2-羟基-N,N-双(2-羟基乙基)-N-甲基-3-(辛氧基)-1-丙胺硫酸甲酯(盐) | 70776-69-1

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 有机硫酸及其衍生物
• 中文名称: 2-羟基-N,N-双(2-羟基乙基)-N-甲基-3-(辛氧基)-1-丙胺硫酸甲酯(盐)
• 英文名称: 2-Hydroxy-N,N-bis(2-hydroxyethyl)-N-methyl-3-octyloxypropylammonium methyl sulfate
• 英文别名: bis(2-hydroxyethyl)-(2-hydroxy-3-octoxypropyl)-methylazanium;methyl sulfate
• CAS: 70776-69-1
• 化学式: C17H39NO8S
• 分子量: 417.6
• InChiKey: CJULUAHYEXWWCU-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  0.25
• 重原子数：
  27
• 可旋转键数：
  15
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  145
• 氢给体数：
  3
• 氢受体数：
  8

反应信息

• 作为产物：
  描述：

  1-[二(2-羟基乙基)氨基]-3-(辛基氧基)丙-2-醇 、 硫酸二甲酯 生成 2-羟基-N,N-双(2-羟基乙基)-N-甲基-3-(辛氧基)-1-丙胺硫酸甲酯(盐)
  参考文献：
  名称：

  POZNIAK, RYSZARD;PASTERNAK, ALEKSY;DUL, MARIAN, PRZEM. CHEM., 68,(1989) N, C. 175-177, 146, 147

  摘要：

  DOI：

文献信息

• Method of synthesizing glycidyl ether compounds in the absence of water and organic solvents
  申请人：KOREA RESEARCH INSTITUTE OF CHEMICAL TECHNOLOGY

  公开号：US20020004605A1

  公开（公告）日：2002-01-10

  The present invention relates to a method of synthesizing glycidyl ether compounds without the addition of solvent. In particular, the present invention provides the improved preparation of the glycidyl ethers by using fatty alcohols with epichlorohydrin in the presence of alkali metal hydroxide and phase-transfer catalysts in the appropriate molar ratios of them without water and organic solvents.

  本发明涉及一种在无需添加溶剂的情况下合成环氧丙烷醚化合物的方法。具体而言，本发明通过在适当的摩尔比下，利用脂肪醇与环氧氯丙烷在碱金属氢氧化物和相转移催化剂的存在下，无需水和有机溶剂，改进了环氧丙烷醚的制备方法。
• NOVEL ALKOXYLATE-CONTAINING COMPOSITIONS
  申请人：DOW GLOBAL TECHNOLOGIES INC.

  公开号：EP2152653A1

  公开（公告）日：2010-02-17
• NOVEL ALKYLOXY-ETHERS AND ALKOXYLATES THEREOF
  申请人：DOW GLOBAL TECHNOLOGIES INC.

  公开号：EP2152652A1

  公开（公告）日：2010-02-17
• NOVEL BRANCHED ALKOXYLATES
  申请人：DOW GLOBAL TECHNOLOGIES INC.

  公开号：EP2139833A1

  公开（公告）日：2010-01-06
• NOVEL ALKOXY-ETHERS AND ALKOXYLATES THEREOF
  申请人：Thoen Johan A.

  公开号：US20100179354A1

  公开（公告）日：2010-07-15

  Novel 1,3-dialkyloxy-2-propanol and alkoxylates thereof may be prepared in good yield by a convenient process comprising adding epichlorohydrin to a stoichiometric excess of alcohol, wherein the ratio of alcohol:epichlorohydrin is at least about 3:1, preferably in the presence of a Group 1A metal hydroxide and a phase transfer catalyst. The result shows excellent selectivity of to the 1,3-substitution positions, and the alkyl chain may be saturated or unsaturated and may contain one or more heteroatoms. The alkoxylates may include repeating alkoxy units in the 2-position. The compositions are useful as surfactants, diluents, and the like.