dimethyltin(IV) bis(N,N'-dimethyldithiocarbamate) | 22845-86-9

• 分子结构分类: 有机化合物 - 有机金属化合物 - 有机过渡后金属化合物
• 英文名称: dimethyltin(IV) bis(N,N'-dimethyldithiocarbamate)
• 英文别名: N,N-dimethylcarbamodithioate;dimethyltin(2+)
• CAS: 22845-86-9
• 化学式: C₈H₁₈N₂S₄Sn
• 分子量: 389.218
• InChiKey: DMMPPVFCPOJUJY-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  2.85
• 重原子数：
  15
• 可旋转键数：
  4
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.75
• 拓扑面积：
  121
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  dimethyltin(IV) bis(N,N'-dimethylthioselenocarbamate) 、 dimethyltin(IV) bis(N,N'-dimethyldithiocarbamate) 以 苯 为溶剂， 以70%的产率得到dimethyltin(IV) (N,N'-dimethyldithiocarbamate)(N,N'-dimethylthioselenocarbamate)
  参考文献：
  名称：

  Synthesis of mixed carbamate complexes of dimethyltin(IV) and their properties in solution

  摘要：

  DOI：

  10.1016/s0020-1693(00)91699-2
• 作为产物：
  描述：

  4,4-dimethyl-2-(2-thienyl)oxazoline 、 Me2SnCl(N,N'-dimethyldithiocarbamate) 在 n-BuLi 作用下， 以 乙醚 、 正己烷 为溶剂， 生成 bis{2-(4,4-dimethyl-2-oxazolinyl)-3-thienyl}dimethyltin 、 {2-(4,4-dimethyl-2-oxazolinyl)-3-thienyl}dimethyltin N,N-dimethyldithiocarbamate 、 dimethyltin(IV) bis(N,N'-dimethyldithiocarbamate)
  参考文献：
  名称：

  Synthesis and spectroscopic studies of thienyl triorganotin(IV) compounds. Crystal structures of [2-(4,4-dimethyl-2-oxazolinyl)-3-thienyl]dimethyltin N,N-dimethyldithiocarbamate and [2-(4,4-dimethyl-2-oxazolinyl)-3-thienyl]diphenyltin chloride

  摘要：

  Two series of stannylated thiophenes of formula (Z-C4H2S)SnR2X (Z = 3-(2-pyridyl) and 2-(4,4-dimethyl-2-oxazolinyl); R = Me, (n)Bu, Ph, p-tolyl and (c)Hex; X = Cl, Br, I, OH, SC(S)NMe2 and 8-quinolinolyl) have been prepared and their structures established by Sn-119m Mossbauer and NMR (C-13 and Sn-119) spectral analyses. A pronounced C,N-chelate bonding mode is inferred for the 3-(2-pyridyl)-2-thienyl ligand in the first series, the tin atoms thus being essentially five-coordinate with trans-C3SnNX trigonal bipyramidal geometries. Crystal structure determinations on two products in the second series, namely [2-(4,4-dimethyl-2-oxazolinyl)-3-thienyl]dimethyltin N,N-dimethyldithiocarbamate (1) and [2-(4,4-dimethyl-2-oxazolinyl)-3-thienyl]diphenyltin chloride (2), confirmed the spectroscopic indications of pentacoordinate trigonal bipyramidal tin environments and revealed that the oxazolinyl nitrogen is the intramolecularly coordinated donor atom in each case and is located in an apical position with respect to the C3Sn trigonal girdle; the Sn-N bond length in 2 (2.580(8); 2.525(7) angstrom) is relatively shorter than in 1 (2.720(3) angstrom). The apical angle for 1 (162.12(7)-degrees) shows the molecule to be more distorted than 2 (168.4(2) and 169.9(2)-degrees).

  DOI：

  10.1016/0022-328x(92)86003-m

文献信息

• Synthesis and spectroscopic studies of thienyl triorganotin(IV) compounds. Crystal structures of [2-(4,4-dimethyl-2-oxazolinyl)-3-thienyl]dimethyltin N,N-dimethyldithiocarbamate and [2-(4,4-dimethyl-2-oxazolinyl)-3-thienyl]diphenyltin chloride
  作者：Kong Mun Lo、S. Selvaratnam、Seik Weng Ng、Chen Wei、V.G. Kumar Das

  DOI：10.1016/0022-328x(92)86003-m

  日期：1992.6

  Two series of stannylated thiophenes of formula (Z-C4H2S)SnR2X (Z = 3-(2-pyridyl) and 2-(4,4-dimethyl-2-oxazolinyl); R = Me, (n)Bu, Ph, p-tolyl and (c)Hex; X = Cl, Br, I, OH, SC(S)NMe2 and 8-quinolinolyl) have been prepared and their structures established by Sn-119m Mossbauer and NMR (C-13 and Sn-119) spectral analyses. A pronounced C,N-chelate bonding mode is inferred for the 3-(2-pyridyl)-2-thienyl ligand in the first series, the tin atoms thus being essentially five-coordinate with trans-C3SnNX trigonal bipyramidal geometries. Crystal structure determinations on two products in the second series, namely [2-(4,4-dimethyl-2-oxazolinyl)-3-thienyl]dimethyltin N,N-dimethyldithiocarbamate (1) and [2-(4,4-dimethyl-2-oxazolinyl)-3-thienyl]diphenyltin chloride (2), confirmed the spectroscopic indications of pentacoordinate trigonal bipyramidal tin environments and revealed that the oxazolinyl nitrogen is the intramolecularly coordinated donor atom in each case and is located in an apical position with respect to the C3Sn trigonal girdle; the Sn-N bond length in 2 (2.580(8); 2.525(7) angstrom) is relatively shorter than in 1 (2.720(3) angstrom). The apical angle for 1 (162.12(7)-degrees) shows the molecule to be more distorted than 2 (168.4(2) and 169.9(2)-degrees).
• Synthesis of mixed carbamate complexes of dimethyltin(IV) and their properties in solution
  作者：Koji Tanaka、Shigeo Araki、T. Tanaka

  DOI：10.1016/s0020-1693(00)91699-2

  日期：1976.1