potassium (2-diethylaminoethyl)dithiocarbamate | 1161011-21-7

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: potassium (2-diethylaminoethyl)dithiocarbamate
• 英文别名: KS2CN(CH2CH2NEt2)2；potassium;N,N-bis[2-(diethylamino)ethyl]carbamodithioate
• CAS: 1161011-21-7
• 化学式: C₁₃H₂₈N₃S₂*K
• 分子量: 329.616
• InChiKey: NNASLKQTWBNPNQ-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  -1.19
• 重原子数：
  19
• 可旋转键数：
  10
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.92
• 拓扑面积：
  42.8
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  potassium (2-diethylaminoethyl)dithiocarbamate 、 copper diacetate 以 甲醇 为溶剂， 以78%的产率得到copper(II) (2-diethylaminoethyl)dithiocarbamate
  参考文献：
  名称：

  Functionalised dithiocarbamate complexes: Synthesis and molecular structures of 2-diethylaminoethyl and 3-dimethylaminopropyl dithiocarbamate complexes [M{S2CN(CH2CH2NEt2)2}n] and [M{S2CN(CH2CH2CH2NMe2)2}n] (n=2, M=Ni, Cu, Zn, Pd; n=3, M=Co)

  摘要：

  The amine-functionalised dithiocarbamate salts K[S2CN(CH2CH2NEt2)(2)] and K[S2CN(CH2CH2CH2NMe2)(2)] have been prepared and used for the synthesis of a number of bis and tris-dithiocarbamate complexes. The molecular structures of five of these namely, [M{S2CN(CH2CH2NEt2)(2)}(2)] (M = Cu, Ni), [M{S2CN(CH2CH2CH2NMe2)(2)}(2)] (M = Cu, Pd) and [Co{S2CN(CH2CH2CH2NMe2)(2)}(3)], have been elucidated by X-ray crystallography. (C) 2008 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2008.09.030

文献信息

• The functionalisation of ruthenium(ii) and osmium(ii) alkenyl complexes with amine- and alkoxy-terminated dithiocarbamates
  作者：Saira Naeem、Eleanor Ogilvie、Andrew J. P. White、Graeme Hogarth、James D. E. T. Wilton-Ely

  DOI：10.1039/b925536b

  日期：——

  The complex cis-[RuCl2(dppm)2] reacts with the amine-terminated dithiocarbamates KS2CN(CH2CH2NEt2)2 and KS2CN(CH2CH2CH2NMe2)2 to form the compounds [RuS2CN(CH2CH2NEt2)2}(dppm)2]+ and [RuS2CN(CH2CH2CH2NMe2)2}(dppm)2]+, respectively. The methoxy-terminated dithiocarbamate compound [RuS2CN(CH2CH2OMe)2}(dppm)2]+ was also prepared from the same precursor using KS2CN(CH2CH2OMe)2. The alkenyl complexes

  复杂 顺式-[RuCl 2（dppm）2 ]与胺端基的二硫代氨基甲酸酯KS 2 CN（CH 2 CH 2 NEt 2）2和KS 2 CN（CH 2 CH 2 CH 2 NMe 2）2反应形成化合物[Ru S 2 CN（CH 2 CH 2 NEt 2）2 }（dppm）2 ] +和[Ru S 2 CN（CH 2 CH 2 CH 2 NMe 2）2 }（dppm）2 ]+。甲氧基封端二硫代氨基甲酸酯还使用KS 2 CN（CH 2 CH 2 OMe）2从相同的前体制备化合物[Ru S 2 CN（CH 2 CH 2 OMe）2 }（dppm）2 ] +。烯基配合物[RuRCl（CO）（BTD）（PPh 3）2]（R = CH CHBu吨，CH CHC 6 H ^ 4 ME-4，CH CHCPh 2 OH），的[Ru（C（C CBU吨）CHBu吨）氯（CO）（PPH 3）2 ]和[OS（CH CHC
• Functionalised dithiocarbamate complexes: Synthesis and molecular structures of 2-diethylaminoethyl and 3-dimethylaminopropyl dithiocarbamate complexes [M{S2CN(CH2CH2NEt2)2}n] and [M{S2CN(CH2CH2CH2NMe2)2}n] (n=2, M=Ni, Cu, Zn, Pd; n=3, M=Co)
  作者：Graeme Hogarth、Ebony-Jewel C.-R.C.R. Rainford-Brent、Shariff E. Kabir、Idris Richards、James D.E.T. Wilton-Ely、Qi Zhang

  DOI：10.1016/j.ica.2008.09.030

  日期：2009.4

  The amine-functionalised dithiocarbamate salts K[S2CN(CH2CH2NEt2)(2)] and K[S2CN(CH2CH2CH2NMe2)(2)] have been prepared and used for the synthesis of a number of bis and tris-dithiocarbamate complexes. The molecular structures of five of these namely, [MS2CN(CH2CH2NEt2)(2)}(2)] (M = Cu, Ni), [MS2CN(CH2CH2CH2NMe2)(2)}(2)] (M = Cu, Pd) and [CoS2CN(CH2CH2CH2NMe2)(2)}(3)], have been elucidated by X-ray crystallography. (C) 2008 Elsevier B.V. All rights reserved.