2-acryloyloxy-6-(2-propyl-4-hydroxyphenyl)oxycarbonylnaphthalene | 886230-43-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: 2-acryloyloxy-6-(2-propyl-4-hydroxyphenyl)oxycarbonylnaphthalene
• 英文别名: (4-Hydroxy-2-propylphenyl) 6-prop-2-enoyloxynaphthalene-2-carboxylate
• CAS: 886230-43-9
• 化学式: C₂₃H₂₀O₅
• 分子量: 376.409
• InChiKey: MTJOHIGVYMUYPA-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.9
• 重原子数：
  28
• 可旋转键数：
  8
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.13
• 拓扑面积：
  72.8
• 氢给体数：
  1
• 氢受体数：
  5

反应信息

• 作为反应物：
  描述：

  2-acryloyloxy-6-(2-propyl-4-hydroxyphenyl)oxycarbonylnaphthalene 、 3,4-bis(6-(acryloyloxy)hexyloxy)benzoic acid 在 甲基磺酰氯 、 N,N-二异丙基乙胺 、 4-二甲氨基吡啶 作用下， 以 四氢呋喃 为溶剂， 反应 2.5h， 以25.4%的产率得到[4-[3,4-Bis(6-prop-2-enoyloxyhexoxy)benzoyl]oxy-2-propylphenyl] 6-prop-2-enoyloxynaphthalene-2-carboxylate
  参考文献：
  名称：

  TRIFUNCTIONAL (METH)ACRYLATE COMPOUND AND POLYMERIZABLE COMPOSITION CONTAINING THE COMPOUND

  摘要：

  公开号：

  EP2261201B1
• 作为产物：
  描述：

  (4-Phenylmethoxy-2-propylphenyl) 6-prop-2-enoyloxynaphthalene-2-carboxylate 在 aluminum (III) chloride 、 盐酸 、 水 作用下， 以 苯甲醚 为溶剂， 反应 1.0h， 以65.6%的产率得到2-acryloyloxy-6-(2-propyl-4-hydroxyphenyl)oxycarbonylnaphthalene
  参考文献：
  名称：

  EP1944287

  摘要：

  公开号：

文献信息

• POLYMERIZABLE COMPOUNDS AND POLYMERIZABLE COMPOSITIONS
  申请人：Itano Kazuyuki

  公开号：US20100032621A1

  公开（公告）日：2010-02-11

  A polymerizable compound represented by general formula (1) of the invention has good solvent solubility and excellent alignment control properties and optical characteristics. In formula (1), M 1 and M 2 are each hydrogen or methyl; X 1 and are each a single bond, or an optionally branched C1-10 alkylene, alkyleneoxy or alkyleneoxycarbonyloxy; X 3 is optionally branched C1-10 alkylene; Y 1 and Y 2 are each an ester linkage, etc.; and rings A, B, C, and D are each a cyclic structure, such as 2,6-naphthlene.

  本发明中的通式（1）所表示的可聚合化合物具有良好的溶剂溶解性和优异的取向控制性能和光学特性。在公式（1）中，M1和M2分别为氢或甲基；X1和X2分别为单键，或可选的支链C1-10烷基，烷氧基或烷氧基羰氧基；X3为可选的支链C1-10烷基；Y1和Y2分别为酯键等；环A、B、C和D分别为环状结构，例如2,6-萘。
• NOVEL POLYMERIZABLE COMPOUNDS
  申请人：Irisawa Masatomi

  公开号：US20090247782A1

  公开（公告）日：2009-10-01

  A novel polymerizable compound of the present invention is represented by the following general formula (I). Due to the presence of a reactive phenolic hydroxyl group at the end of the molecule, it can be reacted easily with various functional compounds and is useful as a monomer and an intermediate for various functional materials, especially as an intermediate for a polymerizable liquid crystal material. wherein R 1 is a hydrogen atom, a methyl group or a halogen atom; R 2 is an optionally substituted alkyl group having 1 to 6 carbon atoms, an optionally substituted alkoxy group having 1 to 6 carbon atoms, a halogen atom or a cyano group; an alkylene group of each of the alkyl and the alkoxy group may be interrupted by an unsaturated bond, an ether bond, a thioether bond or an ester bond; n is an integer from 0 to 14; and m is 0 or 1.

  本发明的一种新型可聚合化合物由以下通式（I）表示。由于分子末端存在反应性酚羟基，因此可以与各种功能化合物容易地反应，作为各种功能材料的单体和中间体特别是作为可聚合液晶材料的中间体。 其中，R1是氢原子，甲基或卤素原子；R2是具有1至6个碳原子的可选取代烷基，具有1至6个碳原子的可选取代烷氧基，卤素原子或氰基；烷基和烷氧基的每个亚烷基可以通过不饱和键，醚键，硫醚键或酯键中断；n是从0到14的整数；m为0或1。
• Polymerizable Compound And Composition Containing The Polymerizable Compound
  申请人：Irisawa Masatomi

  公开号：US20070282087A1

  公开（公告）日：2007-12-06

  The polymerizable compound of the present invention is represented by general formula (1) below and can provide a composition that is polymerizable near ambient temperature and exists in a liquid crystal phase at low temperatures. The composition and a (co)polymer of the polymerizable compound of the present invention are liquid crystal substances useful as optically anisotropic materials. (In the formula, each of rings A 1 to A 3 represents a benzene ring, cyclohexane ring, etc.; each of X to Z represents a C 1-8 alkyl or alkoxy group, C 2-6 alkenyl group, halogen atom, cyano group, or CH 2 ═CR 3 —COO—; each of R 1 to R 3 represents a hydrogen atom, methyl group, or halogen atom; each of L 1 to L 3 represents —CH 2 CH 2 COO—, —COO—, —OCO—, —CH 2 CH 2 —, —O(CH 2 ) f — (herein, f=1-8), etc.; n represents 0 or 1; and a to c represent such numbers that the polymerizable compound has at least one or more of any of X, Y, and Z.)

  本发明的可聚合化合物由下式（1）表示，可提供一种在接近常温下可聚合且在低温下存在液晶相的组合物。本发明的可聚合化合物的（共）聚合物和组成该聚合物的液晶物质是有用的光学各向异性材料。（在式中，环A1到A3分别表示苯环、环己烷环等；X到Z分别表示C1-8烷基或烷氧基、C2-6烯基、卤素原子、氰基或CH2═CR3—COO—；R1到R3分别表示氢原子、甲基或卤素原子；L1到L3分别表示— COO—、—COO—、—OCO—、— —、—O( )f—（此处，f=1-8）等；n表示0或1；a到c表示聚合物至少具有X、Y和Z中的任意一种或多种。）
• POLYMERIZABLE COMPOUND AND COMPOSITION CONTAINING THE POLYMERIZABLE COMPOUND
  申请人：Adeka Corporation

  公开号：EP1813594B1

  公开（公告）日：2011-05-11
• EP1972612
  申请人：——

  公开号：——

  公开（公告）日：——