3-methoxyphenyl naphthalene-2-carboxylate | 1338458-30-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: 3-methoxyphenyl naphthalene-2-carboxylate
• 英文别名: (3-Methoxyphenyl) naphthalene-2-carboxylate
• CAS: 1338458-30-2
• 化学式: C₁₈H₁₄O₃
• 分子量: 278.307
• InChiKey: MUEMDWQICHEIPB-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.1
• 重原子数：
  21
• 可旋转键数：
  4
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.06
• 拓扑面积：
  35.5
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  苯并恶唑 、 3-methoxyphenyl naphthalene-2-carboxylate 在 bis(1,5-cyclooctadiene)nickel (0) 、 potassium phosphate 、 1,2-双(二环己基磷基)-乙烷 作用下， 以 1,4-二氧六环 为溶剂， 反应 24.0h， 以91%的产率得到2-萘-2-基-1,3-苯并恶唑
  参考文献：
  名称：

  Decarbonylative C–H Coupling of Azoles and Aryl Esters: Unprecedented Nickel Catalysis and Application to the Synthesis of Muscoride A

  摘要：

  A nickel-catalyzed decarbonylative C-H biaryl coupling of azoles and aryl esters is described. The newly developed catalytic system does not require the use of expensive metal catalysts or silver- or copper-based stoichiometric oxidants. We have successfully applied this new C-H arylation reaction to a convergent formal synthesis of muscoride A.

  DOI：

  10.1021/ja306062c
• 作为产物：
  描述：

  3-甲氧基苯酚 、 2-溴萘 、 molybdenum hexacarbonyl 在 三正丁胺 作用下， 以 二乙二醇二甲醚 为溶剂， 反应 12.0h， 以82%的产率得到3-methoxyphenyl naphthalene-2-carboxylate
  参考文献：
  名称：

  六羰基钼介导的芳基卤化物的烷氧羰基化

  摘要：

  Mo（CO）6-在芳基卤化物与醇的反应中介导芳基卤化物的烷氧基羰基化，提供芳烃羧酸酯。羰基钼配合物充当一氧化碳的催化剂和来源。烷氧基羰基化反应以少量过量的Mo（CO）6形式的一氧化碳进行，与常规方法相比，该方法比较简单，该常规方法在气态一氧化碳下使用钯催化剂。使用该程序，制备了各种羧酸酯。 钼-羰基配合物-羰基化-酯化-酰化

  DOI：

  10.1055/s-0030-1260060

文献信息

• Multilayered articles and method of manufacture thereof
  申请人：SABIC Global Technologies B.V.

  公开号：EP1724110B1

  公开（公告）日：2019-08-21
• Polycarbonate compositions having infrared absorbance, method of manufacture, and articles prepared therefrom
  申请人：van den Bogerd A. Jos

  公开号：US20070015081A1

  公开（公告）日：2007-01-18

  A composition is disclosed, comprising a polycarbonate resin, an inorganic infrared shielding additive, and carbon black, wherein an article prepared from the composition has the inorganic infrared shielding additive present at about 0.01 to about 1.0 grams per square meter, and carbon black present at about 0.001 to about 2.0 grams per square meter. The article prepared from the composition meets at least one scale requirement for European Norm EN 169 and/or EN 171, and is useful for preparing infrared shielding protective eyewear with low haze.
• Formable Sheets for Medical Applications and Methods of Manufacture Thereof
  申请人：Tadros Safwat

  公开号：US20070148608A1

  公开（公告）日：2007-06-28

  Disclosed herein is an appliance for use in an oral cavity, wherein the appliance comprises a polymeric shell that comprises a polymeric mixture, and further wherein the polymeric shell has cavities designed to receive teeth. Disclosed herein too is a method for maintaining or repositioning teeth in the oral cavity comprising placing an appliance in a patient's mouth, wherein the appliance comprises a polymeric shell that comprises a polymeric mixture, and further wherein the polymeric shell has cavities designed to receive teeth.
• FLAME RETARDANT POLYCARBONATE COMPOSITIONS HAVING GOOD TRANSPARENCY AND LOW HAZE, METHOD OF MANUFACTURE, AND ARTICLES PREPARED THEREFROM
  申请人：Faber Mollerus Rein

  公开号：US20070225416A1

  公开（公告）日：2007-09-27

  A composition is disclosed, comprising a polycarbonate resin and a flame retardant additive comprising a lithium salt, wherein an article prepared from the composition has a haze value less than about 1% as measured at a thickness of about 5.0 mm according to ASTM D1003 and wherein the composition is substantially chlorine and bromine free.
• US7210926B2
  申请人：——

  公开号：US7210926B2

  公开（公告）日：2007-05-01