1,1,4,6-tetramethyl-2,2-bis(trifluoromethyl)-1-azonia-2-borata-cyclohex-4-ene | 131260-16-7

• 分子结构分类: 有机化合物 - 有机卤素化合物 - 卤代烷
• 英文名称: 1,1,4,6-tetramethyl-2,2-bis(trifluoromethyl)-1-azonia-2-borata-cyclohex-4-ene
• 英文别名: 1,1,4,6-tetramethyl-2,2-bis(trifluoromethyl)-1-azonia-2-boranuidacyclohex-4-ene
• CAS: 131260-16-7
• 化学式: C₁₀H₁₆BF₆N
• 分子量: 275.045
• InChiKey: RCZBLLPQYBXZFO-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  2-甲基-1,3-戊二烯 、 dimethylaminobis(trifluoromethyl)borane 以 正戊烷 为溶剂， 以95%的产率得到1,1,4,6-tetramethyl-2,2-bis(trifluoromethyl)-1-azonia-2-borata-cyclohex-4-ene
  参考文献：
  名称：

  [2 + 4] Cycloaddition reactions of dialkylaminobis(trifluoromethyl)boranes with 1,3-dienes, β-unsaturated carbonyl compounds and methyl methacrylate. Crystal structures of (CF3)2H2, R = Me and Et, and (CF3)2

  摘要：

  and characterized by multinuclear NMR spectroscopy and by mass spectrometry, and IR and Raman spectroscopy. The crystal structures of the compounds (CF3)2H2, R = Me and Et, and (CF3)2 have been determined by X-ray diffraction studies. They show that the BN and BCF3 bonds are somewhat longer than those in acyclic amine adducts of bis(trifluoromethyl)boranes. Furthermore, evidence is presented for steric

  DOI：

  10.1016/0022-328x(90)85467-d

文献信息

• ANSORGE, A.;BRAUER, D. J.;BURGER, H.;DORRENBACH, F.;HAGEN, T.;PAWELKE, G.+, J. ORGANOMET. CHEM., 396,(1990) N-3, C. 253-267
  作者：ANSORGE, A.、BRAUER, D. J.、BURGER, H.、DORRENBACH, F.、HAGEN, T.、PAWELKE, G.+

  DOI：——

  日期：——
• [2 + 4] Cycloaddition reactions of dialkylaminobis(trifluoromethyl)boranes with 1,3-dienes, β-unsaturated carbonyl compounds and methyl methacrylate. Crystal structures of (CF3)2H2, R = Me and Et, and (CF3)2
  作者：A. Ansorge、D.J. Brauer、H. Bürger、F. Dörrenbach、T. Hagen、G. Pawelke、W. Weuter

  DOI：10.1016/0022-328x(90)85467-d

  日期：1990.10

  and characterized by multinuclear NMR spectroscopy and by mass spectrometry, and IR and Raman spectroscopy. The crystal structures of the compounds (CF3)2H2, R = Me and Et, and (CF3)2 have been determined by X-ray diffraction studies. They show that the BN and BCF3 bonds are somewhat longer than those in acyclic amine adducts of bis(trifluoromethyl)boranes. Furthermore, evidence is presented for steric