[1-Naphthalen-1-yl-meth-(Z)-ylidene]-phenyl-amine | 78569-39-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: [1-Naphthalen-1-yl-meth-(Z)-ylidene]-phenyl-amine
• CAS: 78569-39-8
• 化学式: C₁₇H₁₃N
• 分子量: 231.297
• InChiKey: WNYBWTSSOIEBMP-AQTBWJFISA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.59
• 重原子数：
  18.0
• 可旋转键数：
  2.0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  12.36
• 氢给体数：
  0.0
• 氢受体数：
  1.0

反应信息

• 作为反应物：
  描述：

  (2R)-2-<2-(tert-Butyldimethylsiloxy)pyrrol-1-yl>-2-phenylethylbenzoate 、 [1-Naphthalen-1-yl-meth-(Z)-ylidene]-phenyl-amine 在 ytterbium(III) triflate 作用下， 以 二氯甲烷 为溶剂， 以90%的产率得到[(2R)-2-[2-[anilino(naphthalen-1-yl)methyl]-5-oxo-2H-pyrrol-1-yl]-2-phenylethyl] benzoate
  参考文献：
  名称：

  Ytterbium triflate-catalyzed reactions of imines with a chiral non-racemic silyloxypyrrole

  摘要：

  In the presence of a catalytic amount of ytterbium triflate the reactions of various aromatic imines with a chiral non-racemic silyloxypyrrole proceeded smoothly to afford the corresponding aldol-type adducts in go od yields and diastereoselectivities. (C) 2000 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0040-4039(00)00625-0
• 作为产物：
  描述：

  1-萘甲醛 、 苯胺 生成 [1-Naphthalen-1-yl-meth-(Z)-ylidene]-phenyl-amine
  参考文献：
  名称：

  Ytterbium triflate-catalyzed reactions of imines with a chiral non-racemic silyloxypyrrole

  摘要：

  In the presence of a catalytic amount of ytterbium triflate the reactions of various aromatic imines with a chiral non-racemic silyloxypyrrole proceeded smoothly to afford the corresponding aldol-type adducts in go od yields and diastereoselectivities. (C) 2000 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0040-4039(00)00625-0

文献信息

• Polymer-Bound Pyridine-Bis(oxazoline). Preparation through Click Chemistry and Evaluation in Asymmetric Catalysis
  作者：Mélanie Tilliet、Stina Lundgren、Christina Moberg、Vincent Levacher

  DOI：10.1002/adsc.200700112

  日期：2007.9.3

  A pyridine-bis(oxazoline) ligand was efficiently immobilized by copper(I)-catalyzed azide-alkyne cycloaddition onto a polystyrene resin. The so obtained click-pybox resin 1a was associated with various metal salts (YbCl3, LuCl3, CuOTf) and the resulting resin-bound catalysts were explored in ring-opening of cyclohexene oxide, silylcyanation of benzaldehyde and alkynylation of imines. These new polymer-supported

  通过铜（I）催化的叠氮化物-炔烃环加成反应将吡啶-双（恶唑啉）配体有效地固定在聚苯乙烯树脂上。如此获得的点击式box盒树脂1a与各种金属盐（YbCl 3，LuCl 3，CuOTf）缔合，并在环己烯氧化物的开环，苯甲醛的甲硅烷基氰化和亚胺的炔基化反应中探索了与树脂结合的催化剂。这些新型的聚合物负载型催化剂在催化活性，对映选择性和可回收性方面表现出良好至优异的性能。
• Ytterbium triflate-catalyzed reactions of imines with a chiral non-racemic silyloxypyrrole
  作者：Bruno Dudot、Jacques Royer、Mireille Sevrin、Pascal George

  DOI：10.1016/s0040-4039(00)00625-0

  日期：2000.6

  In the presence of a catalytic amount of ytterbium triflate the reactions of various aromatic imines with a chiral non-racemic silyloxypyrrole proceeded smoothly to afford the corresponding aldol-type adducts in go od yields and diastereoselectivities. (C) 2000 Elsevier Science Ltd. All rights reserved.