3,3'-(苯基亚胺)二丙烷-1,2-二醇 | 57302-22-4

• 分子结构分类: 有机化合物 - 有机氮化合物
• 中文名称: 3,3'-(苯基亚胺)二丙烷-1,2-二醇
• 英文名称: N,N-bis-(2,3-dihydroxy-propyl)-aniline
• 英文别名: N,N-Bis-(2,3-dihydroxy-propyl)-anilin；3,3'-(phenylimino)bispropane-1,2-diol；3-[N-(2,3-dihydroxypropyl)anilino]propane-1,2-diol
• CAS: 57302-22-4
• 化学式: C₁₂H₁₉NO₄
• 分子量: 241.287
• InChiKey: ZLWISTXMEPFPSK-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -0.6
• 重原子数：
  17
• 可旋转键数：
  7
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  84.2
• 氢给体数：
  4
• 氢受体数：
  5

反应信息

• 作为产物：
  描述：

  N-(环氧丙基)-N-苯基-环氧乙烷甲胺 在 水 作用下， 生成 3,3'-(苯基亚胺)二丙烷-1,2-二醇
  参考文献：
  名称：

  Chezlov, I. G.; Zavlin, P. M.; Kuznetsov, L. L., Russian Journal of Applied Chemistry, 1998, vol. 71, # 1, p. 155 - 161

  摘要：

  DOI：

文献信息

• Process for coloring polyester shaped articles
  申请人：MILLIKEN RESEARCH CORPORATION

  公开号：EP0247782A2

  公开（公告）日：1987-12-02

  A process is provided for the coloration of a preformed polyester resin shaped article having improved dye migration properties, which comprises: (a) coloring said article with a coloring agent in an amount sufficient to provide coloration to said shaped article; said coloring agent having the formula wherein R is an organic dyestuff radical; the polymeric constituent is selected from polyalkylene oxides and copolymers of polyalkylene oxides in which the alkylene moiety of the polymeric constituent contains 2 or more carbon atoms and such polymer constituent has a molecular weight of from about 132 to about 500; and n is an integer of fromm 1 to about 12; and X is selected from -OH, -NH2, -SH, -OCORi, -C02H, -CO2R1, -S03H, -S03Rl phosphate, phosphonite, urea, urethane, alkoxyl and alkoxide, wherein R1 is a lower alkyl group containing from 1 to about 6 carbon atoms; and (b) grafting said coloring agent to said article by heating said article to a temperature below a temperature at which said article will melt, but to a high enough temperature and for a period of time sufficient to achieve grafting of said coloring agent to said article.

  本发明提供了一种预成型聚酯树脂成型品的着色工艺，该工艺具有更好的染料迁移特性，包括 (a) 用一定量的着色剂对所述制品进行着色，其用量足以使所述成型制品着色；所述着色剂的式子为 其中 R 是有机染料自由基；聚合成分选自聚亚烷基氧化物和聚亚烷基氧化物共聚物，其中聚合成分的亚烷基含有 2 个或更多碳原子，且该聚合成分的分子量为约 132 至约 500；n是m 1至约12的整数；X选自-OH、-NH2、-SH、-OCORi、-C02H、-CO2R1、-S03H、-S03Rl磷酸盐、亚磷酸盐、脲、聚氨酯、烷氧基和烷氧化物，其中R1是含有1至约6个碳原子的低级烷基；和 (b) 将所述着色剂接枝到所述制品上，方法是将所述制品加热到低于所述制品将熔化的温度，但温度要足够高，时间要足够长，以实现所述着色剂接枝到所述制品上。
• Polymerizable composition
  申请人：KURARAY CO., LTD.

  公开号：EP0408357A2

  公开（公告）日：1991-01-16

  Provided are polymerizable compositions comprising: (a) a sulfinate represented by the general formula [I] wherein R¹ and R⁵ each represents a substituent having 2 to 6 carbon atoms, R², R³ and R⁴ each represents an atom or substituent inert to the monomer (b) referred to below, Mn+ represents a n-valent cation, and n represents an integer of 1 to 4; and (b) a monomer. (a) is an aromatic sulfinate substituted with bulky groups at its positions 2 and 6. Since the bulky substi­tuents dramatically suppress the addition of the sulfinate to the double bond of the monomers, e.g. (meth)acrylates, (meth)acrylamides and derivatives thereof, the compositions can be stored at room temperature for at least 1 year and thus are of great industrial value and, in particular very useful as dental adhesive compositions.

  提供的可聚合组合物包括 (a) 由通式[I]代表的亚硫酸盐 其中 R¹ 和 R⁵ 各自代表具有 2 至 6 个碳原子的取代基，R²、R³ 和 R⁴ 各自代表对下文所述单体(b)惰性的原子或取代基，Mn+ 代表正价阳离子，n 代表 1 至 4 的整数；以及 (b) 单体。 (a) 是一种在其 2 号和 6 号位置被大基团取代的芳香族亚硫酸盐。由于笨重的取代基极大地抑制了亚硫酸盐与单体（如（甲基）丙烯酸酯、（甲基）丙烯酰胺及其衍生物）双键的加成，因此这种组合物可以在室温下储存至少 1 年，具有极大的工业价值，尤其是作为牙科粘合剂组合物非常有用。
• Zawadzka et al., 1959, vol. <II>, # 6, p. 91,93
  作者：Zawadzka et al.

  DOI：——

  日期：——
• SOROKIN M. F.; SHODEH L. G.; KLOCHKOVA L. V., MOSK. XIM.-TEXNOL. IN-T IM. D. I. MENDELEEVA. M., 1980. 12 S., BIBLIOGR. +
  作者：SOROKIN M. F.、 SHODEH L. G.、 KLOCHKOVA L. V.

  DOI：——

  日期：——
• SOROKIN, M. F.;SHODEH, L. G.;KLOCHKOVA, L. V., IZV. VUZOV. XIMIYA I XIM. TEXNOL., 1982, 25, N 3, 355-360
  作者：SOROKIN, M. F.、SHODEH, L. G.、KLOCHKOVA, L. V.

  DOI：——

  日期：——