bis-(1,3,3,3-tetrachloro-propyl)-ether | 22470-47-9

• 分子结构分类: 有机化合物 - 有机卤素化合物 - 有机氯化物
• 英文名称: bis-(1,3,3,3-tetrachloro-propyl)-ether
• 英文别名: Bis-(1,3,3,3-tetrachlor-propyl)-aether；1,1,1,3-Tetrachloro-3-(1,3,3,3-tetrachloropropoxy)propane
• CAS: 22470-47-9
• 化学式: C₆H₆Cl₈O
• 分子量: 377.737
• InChiKey: YEHHNHSVUHPNNT-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6
• 重原子数：
  15
• 可旋转键数：
  4
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  9.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  四氯化碳 、 二乙烯基醚 在 偶氮二异丁腈 作用下， 生成 (1,3,3,3-tetrachloro-propyl)-vinyl ether 、 bis-(1,3,3,3-tetrachloro-propyl)-ether
  参考文献：
  名称：

  Schostakowskii et al., Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1958, p. 756,759; engl. Ausg. S. 729, 731

  摘要：

  DOI：

文献信息

• A continuous process for the production of epichlorohydrin
  申请人：SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V.

  公开号：EP0247670A1

  公开（公告）日：1987-12-02

  A process for the production of epichlorohydrin is disclosed which comprises reacting allyl chloride, chlorine and water to form an intermediate, then rapid conversion and separation of epichloro­hydrin product; the epichlorohydrin-depleted reaction mixture is cooled and subjected to electrodialysis then reverse osmosis to concentrate and remove deleterious by-products, and at least a substantial portion of the resultant permeate is recycled to the reaction zone, thereby enabling reduced operating costs and/or improved yield.

  本发明公开了一种生产环氧氯丙烷的工艺，该工艺包括烯丙基氯、氯和水反应生成中间体，然后快速转化和分离环氧氯丙烷产物；冷却去环氧氯丙烷的反应混合物，然后进行电渗析和反渗透以浓缩和去除有害副产物，所产生的渗透物至少有很大一部分被回收到反应区，从而降低了操作成本和/或提高了产量。
• A continuous process for the production of dichlorohydrin
  申请人：SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V.

  公开号：EP0256576A1

  公开（公告）日：1988-02-24

  A continuous process for the production of dichlorohydrin which comprises in sequence (a) reacting allyl chloride, water and chlorine in a first reaction zone to form an aqueous reaction mixture of dichlorohydrin and reaction by-products, (b) passing the reaction mixture as feed to an electrodialysis zone, said electrodialysis zone having a feed inlet and a diluate (product) outlet, a concentrate inlet and a concentrate outlet, (c) electrodialyzing said feed in said electrodialysis zone to remove ions formed during the reaction from said feed into a concentrate stream and to obtain a diluate stream containing dichlorohydrin and having a lower ion content than said feed, (d) adding a basic substance to said diluate stream to neutralize at least a majority of the hydrogen ions present in said diluate while maintaining the pH of said diluate below 6.9, (e) subjecting said diluate to reverse osmosis in a reverse osmosis zone to obtain: (1) a retentate stream having a higher dichlorohydrin concentration than said diluate, and (2) a permeate stream of relatively pure water, (f) recycling a major portion of said permeate stream to the reaction zone, (g) passing at least a portion of at least one of: (1) said permeate stream and/or (2) said retentate stream, to the concentrate inlet of said electrodialysis zone, (h) withdrawing an ion concentrate stream from said electrodialysis zone, and (i) withdrawing any retentate stream which was not passed to said electrodialysis zone.

  一种生产二氯海德林的连续工艺，包括以下步骤 (a) 在第一反应区使烯丙基氯、水和氯反应，形成二氯海德林和反应副产物的水反应混合物、 (b) 将反应混合物作为进料送入电渗析区，所述电渗析区有一个进料口和一个稀释液（产品）出口，一个浓缩物进料口和一个浓缩物出口、 (c) 在所述电渗析区对所述进料进行电渗析，以去除反应过程中形成的离子，使其从所述进料进入浓缩物流，并获得含有二氯海德林且离子含量低于所述进料的稀释液流、 (d) 向所述稀释液中加入碱性物质，以中和至少大部分存在于所述稀释液中的氢离子，同时将所述稀释液的 pH 值保持在 6.9 以下、 (e) 在反渗透区对所述稀释液进行反渗透，以获得：(1) 比所述稀释液具有更高二氯海因浓度的回流液，以及 (2) 相对纯净的渗透水流、 (f) 将所述渗透流的大部分回收至反应区、 (g) 将 (1) 所述渗透液流和/或 (2) 所述回流液流中的至少一部分流向所述电渗析区的浓缩物入口、 (h) 从所述电渗析区提取离子浓缩物流，以及 (i) 抽出未进入所述电渗析区的任何回流液。
• Electronic ID database and detection method for pesticide compounds in edible Agro-products based on GC-Q-Orbitrap
  申请人：CHINESE ACADEMY OF INSPECTION AND QUARANTINE

  公开号：US11181512B2

  公开（公告）日：2021-11-23

  Disclosed is an electronic ID database and detection method for pesticide compounds in edible agro-products based on GC-Q-Orbitrap. The electronic ID database includes a collection of various pesticide compounds electronic ID information and is sorted according to retention time in the electronic ID. The electronic ID contains pesticide compounds information, retention time, mass spectrum, fragment ions information and intelligent matching value. The detection method includes sample pretreatment procedures, setting GC-Q-Orbitrap operating conditions and screening procedures for pesticide residues in samples, wherein setting GC-Q-Orbitrap operating conditions includes setting suitable chromatography and mass spectrometry conditions. In pesticide residue screening procedures, firstly, the retention time is used to find out pesticide compounds in electronic ID database. If there is a match, the corresponding electronic ID information is extracted. Then the intelligent matching value is compared, if it is less than threshold value, the result is recorded and displayed, and the screening is completed.

  本发明公开了一种基于 GC-Q-Orbitrap 的食用农产品中农药化合物电子 ID 数据库和检测方法。电子标识数据库包括各种农药化合物电子标识信息的集合，并根据电子标识中的保留时间进行排序。电子 ID 包含农药化合物信息、保留时间、质谱、碎片离子信息和智能匹配值。检测方法包括样品前处理程序、GC-Q-Orbitrap 操作条件设置和样品中农药残留筛选程序，其中 GC-Q-Orbitrap 操作条件设置包括设置合适的色谱和质谱条件。在农药残留筛选程序中，首先利用保留时间在电子 ID 数据库中查找农药化合物。如果匹配，则提取相应的电子 ID 信息。然后比较智能匹配值，如果小于阈值，则记录并显示结果，完成筛选。
• Process for the production of dichlorohydrin
  申请人：SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V.

  公开号：EP0247671B1

  公开（公告）日：1990-07-18
• ELECTRONIC ID DATABASE AND DETECTION METHOD FOR PESTICIDE COMPOUNDS IN EDIBLE AGRO-PRODUCTS BASED ON GC-Q-ORBITRAP
  申请人：CHINESE ACADEMY OF INSPECTION AND QUARANTINE

  公开号：US20210285921A1

  公开（公告）日：2021-09-16

  Disclosed is an electronic ID database and detection method for pesticide compounds in edible agro-products based on GC-Q-Orbitrap. The electronic ID database includes a collection of various pesticide compounds electronic ID information and is sorted according to retention time in the electronic ID. The electronic ID contains pesticide compounds information, retention time, mass spectrum, fragment ions information and intelligent matching value. The detection method includes sample pre-treatment procedures, setting GC-Q-Orbitrap operating conditions and screening procedures for pesticide residues in samples, wherein setting GC-Q-Orbitrap operating conditions includes setting suitable chromatography and mass spectrometry conditions. In pesticide residue screening procedures, firstly, the retention time is used to find out pesticide compounds in electronic ID database. If there is a match, the corresponding electronic ID information is extracted. Then the intelligent matching value is compared, if it is less than threshold value, the result is recorded and displayed, and the screening is completed.