5-dimethylaminopentan-2-ol | 27384-45-8

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: 5-dimethylaminopentan-2-ol
• 英文别名: 5-dimethylamino-pentan-2-ol；1-Dimethylamino-4-hydroxypentan；1-Dimethylamino-pentanol-(4)；1-Dimethylaminopentanol-(4)；5-(Dimethylamino)pentan-2-ol
• CAS: 27384-45-8
• 化学式: C₇H₁₇NO
• mdl: MFCD16146405
• 分子量: 131.218
• InChiKey: RMZCZIIPRKFFPZ-UHFFFAOYSA-N

物化性质

• 沸点：
  79 °C(Press: 14 Torr)
• 密度：
  0.879±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  0.7
• 重原子数：
  9
• 可旋转键数：
  4
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  23.5
• 氢给体数：
  1
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  5-dimethylaminopentan-2-ol 、 碘甲烷 以 乙醚 为溶剂， 生成 4-hydroxypentyltrimethylammonium iodide
  参考文献：
  名称：

  De Amici; De Micheli; Pratesi, Farmaco, Edizione Scientifica, 1987, vol. 42, # 12, p. 921 - 930

  摘要：

  DOI：
• 作为产物：
  描述：

  5-二甲氨基戊烷-2-酮 在 sodium tetrahydroborate 作用下， 生成 5-dimethylaminopentan-2-ol
  参考文献：
  名称：

  De Amici; De Micheli; Pratesi, Farmaco, Edizione Scientifica, 1987, vol. 42, # 12, p. 921 - 930

  摘要：

  DOI：

文献信息

• METAL ALKOXIDE COMPOUND, THIN-FILM-FORMING MATERIAL, METHOD FOR PRODUCING THIN FILM, AND ALCOHOL COMPOUND
  申请人：ADEKA CORPORATION

  公开号：US20150175642A1

  公开（公告）日：2015-06-25

  Disclosed is a metal alkoxide compound having physical properties suitable for a material for forming thin films by CVD, and particularly, a metal alkoxide compound having physical properties suitable for a material for forming metallic-copper thin films. A metal alkoxide compound is represented by general formula (I). A thin-film-forming material including the metal alkoxide compound is described as well. (In the formula, R 1 represents a methyl group or an ethyl group, R 2 represents a hydrogen atom or a methyl group, R 3 represents a C 1-3 linear or branched alkyl group, M represents a metal atom or a silicon atom, and n represents the valence of the metal atom or silicon atom.

  揭示了一种具有适合用于CVD形成薄膜材料的物理性质的金属烷氧化物化合物，特别是一种具有适合用于形成金属铜薄膜材料的金属烷氧化物化合物。金属烷氧化物化合物由通式（I）表示。还描述了包括金属烷氧化物化合物的薄膜形成材料。（在公式中，R1代表甲基基团或乙基基团，R2代表氢原子或甲基基团，R3代表C1-3直链或支链烷基基团，M代表金属原子或硅原子，n代表金属原子或硅原子的价。
• METHOD FOR THE CONTINUOUS PRODUCTION OF AN AMINE USING AN ALUMINUM-COPPER CATALYST
  申请人：Ernst Martin

  公开号：US20110172430A1

  公开（公告）日：2011-07-14

  Process for the continuous preparation of an amine by reaction of a primary or secondary alcohol, aldehyde and/or ketone with hydrogen and a nitrogen compound selected from the group consisting of ammonia, primary and secondary amines at a temperature in the range from 60 to 300° C. in the presence of a catalyst comprising copper oxide and aluminum oxide, wherein the reaction takes place in the gas phase and the catalytically active composition of the catalyst before reduction with hydrogen comprises PS from 20 to 75% by weight of aluminum oxide (Al 2 O 3 ), from 20 to 75% by weight of oxygen-comprising compounds of copper, calculated as CuO, from 0 to 2% by weight of oxygen-comprising compounds of sodium, calculated as Na 2 O, and less than 5% by weight of oxygen-comprising compounds of nickel, calculated as NiO, and the shaped catalyst body has a pellet shape having a diameter in the range from 1 to 4 mm and a height in the range from 1 to 4 mm.

  通过在60至300°C温度范围内，在气相中存在铜氧化物和氧化铝的催化剂的情况下，通过将一级或二级醇、醛和/或酮与氢气和从氨、一级和二级胺组成的氮化合物中选择的氮化合物反应，连续制备胺的过程，其中在还原之前，催化剂的催化活性组成包括氧化铝（Al2O3）的重量百分比为20至75%，氧化铜的重量百分比为20至75%，计为CuO的氧化物的重量百分比为0至2%，计为Na2O的氧化物的重量百分比为小于5%，计为NiO的氧化物的重量百分比为小于5%，并且成型催化剂体具有直径在1至4毫米范围内和高度在1至4毫米范围内的颗粒形状。
• THIN-FILM FORMING RAW MATERIAL FOR USE IN ATOMIC LAYER DEPOSITION METHOD, THIN-FILM FORMING RAW MATERIAL, METHOD FOR PRODUCING THIN-FILM, AND COMPOUND
  申请人：ADEKA CORPORATION

  公开号：US20210340162A1

  公开（公告）日：2021-11-04

  The present invention provides a thin-film forming raw material, which is used in an atomic layer deposition method, including a compound represented by the following general formula (1): where R 1 to R 4 each independently represent an alkyl group having 1 to 5 carbon atoms, and A 1 represents an alkanediyl group having 1 to 5 carbon atoms.

  本发明提供了一种薄膜形成原料，用于原子层沉积方法，包括由以下一般式（1）表示的化合物：其中R1至R4分别独立表示具有1至5个碳原子的烷基基团，A1表示具有1至5个碳原子的烷二基基团。
• The effects of a hydroxyl group on some chemical and biological properties of n-pentyl ammonium salts
  作者：R B Barlow

  DOI：10.1111/j.2042-7158.1978.tb13369.x

  日期：2011.4.12

  The effects of a hydroxyl group on the activity and affinity of compounds related to n-pentyltrimethylammonoum have been studied on the guinea-pig ileum, frog rectus, acetylcholinesterase and on partitioning (Rm) and size (phiov, Vm). The hydroxyl group lowered affinity in all tests, confirming the importance of hydrophobic forces in binding to receptors. Activity on the ileum was lowered appreciably

  在豚鼠回肠，蛙直立肌，乙酰胆碱酯酶以及分配（Rm）和大小（phiov，Vm）上研究了羟基对与正戊基三甲基铵有关的化合物的活性和亲和力的影响。羟基在所有测试中均降低了亲和力，证实了疏水力在与受体结合中的重要性。回肠上的活性明显降低，但在直肠上仅轻微降低。对Rm的影响并未表明羟基，鎓基团和水之间有任何相互作用，但是羟基的表观大小（δphiphiov）取决于鎓基团的性质。
• METHOD FOR PRODUCING AN AMINE
  申请人：Kubanek Petr

  公开号：US20090286977A1

  公开（公告）日：2009-11-19

  Processes comprising: (i) providing a reactant selected from the group consisting of primary alcohols, secondary alcohols, aldehydes, ketones and mixtures thereof; and (ii) reacting the reactant with hydrogen and a nitrogen compound selected from the group consisting of ammonia, primary amines, secondary amines and mixtures thereof, in the presence of a catalyst comprising a zirconium dioxide- and nickel-containing catalytically active composition, to form an amine; wherein the catalytically active composition, prior to reduction with hydrogen, comprises oxygen compounds of zirconium, copper, nickel and cobalt, and one or more oxygen compounds of one or more metals selected from the group consisting of Pb, Bi, Sn, Sb and In.

  包括以下步骤：(i) 提供从一次醇、二次醇、醛、酮及其混合物中选择的反应物；和(ii) 在存在包含氧化锆和镍的催化剂的催化活性组分的条件下，将反应物与氢气和从氨、一次胺、二次胺及其混合物中选择的氮化合物反应，生成胺；其中催化活性组分在与氢气还原之前，包括锆、铜、镍和钴的氧化物，以及从铅、铋、锡、锑和铟中选择的一个或多个金属的一个或多个氧化物。