1-(4-bromonaphthalen-1-yl)-1H-pyrrole | 1432023-57-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: 1-(4-bromonaphthalen-1-yl)-1H-pyrrole
• 英文别名: 1-(4-Bromonaphthalen-1-yl)pyrrole；1-(4-bromonaphthalen-1-yl)pyrrole
• CAS: 1432023-57-8
• 化学式: C₁₄H₁₀BrN
• 分子量: 272.144
• InChiKey: XORDSTLFKNMXNG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.3
• 重原子数：
  16
• 可旋转键数：
  1
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  4.9
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  2,5-二甲氧基四氢呋喃 、 4-溴-1-萘胺 在 ionic liquid immobilized on γ-Fe₂O₃(at)SiO₂ nanoparticles 作用下， 以 水 为溶剂， 反应 1.0h， 以95%的产率得到1-(4-bromonaphthalen-1-yl)-1H-pyrrole
  参考文献：
  名称：

  A recyclable magnetic nanoparticles supported antimony catalyst for the synthesis of N-substituted pyrroles in water

  摘要：

  A new magnetic nanoparticle-supported catalyst for Clauson-Kaas reaction. The corresponding N-substituted pyrroles in by magnetic separation and recycled for antimony catalyst was prepared and evaluated as a recoverable reaction proceeds efficiently in aqueous medium to give the high yield. The immobilized catalyst could be easily recovered six times without significant loss of its catalytic activity. (c) 2013 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.apcata.2013.03.005

文献信息

• A recyclable magnetic nanoparticles supported antimony catalyst for the synthesis of N-substituted pyrroles in water
  作者：Fei-Ping Ma、Pei-He Li、Bao-Le Li、Li-Ping Mo、Ning Liu、Hui-Jun Kang、Ya-Nan Liu、Zhan-Hui Zhang

  DOI：10.1016/j.apcata.2013.03.005

  日期：2013.4

  A new magnetic nanoparticle-supported catalyst for Clauson-Kaas reaction. The corresponding N-substituted pyrroles in by magnetic separation and recycled for antimony catalyst was prepared and evaluated as a recoverable reaction proceeds efficiently in aqueous medium to give the high yield. The immobilized catalyst could be easily recovered six times without significant loss of its catalytic activity. (c) 2013 Elsevier B.V. All rights reserved.