5,5-dichloro-pent-1-ene | 20395-27-1

• 分子结构分类: 有机化合物 - 有机卤素化合物 - 有机氯化物
• 英文名称: 5,5-dichloro-pent-1-ene
• 英文别名: 5,5-Dichlor-pent-1-en；5,5-Dichloropent-1-ene
• CAS: 20395-27-1
• 化学式: C₅H₈Cl₂
• 分子量: 139.025
• InChiKey: FQZIZGAZYNDURA-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3
• 重原子数：
  7
• 可旋转键数：
  3
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.6
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  2-氯乙烷磺酰氯 、 5,5-dichloro-pent-1-ene 生成 1,1,4,7-tetrachloro-heptane
  参考文献：
  名称：

  Rearrangement of polychloroalkyl radicals with 1,4-, 1,5- and 1,6-migration of hydrogen atom

  摘要：

  DOI：

  10.1007/bf00925054
• 作为产物：
  描述：

  5,5,5-trichloro-1-pentene 在 三乙基硅烷 、 五羰基铁 作用下， 生成 5,5-dichloro-pent-1-ene
  参考文献：
  名称：

  Reduction of organic chlorine compounds by systems consisting of a hydrogen donor and a compound of a transition element

  摘要：

  DOI：

  10.1007/bf01106274

文献信息

• High yield carbonylation of halo-hydrocarbons
  申请人：STAUFFER CHEMICAL COMPANY

  公开号：EP0222460A1

  公开（公告）日：1987-05-20

  High yields of aromatic, aromatic acetic and olefinic acids, esters, amides and the like are derived from a pro­cess wherein a halo-hydrocarbon is carbonylated in the pres­ence of a palladium catalyst, a hindered amine base and phosphine in excess. The hindered amine base can comprise C₃-C₁₀ branched alkyls, cyclic compounds, or mixtures of the above. The preferred amine is N,N-diisopropylethyl amine. The preferred catalyst is PdCl₂(PPH₃)₂ with the excess phos­phine generally supplied by a compound of the formula PR¹R²R³ where R¹,R² and R³ are preferably phenyl.

  高产率的芳香族、芳香族乙酸和烯烃酸、酯、酰胺等可通过以下工艺制得：卤代烃在钯催化剂、受阻胺碱和过量膦的存在下发生羰基化反应。受阻胺基可包括 C₃-C₁₀ 支链烷基、环状化合物或上述物质的混合物。首选胺为 N,N-二异丙基乙基胺。优选催化剂为 PdCl₂(PPH₃)₂，过量的膦通常由式 PR¹R²R³ 的化合物提供，其中 R¹、R² 和 R³ 优选为苯基。
• Single phase carbonylation of aromatic halides to carboxylic acid salts
  申请人：STAUFFER CHEMICAL COMPANY

  公开号：EP0273553A1

  公开（公告）日：1988-07-06

  A process for preparing carboxylic acid salts by the reaction of carbon monoxide with substituted or unsubstituted aromatic halides or an aliphatic organic halide comprises the catalyst single phase carbonylation of the halide utilizing in addition to carbon monoxide, a palladium catalyst, an excess of tertiary phosphine, optionally an amine compound, with an alkali metal or alkaline earth metal base added during the reaction to form the salt.

  一种通过一氧化碳与取代或未取代的芳香族卤化物或脂肪族有机卤化物反应制备羧酸盐的工艺，包括卤化物的催化剂单相羰基化，除一氧化碳外，还利用钯催化剂、过量的叔膦，可选择胺化合物，在反应过程中加入碱金属或碱土金属碱，以形成盐。
• RESIN COMPOSITION FOR INK-JET RECORDING SHEET AND RECORDING SHEET MADE WITH THE SAME
  申请人：DAICEL CHEMICAL INDUSTRIES, Ltd.

  公开号：EP1114734A1

  公开（公告）日：2001-07-11

  The present invention Nos. I-VII are a resin composition for an ink-jet recording sheet for constructing an image-receiving layer which is formed on at least one surface of a base material for an ink-jet recording sheet. The present invention No. I relates to a resin composition for an ink-jet recording sheet which comprises (1) 2-80% by mass of a cationic acrylic copolymer (A) having a crosslinkable group, (2) 5-80% by mass of a saponified product (B) of a vinyl acetate-based copolymer having a polymerization degree of 200-1000, and (3) 0-80% by mass of a modifier (R), the present invention No. II relates to a resin composition for an ink-jet recording sheet which contains (1) 2-80 wt% of a cationic acrylic copolymer (A) having a crosslinkable group, (2) 5-80 wt% of a saponified product (B) of a vinyl acetate-based copolymer, (3) (n1-80) wt% of a water-based polyurethane resin (C), (4) (n2-60) wt% of a polyurethane-based graft polymer mixture (D), and (5) (n3-60) wt% of a polyester-based graft polymer mixture (E) in a solid content-based ratio, and total is 100 wt%, in which there are satisfied conditions that a minimum value in n1, n2, and n3 is 0, and (n1+n2+n3) is ≥5, the present invention No. III relates to a resin composition for an ink-jet recording sheet which comprises, [1] 2-80% by weight of a cationic acrylic copolymer (A) having a crosslinkable group, [2] 5-60% by weight of a saponified product (B) of a vinyl acetate-based copolymer, and [3] 0-80% by weight of a water-based polyurethane resin (C) total of the (A), (B), and (C) is 100% by weight}, and [4] 0.05-10 parts by weight of a block isocyanate compound (F) based on 100 parts by weight of the saponified product (B) of a vinyl acetate-based copolymer, the present invention No. IV relates to a resin composition for an ink-jet recording sheet which comprises the use of 2-100% by weight of a cationic acrylic copolymer (A) composed of a monomer having an alkylene oxide group, a monomer having a hydrophilic group, a monomer having a crosslinkable group, a monomer containing cationic group, 0-90% by weight of a saponified product (B) of a vinyl acetate-based copolymer, and 5-60% by weight of a modifier (R), and an image-receiving layer is formed over at least one surface, the present invention No. V relates to a resin composition for an ink-jet recording sheet which comprises formulating 70-100% by weight of a cationic (meth)acrylic polymer (A) in which there are copolymerized a cationic (meth)acrylate monomer having a polyalkylene oxide group, a monomer having a hydrophilic group, a monomer having a crosslinkable group, a monomer containing cationic group, and a cationic monomer, 0-30% by weight of a saponified product (B) of a vinyl acetate-based copolymer (total thereof is 100% by weight), and 0-15 parts by weight of a modifier (R) based on 100 parts by weight of the (A) and the (B), the present invention No. VI relates to an ink-jet recording sheet which comprises being constructed by a composition containing a (meth)acrylic-based copolymer having a hydrolyzable silyl group in which a polymerizable unsaturated monomer having a hydrolyzable silyl group is copolymerized with monomers containing a (meth)acrylate-based polymerizable unsaturated monomer, and inorganic compound fine particles, the present invention No. VII relates to a resin composition for an ink-jet recording sheet characterized by containing 100 parts by weight of a resin composition composed of (1) 1-30% by weight of a cellulose derivative (A) and (2) 70-99% by weight of a good solvent (B) for the cellulose derivative (total is 100% by weight), (3) 0.1-20 parts by weight of an organic acid (C) which can dissolve in the good solvent (B) or a weak solvent (D) for the cellulose derivative, and optionally, (4) 0-150 parts by weight of a weak solvent (D) for the cellulose derivative, and relates to a recording sheet in which an image-receiving layer is formed on a body to be recorded composed of the resin composition. the present invention No. VIII is to provide a heat transfer sheet which is excellent in an ink-absorbing ability, an ink-fixing ability, and a printing ability in the case of molding into the heat transfer sheet, and which is high in a water resistance, durability, particularly, micro cracks resistance of a recorded picture, and in which an ink-receiving layer is formed on an elastic material, and micro cracks are not caused even though the recorded picture is expanded and shrunk, and a resin composition for constructing thereof, a resin composition containing a polymer (A) containing a monomer unit shown by a specified formula (1) and a hot-melt adhesive resin (B), a heat transfer sheet comprised the resin composition, and a method for the preparation thereof.

  本发明第I-VII号是一种喷墨记录薄片用树脂组合物，用于在喷墨记录薄片基材的至少一个表面上形成图像接收层。 本发明 I 涉及一种用于喷墨记录薄片的树脂组合物，该树脂组合物包括：(1) 2-80% （质量百分比）具有可交联基团的阳离子丙烯酸共聚物 (A)；(2) 5-80% （质量百分比）聚合度为 200-1000 的醋酸乙烯酯基共聚物的皂化产物 (B)；(3) 0-80% （质量百分比）改性剂 (R)、 本发明第II 涉及一种用于喷墨记录片材的树脂组合物，它含有 (1) 2-80 wt%的具有可交联基团的阳离子丙烯酸共聚物 (A)，(2) 5-80 wt%的醋酸乙烯酯基共聚物的皂化产物 (B)，(3) (n1-80) wt%的水基聚氨酯树脂 (C)、(4)(n2-60)重量％的聚氨酯基接枝聚合物混合物(D)，和(5)(n3-60)重量％的聚酯基接枝聚合物混合物(E)，以固含量为基础的比例，总计为100重量％，其中满足的条件是n1、n2和n3中的最小值为0，且(n1+n2+n3)≥5、 本发明 III 号涉及一种用于喷墨记录片材的树脂组合物，它包括：[1] 2-80% （重量比）具有可交联基团的阳离子丙烯酸共聚物 (A)、 [2] 5-60% （重量百分比）醋酸乙烯共聚物的皂化产品 (B)，以及 [3] 0-80%（重量）的水性聚氨酯树脂（C）(A)、(B)和(C)的总和为 100%（重量）}，以及 [4] 以 100 份醋酸乙烯酯基共聚物的皂化产物（B）为基数，加入 0.05-10 份 （重量）的嵌段异氰酸酯化合物（F）、 本发明 No.IV涉及一种用于喷墨记录片材的树脂组合物，它包括使用 2-100%（重量）的阳离子丙烯酸共聚物（A），该共聚物由具有环氧烷基的单体、具有亲水基团的单体、具有可交联基团的单体、含有阳离子基团的单体、0-90%（重量）的醋酸乙烯酯基共聚物的皂化产物（B）和 5-60%（重量）的改性剂（R）组成，并在至少一个表面上形成图像接收层、 本发明第V 涉及一种用于喷墨记录片材的树脂组合物，它包括配制 70-100% （重量）的阳离子（甲基）丙烯酸聚合物 (A)，其中共聚有一个具有聚氧化亚烷基的阳离子（甲基）丙烯酸酯单体、一个具有亲水基团的单体、具有可交联基团的单体、含有阳离子基团的单体和阳离子单体，0-30%（重量）的醋酸乙烯酯基共聚物的皂化产物（B）（其总重量为 100%（重量）），以及 0-15 份（重量）的改性剂（R）（以 100 份（重量）的（A）和（B）为基准）、 本发明之六涉及一种喷墨记录片材，其包括由含有可水解硅烷基的(甲基)丙烯酸基共聚物的组合物构成，在该组合物中，具有可水解硅烷基的可聚合不饱和单体与含有(甲基)丙烯酸基可聚合不饱和单体的单体共聚，以及无机化合物细颗粒、 本发明第 VII 号涉及一种用于喷墨记录片材的树脂组合物，其特征在于含有 100 份(重量)的树脂组合物，其组成为(1)1-30%(重量)的纤维素衍生物(A)和(2)70-99%(重量)的纤维素衍生物的良好溶剂(B)(总计为 100%(重量))，(3)0.1-20份(重量)能溶解在纤维素衍生物的良好溶剂(B)或弱溶剂(D)中的有机酸(C)，以及任选地，(4)0-150份(重量)纤维素衍生物的弱溶剂(D)，并涉及一种在由树脂组合物构成的待记录体上形成图像接收层的记录片材。 本发明的第VIII 是要提供一种热转印片材，它在模压成热转印片材的情况下具有优异的吸墨能力、固墨能力和印刷能力，并具有较高的耐水性、耐久性，特别是记录图像的抗微裂纹能力，而且其中的受墨层是在弹性材料上形成的、以及用于构建这种材料的树脂组合物、含有指定式（1）所示单体单元的聚合物（A）和热熔粘合剂树脂（B）的树脂组合物、由该树脂组合物构成的热转印片材及其制备方法。
• POLYISOCYANATE COMPOSITION AND ISOCYANATE POLYMER COMPOSITION
  申请人：Asahi Kasei Chemicals Corporation

  公开号：EP2915803A1

  公开（公告）日：2015-09-09

  The present invention relates to a polyisocyanate composition comprising, on the basis of the total mass of the polyisocyanate composition, 97 weight % or more of a polyisocyanate, and 2.0 mass ppm or more and 1.0×104 mass ppm or less of a compound having at least one unsaturated bond in which the compound is a different compound from the polyisocyanate, or 5.0 mass ppm or more and 2.0×104 mass ppm or less of at least one inactive compound selected from the group consisting of a hydrocarbon compound, an ether compound, a sulfide compound, a halogenated hydrocarbon compound, a Si-containing hydrocarbon compound, a Si-containing ether compound, and a Si-containing sulfide compound.

  本发明涉及一种多异氰酸酯组合物，以该多异氰酸酯组合物的总质量为基准，该组合物包含 97 重量％或以上的多异氰酸酯，以及 2.0 质量 ppm 或以上且 1.0×104 质量 ppm 或以下的至少具有一个不饱和键的化合物，其中该化合物是与多异氰酸酯不同的化合物，或 5.0 质量 ppm 或以上且 2.0×104 质量 ppm 或以下的至少一种非活性化合物，该化合物选 自烃化合物、醚化合物、硫化物化合物、卤代烃化合物、含硅烃化合物、含硅醚化合物和含硅硫 化物组成的组。
• ISOCYANATE COMPOSITION, PRODUCTION METHOD FOR ISOCYANATE COMPOSITION, AND PRODUCTION METHOD FOR ISOCYANATE POLYMER
  申请人：ASAHI KASEI KABUSHIKI KAISHA

  公开号：EP3527593A1

  公开（公告）日：2019-08-21

  An isocyanate composition according to the present invention contains an isocyanate compound of formula (1) and/or (2) (wherein R1 represents a hydrogen or a monovalent organic group, and R2 represents a monovalent organic group), and, relative to the total mass of the isocyanate compound in the composition, 1.0 ppm by mass to 10% by mass of a compound of formula (3): R13-(COO-R14)a (wherein R13 represents an organic group with a valence of a, R14 represents a monovalent organic group, and a represents an integer of 1 or 2), which is different from the isocyanate compound, and/or, 1.0 ppm by mass to 10% by mass of a compound having an UV absorption in an area of decamer or higher isocyanates in a measurement spectrum of gel permeation chromatography.

  根据本发明的异氰酸酯组合物含有式(1)和/或(2)的异氰酸酯化合物(其中 R1 代表氢或一价有机基团，R2 代表一价有机基团)，以及相对于组合物中异氰酸酯化合物的总质量，1.0ppm(质量)至 10%(质量)的式(3)化合物：R13-(COO-R14)a（其中 R13 代表价数为 a 的有机基团，R14 代表一价有机基团，a 代表 1 或 2 的整数），该化合物与异氰酸酯化合物不同，和/或，在凝胶渗透色谱法的测量光谱中，在十聚体或更高异氰酸酯区域具有紫外吸收的化合物的质量百分比为 1.0 ppm 至 10%。