3,6,9,12,15-五氮杂十七烷-1,17-二胺 | 4403-32-1

• 分子结构分类: 有机化合物 - 有机氮化合物
• 中文名称: 3,6,9,12,15-五氮杂十七烷-1,17-二胺
• 中文别名: 2-(4-甲基苯基)-1,3-噻唑
• 英文名称: hexaethyleneheptamine
• 英文别名: hexaethyleneheptaamine；pentaethylenehexamine；peha；3,6,9,12,15-Pentaazaheptadecane-1,17-diamine；N'-[2-[2-[2-[2-(2-aminoethylamino)ethylamino]ethylamino]ethylamino]ethyl]ethane-1,2-diamine
• CAS: 4403-32-1
• 化学式: C₁₂H₃₃N₇
• 分子量: 275.441
• InChiKey: AQGNVWRYTKPRMR-UHFFFAOYSA-N

物化性质

• 沸点：
  439.5±40.0 °C(Predicted)
• 密度：
  0.990±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  -3.8
• 重原子数：
  19
• 可旋转键数：
  16
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  112
• 氢给体数：
  7
• 氢受体数：
  7

反应信息

• 作为反应物：
  描述：

  3,6,9,12,15-五氮杂十七烷-1,17-二胺 、 硫脲 反应 2.0h， 生成
  参考文献：
  名称：

  咪唑基硫脲衍生物、缓蚀剂及其制备方法

  摘要：

  本发明公开了一种咪唑基硫脲衍生物、缓蚀剂及其制备方法，属于金属腐蚀防护领域。该咪唑基硫脲衍生物的化学结构式为：其中，R为含有6-20个碳原子的烷基、苯基或者烯基；n为0、1、2、3、4或5。本发明具有上述结构的咪唑基硫脲衍生物能在CH3COOH-H2S-CO2-Cl—的腐蚀环境中，作为抑制金属，尤其是L360碳钢材质金属的腐蚀的活性成分，具有良好的防腐效果。

  公开号：

  CN105418509A
• 作为产物：
  描述：

  5,10,15,20,25-Pentaazanonacosane-1,29-diamine 在 三氟乙酸 作用下， 以 水 为溶剂， 生成 3,6,9,12,15-五氮杂十七烷-1,17-二胺
  参考文献：
  名称：

  用于受控仿生二氧化硅形成的定制合成多胺

  摘要：

  从硅藻中分离出的有机化合物包含具有丙胺主链和可变甲基化水平和链长的长链多胺。这些长链多胺被认为是负责形成分层结构的基于二氧化硅的硅藻细胞壁的重要分子类别之一。在这里，我们描述了一种基于固相肽合成的合成路线，从中可以获得具有不同链长、甲基化模式和亚基的明确定义的长链多胺。定量二氧化硅沉淀实验以及通过扫描和透射电子显微镜获得的沉淀二氧化硅结构的结构信息揭示了二氧化硅沉淀物的数量、大小和形式对多胺分子结构的明显依赖性。此外，阐明了磷酸盐浓度的影响，揭示了二价阴离子对沉淀过程的重要性。我们能够进一步了解长链多胺的沉淀特性，作为其疏水性、质子化状态和磷酸盐浓度的函数，这可能为在环境条件下更好地控制纳米结构二氧化硅的形成铺平道路。

  DOI：

  10.1021/ja9061163

文献信息

• USE OF NITROGEN COMPOUNDS QUATERNISED WITH ALKYLENE OXIDE AND HYDROCARBYL-SUBSTITUTED POLYCARBOXYLIC ACID AS ADDITIVES IN FUELS AND LUBRICANTS
  申请人：BASF SE

  公开号：US20160130514A1

  公开（公告）日：2016-05-12

  The invention relates to the use of quaternized nitrogen compounds as a fuel and lubricant additive or kerosene additive, such as in particular as a detergent additive, for decreasing or preventing deposits in the injection systems of direct-injection diesel engines, in particular in common rail injection systems, for decreasing the fuel consumption of direct-injection diesel engines, in particular of diesel engines having common rail injection systems, and for minimizing the power loss in direct-injection diesel engines, in particular in diesel engines having common rail injection systems; the invention further relates to the use as an additive for petrol, in particular for operation of DISI engines.

  该发明涉及将季铵化氮化合物用作燃料和润滑剂添加剂或煤油添加剂，特别是作为清洁剂添加剂，用于减少或预防直喷柴油发动机的喷射系统中的沉积物，在特定是在共轨喷射系统中，用于降低直喷柴油发动机的燃料消耗，特别是具有共轨喷射系统的柴油发动机，并用于减少直喷柴油发动机的功率损失，特别是在具有共轨喷射系统的柴油发动机中；该发明还涉及将其用作汽油添加剂，特别是用于DISI发动机的运行。
• [EN] MERCAPTO-CONTAINING BISANHYDROHEXITOL DERIVATIVES AND USES THEREOF<br/>[FR] DÉRIVÉS DE BISANHYDROHEXITOL CONTENANT DES GROUPES MERCAPTO ET LEURS UTILISATIONS
  申请人：3M INNOVATIVE PROPERTIES CO

  公开号：WO2013090138A1

  公开（公告）日：2013-06-20

  Bisanhydrohexitol derivatives having terminal mercapto groups are provided. Additionally, curable compositions that include these mercapto-containing bisanhydrohexitol derivatives, cured compositions prepared from the curable compositions, and articles containing the cured compositions are provided. More specifically, the curable compositions are epoxy-based formulations and the mercapto-containing bisanhydrohexitol derivatives function as curing agents for epoxy resins.

  提供具有末端巯基的双脱水己糖醇衍生物。另外，还提供了包含这些含巯基双脱水己糖醇衍生物的可固化组合物、由可固化组合物制备的固化组合物，以及包含固化组合物的物品。更具体地说，这些可固化组合物是基于环氧的配方，而含巯基的双脱水己糖醇衍生物作为环氧树脂的固化剂。
• Cyclopentadiene derivatives as dispersants for lubricating vils and for fuels
  申请人：SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V.

  公开号：EP0613886A1

  公开（公告）日：1994-09-07

  The invention provides compounds of the general formula in which R¹ and R² each represent a hydrogen atom, or together represent a carbon-carbon single bond; each of R⁴ and R⁵ independently represents a hydrogen atom, or a C₁-C₂₀ alkyl or phenyl group, each of which may be optionally substituted; R⁶ represents a hydrogen atom, or a C₁-C₂₀ alkyl or phenyl group, each of which may be optionally substituted and R⁷ represents a group -CH₂-NHR⁸ in which R⁸ represents an optionally substituted alkyl group, or a group -COX wherein X represents an optionally substituted alkoxy group or -NHR⁸ where R⁸ is as defined above; or R⁶ and R⁷ together represent a group where R⁸ is as defined above; x is 1 to 6; and each R³ independently represents an optionally substituted alkyl or alkenyl group or a group of formula or         ―D―Y   (IIIB) wherein m is in the range 0 to 25, n is in the range 1 to 20, each R⁹ independently represents a hydrogen atom or a methyl or ethyl group, D is derived from a saturated or unsaturated hydrocarbon containing from 20 to 500 carbon atoms, and Y represents a group of formula in which R¹, R², R⁴, R⁵ and R⁶ are as defined above; x' is 0 to 5; R3' is as defined for R³ other than a group of formula II, IIIA or IIIB, R7' represents a group R⁷ as defined above or a group -CHO or -COOH, or R⁶ and R7' together represent a group where R⁸ is as defined above, each group R³ containing a total of up to 550 carbon atoms, with the provisos that up to a maximum of 3 R³ groups can each simultaneously contain a total of greater than 40 carbon atoms and that the groups R³ taken together contain a total of greater than 20 carbon atoms; a process for their preparation; novel intermediates; lubricating oil compositions, fuel compositions and additive concentrates containing the formula I compounds; and the use of the formula I compounds as dispersant additives.

  该发明提供了一般式为的化合物 其中R¹和R²分别代表氢原子，或者一起代表碳-碳单键；R⁴和R⁵各自独立地代表氢原子，或者C₁-C₂₀烷基或苯基，每个基团可能被取代；R⁶代表氢原子，或者C₁-C₂₀烷基或苯基，每个基团可能被取代，R⁷代表一个基团-CH₂-NHR⁸，其中R⁸代表一个可选择取代的烷基基团，或一个基团-COX，其中X代表一个可选择取代的烷氧基团或-NHR⁸，其中R⁸如上定义；或者R⁶和R⁷一起代表一个基团 其中R⁸如上定义；x为1至6；每个R³独立地代表一个可选择取代的烷基或烯基基团，或一个式的基团 或 其中m在0至25范围内，n在1至20范围内，每个R⁹独立地代表氢原子或甲基或乙基基团，D来源于含有20至500个碳原子的饱和或不饱和碳氢化合物，Y代表一个式的基团 其中R¹、R²、R⁴、R⁵和R⁶如上定义；x'为0至5；R³'如上定义为R³，但不包括式II、IIIA或IIIB的基团，R⁷'代表一个如上定义的基团R⁷或一个基团-CHO或-COOH，或者R⁶和R⁷'一起代表一个基团 其中R⁸如上定义，每个基团R³包含总共最多550个碳原子，但最多3个R³基团可以同时包含总共大于40个碳原子，且这些R³基团总共包含大于20个碳原子；一种制备它们的方法；新颖的中间体；含有式I化合物的润滑油组合物、燃料组合物和添加剂浓缩物；以及将式I化合物用作分散剂添加剂的用途。
• Additive concentrates containing cyclopentadiene derivatives for lubricating oils and for fuels
  申请人：SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V.

  公开号：EP0613887A1

  公开（公告）日：1994-09-07

  The invention provides an additive concentrate comprising an inert carrier fluid and from 10 to 80%w, based on the total concentrate, of a compound of the general formula in which R¹ and R² each represent a hydrogen atom, or together represent a carbon-carbon single bond; each of R⁴ and R⁵ independently represents a hydrogen atom, or a C₁-C₂₀ alkyl or phenyl group, each of which may be optionally substituted; R⁶ represents a hydrogen atom, or a C₁-C₂₀ alkyl or phenyl group, each of which may be optionally substituted and R⁷ represents a group -CH₂-NHR⁸ in which R⁸ represents an optionally substituted alkyl group, or a group -COX wherein X represents an optionally substituted alkoxy group or -NHR⁸ where R⁸ is as defined above; or R⁶ and R⁷ together represent a group where R⁸ is as defined above; x is 1 to 6; and each R³ independently represents an optionally substituted alkyl or alkenyl group or a group of formula or         ―D―Y   (IIIB) wherein m is in the range 0 to 25, n is in the range 1 to 20, each R⁹ independently represents a hydrogen atom or a methyl or ethyl group, D is derived from a saturated or unsaturated hydrocarbon containing from 20 to 500 carbon atoms, and Y represents a group of formula in which R¹, R², R⁴, R⁵ and R⁶ are as defined above; x' is 0 to 5; R3' is as defined for R³ other than a group of formula II, IIIA or IIIB, R7' represents a group R⁷ as defined above or a group -CHO or -COOH, or R⁶ and R7' together represent a group where R⁸ is as defined above, each group R³ containing a total of up to 550 carbon atoms, with the proviso that up to a maximum of 3 R³ groups can each simultaneously contain a total of greater than 40 carbon atoms; lubricating oil and fuel compositions containing the formula I compounds; and the use of the formula I compounds as dispersant additives.

  该发明提供了一种添加剂浓缩物，包括惰性载体流体和总浓缩物中占10至80%重量的一般式化合物，其中R¹和R²分别代表氢原子，或者一起代表碳-碳单键；R⁴和R⁵各自独立地代表氢原子，或者C₁-C₂₀烷基或苯基，每个基团可能被取代；R⁶代表氢原子，或者C₁-C₂₀烷基或苯基，每个基团可能被取代，R⁷代表一个基团-CH₂-NHR⁸，其中R⁸代表一个可选择取代的烷基基团，或者一个基团-COX，其中X代表一个可选择取代的烷氧基团或-NHR⁸，其中R⁸如上定义；或者R⁶和R⁷一起代表一个基团 其中R⁸如上定义；x为1至6；每个R³独立地代表一个可选择取代的烷基或烯基基团，或者一个式的基团 或 其中m在0至25范围内，n在1至20范围内，每个R⁹独立地代表氢原子或甲基或乙基基团，D来源于含有20至500个碳原子的饱和或不饱和碳氢化合物，Y代表一个式的基团 其中R¹、R²、R⁴、R⁵和R⁶如上定义；x'为0至5；R³'如上定义为R³，但不包括式II、IIIA或IIIB的基团，R⁷'代表一个如上定义的基团R⁷或一个基团-CHO或-COOH，或者R⁶和R⁷'一起代表一个基团 其中R⁸如上定义，每个基团R³包含总共最多550个碳原子，但最多3个R³基团可以同时包含总共大于40个碳原子；含有式I化合物的润滑油和燃料组合物；以及将式I化合物用作分散剂添加剂。
• POLYCATIONIZED PHOSPHOLIPID DERIVATIVES
  申请人：DEWA Takehisa

  公开号：US20100094020A1

  公开（公告）日：2010-04-15

  The present invention provides novel phospholipid derivatives. Furthermore, the present invention provides lipid membrane structures excellent in gene/nucleic acid introduction efficiency into a cell.

  本发明提供了新颖的磷脂衍生物。此外，本发明提供了在细胞内具有出色的基因/核酸引入效率的脂质膜结构。