内外表面的疾病或异常的光敏剂。