[4-[6-[3,4-Bis(6-prop-2-enoyloxyhexoxy)benzoyl]oxynaphthalene-2-carbonyl]oxy-3-propylphenyl] 6-(6-prop-2-enoyloxyhexoxy)naphthalene-2-carboxylate | 1190285-34-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: [4-[6-[3,4-Bis(6-prop-2-enoyloxyhexoxy)benzoyl]oxynaphthalene-2-carbonyl]oxy-3-propylphenyl] 6-(6-prop-2-enoyloxyhexoxy)naphthalene-2-carboxylate
• CAS: 1190285-34-7
• 化学式: C₆₅H₇₀O₁₅
• 分子量: 1091.26
• InChiKey: QGVZAIBDSUKWKD-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  15.6
• 重原子数：
  80
• 可旋转键数：
  41
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.32
• 拓扑面积：
  186
• 氢给体数：
  0
• 氢受体数：
  15

反应信息

• 作为产物：
  描述：

  3,4-bis(6-(acryloyloxy)hexyloxy)benzoic acid 、 [4-[6-(6-Prop-2-enoyloxyhexoxy)naphthalene-2-carbonyl]oxy-2-propylphenyl] 6-hydroxynaphthalene-2-carboxylate 在 4-二甲氨基吡啶 、 N,N'-二异丙基碳二亚胺 作用下， 以 四氢呋喃 为溶剂， 反应 3.16h， 以81.6%的产率得到[4-[6-[3,4-Bis(6-prop-2-enoyloxyhexoxy)benzoyl]oxynaphthalene-2-carbonyl]oxy-3-propylphenyl] 6-(6-prop-2-enoyloxyhexoxy)naphthalene-2-carboxylate
  参考文献：
  名称：

  TRIFUNCTIONAL (METH)ACRYLATE COMPOUND AND POLYMERIZABLE COMPOSITION CONTAINING THE COMPOUND

  摘要：

  公开号：

  EP2261201B1

文献信息

• POLYMERIZABLE COMPOUND AND OPTICAL ISOMER
  申请人：DIC Corporation

  公开号：US20180022716A1

  公开（公告）日：2018-01-25

  The present invention provides a polymerizable compound having high storage stability without causing crystal precipitation when added to a polymerizable composition. The present invention also provides a polymerizable composition containing the compound. When the filmy polymer produced through polymerization of the polymerizable composition is irradiated with UV light, it hardly discolors or peels from substrate. Further, the present invention provides a polymer produced through polymerization of the polymerizable composition and an optically anisotropic body using the polymer.

  本发明提供了一种聚合物化合物，具有高储存稳定性，添加到聚合物化合物时不会导致结晶沉淀。本发明还提供了含有该化合物的聚合物化合物。当通过聚合物化合物的聚合产生薄膜状聚合物时，若用紫外光照射，它几乎不会变色或脱落。此外，本发明提供了通过聚合物化合物的聚合产生的聚合物，以及使用该聚合物的光学各向异性体。
• POLYMERIZABLE LIQUID CRYSTAL COMPOSITION, POLARIZED LIGHT-EMITTING COATING MATERIAL, NOVEL NAPHTHOLACTAM DERIVATIVE NOVEL COUMARIN DERIVATIVE, NOVEL NILE RED DERIVATIVE, AND NOVEL ANTHRACENE DERIVATIVE
  申请人：Kubota Yusuke

  公开号：US20130334461A1

  公开（公告）日：2013-12-19

  Provided are a polymerizable liquid crystal composition, a coating material, a medium, and a polarizing device each produced using a polymerizable liquid crystal compound and a colorant and each capable of producing polarized light suitable for polarizing devices, and also a novel naphtholactam derivative, a novel coumarin derivative, a novel Nile Red derivative, and a novel anthracene derivative each suitable for use as the colorant. Specifically provided are a polymerizable liquid crystal composition containing (A) at least one liquid crystal compound having a polymerizable functional group, (B) at least one colorant, and (C) a polymerization initiator, and a novel naphtholactam derivative of formula (IV′), a novel coumarin derivative of formula (VI′), a novel Nile Red derivative of formula (VII′), and a novel anthracene derivative of formula (VIII′) each suitable for use as the colorant (B).

  提供了一种可聚合的液晶组合物、涂料材料、介质和极化装置，每种都使用了聚合液晶化合物和颜料，并且能够产生适合于极化装置的偏振光，还提供了一种新型萘内酰胺衍生物、一种新型香豆素衍生物、一种新型尼罗红衍生物和一种新型蒽衍生物，每种都适用于用作颜料。具体提供了一种聚合液晶组合物，包含（A）至少一种具有聚合功能基团的液晶化合物，（B）至少一种颜料，和（C）聚合引发剂，以及一种适用于用作颜料（B）的新型萘内酰胺衍生物（IV′）, 一种新型香豆素衍生物（VI′）, 一种新型尼罗红衍生物（VII′）和一种新型蒽衍生物（VIII′）。
• POLYMERIZABLE OPTICALLY ACTIVE IMIDE COMPOUND AND POLYMERIZABLE COMPOSITION CONTAINING THE COMPOUND
  申请人：Adeka Corporation

  公开号：EP2325168A1

  公开（公告）日：2011-05-25

  A polymerizable optically-active imide compound represented by the following general formula (I). Preferable among the polymerizable optically-active imide compound are compounds wherein X3 and X4 in general formula (I) are both -CO-, compounds wherein the rings A2 and A3 in general formula (I) are both naphthalene rings, compounds wherein the rings A1, A2, A3, and A4 are all benzene rings, compounds wherein M1 and M2 in general formula (I) are both hydrogen atoms, or compounds wherein rings A1 and A4, as well as rings A2 and A3, in general formula (I) are the same ring, the groups M1 and M2, X1 and X6, X2 and X5, as well as X3 and X6 are the same group in each pair, and n and m are the same number. wherein, rings A1, A2, A3, and A4 each independently represent a benzene ring or a naphthalene ring; M1 and M2 each independently represent a hydrogen atom or a methyl group; R1 represents a C1-10 alkyl group or the like; X1 represents a direct bond, -L1-, -L1O-, -L1O-CO-, -L1CO-O-, or -L1O-CO-O-; X2 and X5 each independently represent a linking group consisting of a direct bond, an ester bond, an ether bond, a C1-8 alkylene group that may be branched and that may have an unsaturated bond, or a combination thereof; X3 represents a direct bond, -CO-, -L2-, -OL2-, -O-COL2-, -CO-OL2-, or -O-CO-OL2-; X4 represents a direct bond, -CO-, -L1-, -L1O-, -L1O-CO-, -L1CO-O-, or -L1O-CO-O-; X6 represents a direct bond, -L2-, -OL2-, -O-COL2-, -CO-OL2-, or -O-CO-OL2-; L1 and L2 each independently represent a C1-8 alkylene group that may be branched; and n and m each independently represent 0 or 1.

  由以下通式(I)表示的可聚合的光学活性亚胺化合物。在可聚合的光学活性亚胺化合物中，通式（I）中的 X3 和 X4 均为-CO-的化合物、通式（I）中的环 A2 和 A3 均为萘环的化合物、环 A1、A2、A3 和 A4 均为苯环的化合物、通式（I）中的 M1 和 M2 均为氢原子的化合物、通式（I）中的环 A2 和 A3 均为萘环的化合物、通式（I）中的环 A1、A2、A3 和 A4 均为苯环的化合物是较好的、通式（I）中的 M1 和 M2 均为氢原子的化合物，或通式（I）中的环 A1 和 A4 以及环 A2 和 A3 为同一环，每对基团 M1 和 M2、X1 和 X6、X2 和 X5 以及 X3 和 X6 为同一基团，且 n 和 m 为相同数目的化合物。 其中，环 A1、A2、A3 和 A4 各自独立地代表苯环或萘环；M1 和 M2 各自独立地代表氢原子或甲基；R1 代表 C1-10 烷基或类似基团；X1 代表直接键、-L1-、-L1O-、-L1O-CO-、-L1CO-O-或 -L1O-CO-O-；X2 和 X5 各自独立地代表一个连接基团，该基团由直接键、酯键、醚键、C1-8 烷基（可支化且可具有不饱和键）或它们的组合组成；X3 代表直接键、-CO-、-L2-、-OL2-、-O-COL2-、-CO-OL2-或-O-CO-OL2-； X4 代表直接键、-CO-、-L1-、-L1O-、-L1O-CO-、-L1CO-O-或-L1O-CO-O-；X6 代表直接键、-L2-、-OL2-、-O-COL2-、-CO-OL2- 或 -O-CO-OL2-； L1 和 L2 各自独立地代表可支化的 C1-8 烯基；以及 n 和 m 各自独立地代表 0 或 1。
• TRIFUNCTIONAL (METH)ACRYLATE COMPOUND AND POLYMERIZABLE COMPOSITION CONTAINING SAME
  申请人：Shinano Hirokatsu

  公开号：US20110037025A1

  公开（公告）日：2011-02-17

  A trifunctional (meth)acrylate compound represented by the following general formula (I); and a polymerizable composition containing the compound. The compound preferably is a compound in which ring A1, ring A 2 , and ring A 3 in general formula (I) each is a benzene ring or naphthalene ring and at least one of the ring A 1 , ring A 2 , and ring A 3 is a naphthalene ring, or is a compound in which X 1 , X 2 , and X 3 each is —COO— or —OCO—. More preferred is a compound in which ring A 3 is a naphthalene ring. Even more preferred is the compound which by itself can retain a liquid-crystal phase at 30° C. and lower temperatures. (In the formula, M 1 , M 2 , and M 3 each represents methyl, etc.; rings A 1 , A 2 , and A 3 each represents a benzene ring, naphthalene ring, etc.; Z 1 , Z 2 , and Z 3 each represents C 1-6 alkyl, etc.; X 1 , X 2 , and X 3 each represents —COO—, —OCO—, etc.; Y 1 and Y 2 each represents -L 1 -, and Y 3 represents -L 2 -, etc. (L 1 and L 2 each represents C 1-8 alkylene); a, b, and c indicate the number of substituents of the ring A 1 , ring A 2 , and ring A 3 , respectively, and when the number of six-membered rings contained in each substituted monocycle or fused ring is expressed by u, then the a, b, and c each independently is an integer of 2u+2 or smaller, provided that at least one of the a, b, and c is an integer of 1 or larger; p's each independently is an integer of 1-8; q and r each independently is an integer of 1-3; and s and t each independently is 0 or 1, provided that s+t≧1.)
• US8057701B2
  申请人：——

  公开号：US8057701B2

  公开（公告）日：2011-11-15