3,3'-亚甲基双(3,4-二氢-2H-1,3-苯并恶嗪) | 14723-40-1

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 苯并恶嗪类
• 中文名称: 3,3'-亚甲基双(3,4-二氢-2H-1,3-苯并恶嗪)
• 英文名称: 3,3'-methylenebis(3,4-dihydro-2H-1,3-benzoxazine)
• 英文别名: 3,4,3',4'-tetrahydro-2H,2'H-3,3'-methanediyl-bis-benzo[e][1,3]oxazine；bis-(4H-benz[e][1,3]oxazin-3-yl)-methane；Bis-(4H-benz[e][1,3]oxazin-3-yl)-methan；3,3'-Methylen-bis-(3,4-dihydro-2H-1,3-benzoxazin)；3-(2,4-Dihydro-1,3-benzoxazin-3-ylmethyl)-2,4-dihydro-1,3-benzoxazine
• CAS: 14723-40-1
• 化学式: C₁₇H₁₈N₂O₂
• 分子量: 282.342
• InChiKey: SBNOOUSOXGFWCK-UHFFFAOYSA-N

物化性质

• 熔点：
  154-155 °C
• 沸点：
  414.3±45.0 °C(Predicted)
• 密度：
  1.225±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3.1
• 重原子数：
  21
• 可旋转键数：
  2
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.29
• 拓扑面积：
  24.9
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  (E)-2-羟基苯甲醛肟 在 palladium on activated charcoal 、 硫酸 作用下， 生成 3,3'-亚甲基双(3,4-二氢-2H-1,3-苯并恶嗪)
  参考文献：
  名称：

  Condensation Products of Aldehydes and Ketones with o-Aminobenzyl Alcohol and o-Hydroxybenzylamine

  摘要：

  DOI：

  10.1021/ja01239a022

文献信息

• Chromium complexes of hydroxyl-functionalised 1,3,5-triazacyclohexanes
  作者：Murray V. Baker、David H. Brown、Brian W. Skelton、Allan H. White

  DOI：10.1039/a900122k

  日期：——

  The chromium co-ordination chemistry of three 1,3,5-triazacyclohexanes bearing hydroxyl-functionalised substituents on nitrogen has been explored. The complexes [CrL3(C3H6N3R3)] (L = CO, R = CH2CH2OH, CH2CH2CH2OH or o-hydroxybenzyl; L  = Br, R = CH2CH2CH2OH) have been prepared. Characterisation of the carbonyl complexes by spectroscopic and structural methods indicated that the triazacyclohexanes co-ordinate

  已经研究了在氮上带有羟基官能化取代基的三个1,3,5-三氮杂环己烷的铬配位化学。配合物[CrL 3（C 3 H 6 N 3 R 3）]（L = CO，R = CH 2 CH 2 OH，CH 2 CH 2 CH 2 OH或邻羟基苄基； L = Br，R = CH 2 CH 2通道2OH）已经准备好了。通过光谱和结构方法表征羰基配合物表明，三氮杂环己烷仅通过三个氮原子与铬中心配位。1,3,5-三（邻羟基苄基）-1,3,5-三氮杂环己烷和[Cr（CO）3（C 3 H 6 N 3 R 3）]的晶体结构测定（R = CH 2 CH 2 OH或CH 2 CH 2 CH 2 OH）。
• COMPOSITION FOR CURABLE RESIN, CURED PRODUCT OF SAID COMPOSITION, PRODUCTION METHOD FOR SAID COMPOSITION AND SAID CURED PRODUCT, AND SEMICONDUCTOR DEVICE
  申请人：JXTG Nippon Oil & Energy Corporation

  公开号：EP3702391A1

  公开（公告）日：2020-09-02

  [Problem] To provide a curable resin composition for obtaining a cured product that is excellent in high heat resistance and high-temperature stability, a cured product thereof, and methods of producing the curable resin composition and the cured product. Also provided is a semiconductor device using the cured product as a sealant. [Solution] A curable resin composition containing (A) a multifunctional benzoxazine compound having two or more benzoxazine rings, (B) an epoxy compound having at least one norbornane structure and at least two epoxy groups, (C) a naphthylene ether type epoxy compound, and (D) a curing agent, and optionally (E) an inorganic filler and (F) a curing accelerator; a cured product thereof; and methods of producing the curable resin composition and the cured product. A semiconductor device in which a semiconductor element is disposed in a cured product obtained by curing a curable resin composition containing components (A) to (D), and optionally components (E) and (F).

  [问题] 提供一种可获得耐高温性和高温稳定性优异的固化物的可固化树脂组合物、其固化物，以及生产该可固化树脂组合物和固化物的方法。此外，还提供了使用该固化物作为密封剂的半导体器件。 [解]一种可固化树脂组合物，含有(A)具有两个或两个以上苯并恶嗪环的多功能苯并恶嗪化合物，(B)具有至少一个降冰片烷结构和至少两个环氧基团的环氧化合物，(C)萘醚型环氧化合物，和(D)固化剂，以及可选的(E)无机填料和(F)固化促进剂；其固化产物；以及生产该可固化树脂组合物和固化产物的方法。一种半导体器件，其中半导体元件放置在通过固化可固化树脂组合物获得的固化产物中，该树脂组合物包含组分（A）至（D），以及可选组分（E）和（F）。
• COMPOSITION FOR CURED RESIN, CURED PRODUCT OF SAID COMPOSITION, PRODUCTION METHOD FOR SAID COMPOSITION AND SAID CURED PRODUCT, AND SEMICONDUCTOR DEVICE
  申请人：JXTG Nippon Oil & Energy Corporation

  公开号：EP3702388A1

  公开（公告）日：2020-09-02

  [Problem] To provide a curable resin composition for obtaining a cured product that can satisfy both high heat resistance and high mechanical strength, a cured product thereof, and methods of producing the curable resin composition and the cured product. Also provided is a semiconductor device using the cured product as a sealant. [Solution] A curable resin composition containing (A) a multifunctional benzoxazine compound having two or more benzoxazine rings, (B) an epoxy compound having at least one norbornane structure and at least two epoxy groups, (C) a biphenyl type epoxy compound, and (D) a curing agent, and optionally (E) an inorganic filler and (F) a curing accelerator; a cured product thereof; and methods of producing the curable resin composition and the cured product. A semiconductor device in which a semiconductor element is disposed in a cured product obtained by curing a curable resin composition containing components (A) to (D), and optionally components (E) and (F).

  [问题] 提供一种可获得同时满足高耐热性和高机械强度的固化物的可固化树脂组合物、其固化物，以及生产该可固化树脂组合物和固化物的方法。此外，还提供了使用该固化物作为密封剂的半导体器件。 [解]一种可固化树脂组合物，含有(A)具有两个或两个以上苯并恶嗪环的多功能苯并恶嗪化合物，(B)具有至少一个降冰片烷结构和至少两个环氧基团的环氧化合物，(C)联苯型环氧化合物，和(D)固化剂，以及可选的(E)无机填料和(F)固化促进剂；其固化产物；以及生产该可固化树脂组合物和固化产物的方法。一种半导体器件，其中半导体元件放置在通过固化可固化树脂组合物获得的固化产物中，该树脂组合物包含组分（A）至（D），以及可选组分（E）和（F）。
• Ring-chain tautomerism of derivatives of o-hydroxybenzylamine with aldehydes and ketones
  作者：Antony F. McDonagh、Howard E. Smith

  DOI：10.1021/jo01265a001

  日期：1968.1
• Stable Solution of the Polymer Prepared from N,O-Heterocycles and its Preparation Method and Use
  申请人：Liao Shih-Hao

  公开号：US20120059096A1

  公开（公告）日：2012-03-08

  A stable solution of the polymer prepared from N,O-heterocyclic compound and its preparing method are provided, wherein the stable solution is prepared by making the N,O-heterocyclic compound of formulae I or II carry out a ring-opening polymerization: wherein R1 to R3, W1, W2, m, n, p and q are as defined in the specification. The stable solution can be used as a hardener for curing epoxy resin.