naphthalene-1,2,6-tricarboxylic acid | 36440-00-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: naphthalene-1,2,6-tricarboxylic acid
• 英文别名: Naphthalin-1,2,6-tricarbonsaeure；1,2,6-Tricarboxy-naphthalin
• CAS: 36440-00-3
• 化学式: C₁₃H₈O₆
• 分子量: 260.203
• InChiKey: QVFIXVODASDDMO-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.8
• 重原子数：
  19
• 可旋转键数：
  3
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  112
• 氢给体数：
  3
• 氢受体数：
  6

反应信息

• 作为产物：
  描述：

  2,6-dimethyl-[1]naphthoic acid 在 sodium dichromate 作用下， 生成 naphthalene-1,2,6-tricarboxylic acid
  参考文献：
  名称：

  萘三甲酸的所有异构体的合成

  摘要：

  萘三甲酸的所有 14 种异构体都是通过三甲基萘、二甲基丙酮酮、二甲基萘甲酸、甲基萘二甲酸、β-（二甲基萘甲酰基）丙酸或β-（苊酰基）丙酸与重铬酸钠或铁氰化钾水溶液氧化合成的。这些萘三甲酸、酸酐和三甲酯大部分是新化合物。

  DOI：

  10.1246/bcsj.45.519

文献信息

• Additives and products including oligoesters
  申请人：——

  公开号：US20030199593A1

  公开（公告）日：2003-10-23

  The present invention relates to oligoesters and their use or the creation of additives. Oligoester containing additives and/or oligoesters themselves may be used for formulating pharmaceutical preparations, cosmetics or personal care products such as shampoos and conditioners. These oligoesters are particularly useful for the creation of multi-purpose additives that can impart conditioning, long substantivity and/or UV protection. Individual oligoesters and oligoester mixtures are described.

  本发明涉及寡酯及其用途或添加剂的制备。含有寡酯的添加剂和/或寡酯本身可用于配制药物制剂、化妆品或个人护理产品，如洗发水和护发素。这些寡酯对于制备能够赋予调理、长效性和/或紫外线保护的多功能添加剂特别有用。描述了单独的寡酯和寡酯混合物。
• POLYBENZIMIDAZOLES AND METHODS OF MAKING AND USING THEREOF
  申请人：BOARD OF REGENTS, THE UNIVERSITY OF TEXAS SYSTEM

  公开号：US20170081477A1

  公开（公告）日：2017-03-23

  Disclosed are polybenzimidazoles containing sulfonyl groups. The polymers can be synthesized in Eaton's reagent from 3,3′,4,4′-tetraaminodiphenylsulfone, which itself can be synthesized from 4,4′-dichlorodiphenylsulfone. Methods of synthesizing the polymers are disclosed. The disclosed polymers can be used for high temperature H 2 /CO 2 separation membranes and other uses.

  揭示了含有磺酰基团的聚苯并咪唑。这些聚合物可以从3,3′,4,4′-四氨基二苯砜在伊顿试剂中合成，而这种化合物本身可以从4,4′-二氯二苯砜合成。公开了合成这些聚合物的方法。这些聚合物可用于高温H2/CO2分离膜和其他用途。
• Additives and products includings oligoesters
  申请人：Pereira Abel G.

  公开号：US20100035999A1

  公开（公告）日：2010-02-11

  The present invention relates to oligoesters and their use for the creation of additives. Oligoester containing additives and/or oligoesters themselves may be used for formulating pharmaceutical preparations, cosmetics or personal care products such as shampoos and conditioners. These oligoesters are particularly useful for the creation of multi-purpose additives that can impart conditioning, long substantivity and/or UV protection. Individual oligoesters and oligoester mixtures are described.

  本发明涉及寡聚酯及其用于创建添加剂的使用。含有寡聚酯的添加剂和/或寡聚酯本身可用于制定制药制剂、化妆品或个人护理产品，如洗发水和护发素。这些寡聚酯特别适用于创建多功能添加剂，可以赋予调理、长效性和/或紫外线保护。描述了单个寡聚酯和寡聚酯混合物。
• Cocondensation polyester, process for manufacturing same and uses thereof
  申请人：MITSUI PETROCHEMICAL INDUSTRIES, LTD.

  公开号：EP0394751A2

  公开（公告）日：1990-10-31

  A cocondensation polyester according to the present invention is substantially linear and is composed of mononuclear aromatic dicarboxylic acid constituent units comprising isophthalic acid constituent units as their main ingredient, (b) binuclear aromatic dicarboxylic acid constituent units comprising 2,6-naphthalenedicarboxylic acid constituent units as their main ingredient, (c) diol constituent units comprising ethylene glycol constituent units as their main ingredient, and (d) polyfunctional constituent units derived from a polyfunctional compound having 3 or more carboxyl groups and/or hydroxyl groups in total and 3 to 15 carbon atoms, said polyester having an intrinsic viscosity [η] of 0.5 to 1.5 dl/g and a glass transition temperature of 70°C or higher. A second cocondensation polyester according to the present invention is substantially linear and is composed of the above-mentioned (a) mononuclear aromatic dicarboxylic acid constituent units, (b) binuclear aromatic dicarboxylic acid constituent units, (c) diol constituent units, (d) polyfunctional constituent units, and additional (e) aliphatic dicarboxylic acid constituent units comprising succinic acid constituent units as their main ingredient, said polyester having an intrinsic viscosity [η] of 0.5 to 1.5 dl/g. Furthermore, the present invention provides a process for preparing these cocondasation polyesters, and uses thereof by utilizing excellent gas barrier properties and transparency thereof.

  根据本发明的缩聚聚酯基本上是线性的，由单核芳香族二羧酸组成单元组成，其主要成分是间苯二甲酸组成单元；(b) 双核芳香族二羧酸组成单元，其主要成分是2,6-萘二甲酸组成单元、(c) 以乙二醇组成单元为主要成分的二元醇组成单元，以及 (d) 由具有 3 个或 3 个以上羧基和/或羟基以及 3 至 15 个碳原子的多官能团化合物衍生的多官能团组成单元，所述聚酯的固有粘度[η]为 0.5至1.5分升/克，玻璃化转变温度为70℃或更高。 根据本发明的第二种缩酮聚酯基本上是线性的，由上述 (a) 单核芳香族二羧酸组成单元，(b) 双核芳香族二羧酸组成单元、(c) 二元醇组成单元，(d) 多官能团组成单元，以及 (e) 以琥珀酸组成单元为主要成分的脂肪族二羧酸组成单元，所述聚酯的固有粘度[η]为 0.5 至 1.5 分升/克。 此外，本发明还提供了一种利用优异的气体阻隔性和透明性制备这些稠化聚酯的工艺及其用途。
• Process for introducing a carboxyl group to an aromatic carboxylic acid or a derivative thereof
  申请人：Hirai, Hidefumi

  公开号：EP0539243A2

  公开（公告）日：1993-04-28

  Disclosed is a process for introducing a carboxyl group to an aromatic carboxylic acid or a derivative thereof, which comprises reacting a starting aromatic carboxylic acid, such as a benzoic acid, a biphenylcarboxylic acid, a naphthalenecarboxylic acid, a diphenylcarboxylic acid, or a derivative thereof, with a carbon tetrahalide in the presence of a cyclodextrin and an alkali metal hydroxide, thereby introducing a carboxyl group to the aromatic ring of the starting aromatic carboxylic acid or the derivative thereof in substitution for a hydrogen atom bonded thereto. By the process of the present invention, a desired aromatic polycarboxylic acid or a derivative thereof can be easily obtained with high selectivity.

  本发明公开了一种向芳香族羧酸或其衍生物引入羧基的工艺，该工艺包括在环糊精和碱金属氢氧化物存在下，使起始芳香族羧酸（如苯甲酸、联苯羧酸、萘羧酸、二苯基羧酸）或其衍生物与四卤化碳反应，从而向起始芳香族羧酸的芳香环引入羧基、或其衍生物，在环糊精和碱金属氢氧化物存在下与四卤化碳反应，从而在起始芳香族羧酸或其衍生物的芳香环上引入一个羧基，以取代与其结合的氢原子。通过本发明的工艺，可以很容易地以高选择性获得所需的芳香族聚羧酸或其衍生物。