1-[[3,5-Bis(phenylmethoxy)phenyl]methoxymethyl]-2-methoxynaphthalene | 862806-04-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: 1-[[3,5-Bis(phenylmethoxy)phenyl]methoxymethyl]-2-methoxynaphthalene
• CAS: 862806-04-0
• 化学式: C₃₃H₃₀O₄
• 分子量: 490.599
• InChiKey: KWPLWTLZAXPOLC-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7.2
• 重原子数：
  37
• 可旋转键数：
  11
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.15
• 拓扑面积：
  36.9
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  1-[[3,5-Bis(phenylmethoxy)phenyl]methoxymethyl]-2-methoxynaphthalene 以 苯 为溶剂， 以100%的产率得到
  参考文献：
  名称：

  Photochemical generation of benzene–naphthalene biplanemers

  摘要：

  A direct biplanemer synthesis could be achieved by a quantitative [4 pi+4 pi]photocycloaddition of benzyloxy substituted benzene and naphthalene rings (3d,e reversible arrow 4d,e). Since the products do not show a thermal Cope rearrangernent-in contrast to the related longicyclic conjugated 9,10-benzotricyclo[4.2. 2.2(2.5)]docleca-3,7,9-trienes- but a quantitative reverse reaction, they are interesting systems for an optical switching. (c) 2005 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2005.05.092
• 作为产物：
  描述：

  以100%的产率得到1-[[3,5-Bis(phenylmethoxy)phenyl]methoxymethyl]-2-methoxynaphthalene
  参考文献：
  名称：

  Photochemical generation of benzene–naphthalene biplanemers

  摘要：

  A direct biplanemer synthesis could be achieved by a quantitative [4 pi+4 pi]photocycloaddition of benzyloxy substituted benzene and naphthalene rings (3d,e reversible arrow 4d,e). Since the products do not show a thermal Cope rearrangernent-in contrast to the related longicyclic conjugated 9,10-benzotricyclo[4.2. 2.2(2.5)]docleca-3,7,9-trienes- but a quantitative reverse reaction, they are interesting systems for an optical switching. (c) 2005 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2005.05.092

文献信息

• Synthesis of Dendritic Phenol Ether Derivatives with a Naphthalene Core
  作者：Zhonghua Xiang、Derong Cao

  DOI：10.1080/00397910801913980

  日期：2008.4

  Abstract A series of dendritic phenol ether derivatives with a naphthalene core were synthesized by the Williamson reaction as a coupling reaction between 1‐hydroxymethylnaphthalene and polyether‐based dendritic fragments in the presence of phase‐transfer catalyst and alkali. The modified method for chlorination of dendritic benzyl alcohol was also developed using PPh3 and CCl4 as reagents and CH2Cl2/CCl4

  摘要 在相转移催化剂和碱的存在下，1-羟甲基萘与聚醚类树枝状碎片通过威廉姆森反应合成了一系列具有萘核的树枝状苯酚醚衍生物。还以PPh3和CCl4为试剂，CH2Cl2/CCl4为溶剂开发了树枝状苯甲醇氯化的改进方法。
• Photochemical generation of benzene–naphthalene biplanemers
  作者：Derong Cao、Herbert Meier

  DOI：10.1016/j.tetlet.2005.05.092

  日期：2005.7

  A direct biplanemer synthesis could be achieved by a quantitative [4 pi+4 pi]photocycloaddition of benzyloxy substituted benzene and naphthalene rings (3d,e reversible arrow 4d,e). Since the products do not show a thermal Cope rearrangernent-in contrast to the related longicyclic conjugated 9,10-benzotricyclo[4.2. 2.2(2.5)]docleca-3,7,9-trienes- but a quantitative reverse reaction, they are interesting systems for an optical switching. (c) 2005 Elsevier Ltd. All rights reserved.