4,4'-(ethyne-1,2-diyl)bis(2-methylphenol) | 1129260-37-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 酚类
• 英文名称: 4,4'-(ethyne-1,2-diyl)bis(2-methylphenol)
• 英文别名: 4-[2-(4-Hydroxy-3-methylphenyl)ethynyl]-2-methylphenol
• CAS: 1129260-37-2
• 化学式: C₁₆H₁₄O₂
• 分子量: 238.286
• InChiKey: ITRXTLKMDHHHJK-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4
• 重原子数：
  18
• 可旋转键数：
  2
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.12
• 拓扑面积：
  40.5
• 氢给体数：
  2
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  4-碘-2-甲基苯酚 、 乙炔 在 copper(l) iodide 、 1,8-二氮杂双环[5.4.0]十一碳-7-烯 、 三苯基膦 作用下， 以 1,4-二氧六环 、 水 为溶剂， 反应 10.0h， 以62%的产率得到4,4'-(ethyne-1,2-diyl)bis(2-methylphenol)
  参考文献：
  名称：

  Synthesis of Functionalized Bisarylacetylene Derivatives from Acetylene Gas Over Nano-sized Carbon Ball Supported Palladium Catalyst

  摘要：

  DOI：

  10.5012/bkcs.2010.31.7.2097

文献信息

• FIRE-RETARDANT POLYARYLATE RESIN CONTAINING DIHYDROXYPHENYLACETYLENE AND COMPOSITIONS THEREOF
  申请人：KIM Kyoung Mahn

  公开号：US20100298478A1

  公开（公告）日：2010-11-25

  Provided is a flame-retardant polyarylate resin and a composition thereof, and more particularly, a polyarylate resin prepared by co-polymerizing 4,4′-dihydroxyphenylacetylene (DHPA), phthaloyl chloride (PC) and bishydroxyphenol (BHP) and a composition of the polyarylate resin. The polyarylate resin has lower heat release capacity than a conventional resin or a resin containing a halogen-based flame-retardant, is environmentally friendly, does not produce toxic materials, and has more excellent flame-retardancy than a conventional halogen-based flame-retardant and a flame-retardant resin. In addition, the polyarylate resin has excellent processibility and compatibility due to high solubility in a commonly used industrial solvent and has excellent thermal stability due to a high molecular weight.
• US7943722B2
  申请人：——

  公开号：US7943722B2

  公开（公告）日：2011-05-17
• Synthesis of Functionalized Bisarylacetylene Derivatives from Acetylene Gas Over Nano-sized Carbon Ball Supported Palladium Catalyst
  作者：Eul-Kgun Yum、Jong-Woo Son、Soo-Kwang Kim、Sung-Nam Kim、Kyung-Mahn Kim、Chul-Wee Lee

  DOI：10.5012/bkcs.2010.31.7.2097

  日期：2010.7.20