N-(pyrid-2-ylmethyl)naphthalenesulfonylamide | 312594-33-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: N-(pyrid-2-ylmethyl)naphthalenesulfonylamide
• 英文别名: N-(2-methylpyridyl)naphthalenesulfonylamide；N-(pyryd-2-ylmethyl)naphthalenesulfonamide；N-(pyridin-2-ylmethyl)naphthalene-2-sulfonamide
• CAS: 312594-33-5
• 化学式: C₁₆H₁₄N₂O₂S
• 分子量: 298.365
• InChiKey: BYNPZXLJLAZBOM-UHFFFAOYSA-N

物化性质

• 溶解度：
  36.9 [ug/mL]

计算性质

• 辛醇/水分配系数(LogP)：
  2.6
• 重原子数：
  21
• 可旋转键数：
  4
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.06
• 拓扑面积：
  67.4
• 氢给体数：
  1
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  copper diacetate 、 N-(pyrid-2-ylmethyl)naphthalenesulfonylamide 以 N,N-二甲基甲酰胺 为溶剂， 以20%的产率得到bis(μ-acetato)-bis(μ-hydroxo)-bis[N-(pyryd-2-ylmethyl)naphthalenesulfonylamidate]tricopper(II)
  参考文献：
  名称：

  线性混合 μ-乙酸酯、μ-羟基三核铜 (II) 配合物与 N-磺酰胺衍生物的强铁磁耦合 - 合成、结构、EPR 和磁性

  摘要：

  DOI：

  10.1002/1099-0682(200208)2002:8<2094::aid-ejic2094>3.0.co;2-z
• 作为产物：
  描述：

  2-氨甲基吡啶 、 2-萘磺酰氯 以71%的产率得到N-(pyrid-2-ylmethyl)naphthalenesulfonylamide
  参考文献：
  名称：

  线性混合 μ-乙酸酯、μ-羟基三核铜 (II) 配合物与 N-磺酰胺衍生物的强铁磁耦合 - 合成、结构、EPR 和磁性

  摘要：

  DOI：

  10.1002/1099-0682(200208)2002:8<2094::aid-ejic2094>3.0.co;2-z

文献信息

• Influence of tetrahedral distortion of CuN4 complexes on spectroscopic properties. Synthesis, characterization and crystal structures of [Cu(N-(2-methylpyridyl)benzenesulfonylamidate)2], [Cu(N-(2-methylpyridyl)toluenesulfonylamidate)2] and [Cu(N-(2-methylpyridyl)naphthalenesulfonylamidate)2] compounds
  作者：Laura Gutierrez、Gloria Alzuet、Joaquı́n Borrás、Malva Liu-González、Francisco Sanz、Alfonso Castiñeiras

  DOI：10.1016/s0277-5387(01)00717-3

  日期：2001.4

  A series of new N-sulfonamide ligands and their copper(II) complexes, [Cu(N-(2-methylpyridyl)toluenesulfonylamidate)(2)] (1), [Cu(N-(2-methylpyridyl)benzenesulfonylamidate)(2)] (2) and [Cu(N-(2-methylpyridyl)naphthalenesulfonylamidate)(2)] (3), have been synthesized and characterized. Single crystal X-ray analysis of the three-complexes revealed that all of them present a tetracoordinate CuN4 chromophore. The ligands act as bidentate, coordinating the metal ion through the pyridine and sulfonamido N atoms. The main structural difference among the compounds is the varied degree of distortion of square-planar stereochemistry. Complex 1 exhibits a regular square-planar geometry. In complexes 2 and 3 the tetrahedrality values of 50.2 degrees and 39.0 degrees respectively indicate a strong distortion. EHMO calculations on idealized models show the correlation between the geometrical distortion and the spectroscopic properties. (C) 2001 Elsevier Science B.V. All rights reserved.
• ABA Receptor Agonists for Increased Plant Stress Resistance
  申请人：Xu Yong

  公开号：US20130045952A1

  公开（公告）日：2013-02-21

  The present invention relates to ABA agonist compounds which increase plant stress resistance. The invention also relates to methods of using these compounds. The invention further relates to compositions and formulations comprising the ABA agonist compounds, and uses thereof.
• Strong Ferromagnetic Coupling in Linear Mixed μ-Acetato, μ-Hydroxo Trinuclear Copper(II) Complexes withN-sulfonamide derivatives − Synthesis, Structure, EPR and Magnetic Properties
  作者：Laura Gutierrez、Gloria Alzuet、Jose A. Real、Joan Cano、Joaquin Borrás、Alfonso Castiñeiras

  DOI：10.1002/1099-0682(200208)2002:8<2094::aid-ejic2094>3.0.co;2-z

  日期：2002.8