4-(1-phenyl-1-methylcyclobutane-3-yl)-2-(2-hydroxy-1-naphtylidene)thiazole | 354553-31-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: 4-(1-phenyl-1-methylcyclobutane-3-yl)-2-(2-hydroxy-1-naphtylidene)thiazole
• 英文别名: 1-[[4-(3-Methyl-3-phenylcyclobutyl)-1,3-thiazol-2-yl]iminomethyl]naphthalen-2-ol
• CAS: 354553-31-4
• 化学式: C₂₅H₂₂N₂OS
• 分子量: 398.528
• InChiKey: NHLIPSZVSLLJLW-UHFFFAOYSA-N

物化性质

• 熔点：
  154 °C
• 沸点：
  605.0±65.0 °C(predicted)
• 密度：
  1.25±0.1 g/cm3(Temp: 20 °C; Press: 760 Torr)(predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  6.4
• 重原子数：
  29
• 可旋转键数：
  4
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.2
• 拓扑面积：
  73.7
• 氢给体数：
  1
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  4-(1-phenyl-1-methylcyclobutane-3-yl)-2-(2-hydroxy-1-naphtylidene)thiazole 、 zinc(II) acetate dihydrate 以 甲醇 为溶剂， 以67%的产率得到Zn(4-(1-phenyl-1-methylcyclobutane-3-yl)-2-(2-oxy-1-naphtylidene)thiazole)2
  参考文献：
  名称：

  A NEW CYCLOBUTANE-SUBSTITUTED SCHIFF BASE LIGAND AND ITS Co(II), Cu(II), Ni(II), AND Zn(II) COMPLEXES

  摘要：

  A new ligand, 4-(1-phenyl-1-methylcyclobutyl-3-yl)-2-(2-hydroxy-1-naphtylidene)thiazole (LH), has been synthesized starting from 1-phenyl-1-methyl-3-(2-chloro-1-oxoethyl) cyclobutane, thiourea and 2-hydroxy-1-napthalaldehyde. Mononuclear complexes with a metal-ligand ratio of 1:2 have been prepared with Co(II), Cu(II), Ni(II) and Zn(II) salts. Structures of the ligand and its complexes are suggested based on elemental analyses, IR, C-13 and H-1 NMR spectra, magnetic susceptibility measurements and thermogravimetric analyses (TGA).

  DOI：

  10.1081/sim-100002045

文献信息

• A NEW CYCLOBUTANE-SUBSTITUTED SCHIFF BASE LIGAND AND ITS Co(II), Cu(II), Ni(II), AND Zn(II) COMPLEXES
  作者：Alaaddin Çukurovali、Ibrahim Yilmaz、Misir Ahmedzade、Habibe Özmen

  DOI：10.1081/sim-100002045

  日期：2001.2.28

  A new ligand, 4-(1-phenyl-1-methylcyclobutyl-3-yl)-2-(2-hydroxy-1-naphtylidene)thiazole (LH), has been synthesized starting from 1-phenyl-1-methyl-3-(2-chloro-1-oxoethyl) cyclobutane, thiourea and 2-hydroxy-1-napthalaldehyde. Mononuclear complexes with a metal-ligand ratio of 1:2 have been prepared with Co(II), Cu(II), Ni(II) and Zn(II) salts. Structures of the ligand and its complexes are suggested based on elemental analyses, IR, C-13 and H-1 NMR spectra, magnetic susceptibility measurements and thermogravimetric analyses (TGA).