3-methacryloyloxypropyl phosphonic acid | 252210-30-3

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 有机膦酸及其衍生物
• 英文名称: 3-methacryloyloxypropyl phosphonic acid
• 英文别名: 3-(2-methylprop-2-enoyloxy)propylphosphonic acid
• CAS: 252210-30-3
• 化学式: C₇H₁₃O₅P
• 分子量: 208.151
• InChiKey: KYEAMYHCEZEPOJ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.2
• 重原子数：
  13
• 可旋转键数：
  6
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.57
• 拓扑面积：
  83.8
• 氢给体数：
  2
• 氢受体数：
  5

反应信息

• 作为产物：
  描述：

  (trimethylsilyl) 3-methacryloyloxypropylphosphonate 以 甲醇 为溶剂， 反应 2.0h， 以to give 3-methacryloyloxypropyl phosphonic acid as a highly viscous, colorless oil (19.9 g; yield 99%)的产率得到3-methacryloyloxypropyl phosphonic acid
  参考文献：
  名称：

  (Meth)acrylate phosphonic esters as adhesion promoters

  摘要：

  本发明涉及表面组成物，其包括：a) 至少一种（甲基）丙烯酸酯预聚物，b) 公式（I）中定义的促进粘附单体，其中Q，R1，R2，R4，R5，m和n在此定义。此外，该组成物可用于提高对表面的粘附性，特别是对金属表面，并可包括其他可选组分，如促进粘附光引发剂。

  公开号：

  US08372516B2

文献信息

• HAIR TREATMENT PRODUCTS COMPRISING POLYMERS
  申请人：Schulze zur Wiesche Erik

  公开号：US20090304620A1

  公开（公告）日：2009-12-10

  The invention relates to hair treatment products, comprising at least one copolymer made of 0.1 to 50% (in relation to the total number of monomers in the copolymer) monomers of the formula (I), wherein the unknowns are defined as in claim 1 , and A2) are monomers from the group of acrylic acid, methacrylic acid and the like, and—optionally non-ionic monomers from the group of acrylamide, vinyl alcohol, and the like, wherein the monomers A2 and A3 together represent 50 to 99.9% (in relation to the total number of monomers in the copolymer) of the copolymer, at least one silicon and at least one selected care product, wherein the products result in advantageous effects for skin and hair.

  该发明涉及头发护理产品，包括至少一种由0.1至50%（相对于共聚物中单体总数的比例）的公式（I）的单体制成的共聚物，其中未知数的定义如权利要求1中定义的，以及A2）是来自丙烯酸、甲基丙烯酸等单体组的单体，以及——可选的非离子单体，来自丙烯酰胺、乙烯醇等单体组，其中单体A2和A3共同代表共聚物中50至99.9%（相对于共聚物中单体总数的比例）的单体，至少含有一种硅和至少一种选定的护理产品，其中这些产品对皮肤和头发具有有利效果。
• [EN] MONOMER COMPOUND COMPRISING SEVERAL CATIONIC GROUPS, PROCESS FOR MAKING THE SAME, AND POLYMERS COMPRISING UNITS DERIVING THEREFROM<br/>[FR] COMPOSE MONOMERE COMPRENANT PLUSIEURS GROUPES CATIONIQUES, SON PROCEDE DE FABRICATION, ET POLYMERES COMPRENANT DES UNITES QUI EN DERIVENT
  申请人：RHODIA

  公开号：WO2003101935A1

  公开（公告）日：2003-12-11

  Monomer compounds comprising several cationic groups are provided. The invention also relates to a process for making these monomer compounds. The process is highly selective and prevents unwanted reactions leading to undesired structures. The invention relates also to polymers, including copolymers, comprising units deriving from said monomer compounds. The monomer compounds comprise several cationic groups, e.g. those having the following formula (I): wherein - R1 is a hydrogen atom, a methyl group or an ethyl group, - A, which is identical or different, is a group comprising an ester group of formula -A1-C(O)-O-A2-, or an amide group of formula -A1-C(O)-NR10-A2-, wherein: - R10, which is identical or different, is hydrogen or an alkyl, hydroxyalkyl, or aminoalkyl C1-C6 linear or branched group - A1, which is identical or different is a covalent bond or a group of formula -(CH2)P1- wherein p1 is an integer of from 1 to 6, preferably 1, - A2, which is identical or different, is a linear or branched hydrocabron group comprising optionally N, O, or S hereroatomes or heterogroups, optionally substituted, optionally forming or comprising a cycle, such as a heterocycle, A2 preferably being a group of formula -(CH2)p2- wherein p2 is an integer of from 1 to 6, - R1, R2, R3, R5 and R6, which are identical or different, are hydrogen, alkyl, hydroxyalkyl, or aminoalkyl C1-C6 linear or branched groups, or, if inside the brackets, form a heterocycle with group A2, - m is an integer of from 1 to 10, preferably of from 1 to 2, - n is an integer of from 1 to 6, preferably 2 or 4, Z is -O-, -C(O)O, or -C(O)NH-, B is linear or branched C2-C12 polymethylene chain, preferably a C3-C6 one, optionally comprising heteroatoms or heterogroups, such as O or NH, and optionally substituted with one or several hydroxy or amino groups, and -X-, which are identical or different, are counter ions.

  提供了包含多个阳离子基团的单体化合物。该发明还涉及制备这些单体化合物的方法。该方法高度选择性，并防止导致不希望的结构的非预期反应。该发明还涉及包含从上述单体化合物衍生的单元的聚合物，包括共聚物。单体化合物包括多个阳离子基团，例如具有以下式(I)的基团：其中-R1是氢原子，甲基基团或乙基基团，-A，相同或不同，是包含式-A1-C(O)-O-A2-的酯基团，或包含式-A1-C(O)-NR10-A2-的酰胺基团，其中：-R10，相同或不同，是氢或烷基、羟基烷基或氨基烷基C1-C6直链或支链基团，-A1，相同或不同，是共价键或式-(CH2)P1-的基团，其中p1是1到6之间的整数，优选为1，-A2，相同或不同，是线性或支链的烃基团，包括可选的N、O或S杂原子或杂基团，可选地取代，可选地形成或包含环，例如杂环，A2优选为式-(CH2)p2-的基团，其中p2是1到6之间的整数，-R1、R2、R3、R5和R6，相同或不同，是氢、烷基、羟基烷基或氨基烷基C1-C6直链或支链基团，或者如果在括号内，则与基团A2形成杂环，-m是1到10之间的整数，优选为1到2之间的整数，-n是1到6之间的整数，优选为2或4，Z是-O-、-C(O)O或-C(O)NH-，B是线性或支链的C2-C12聚亚甲基链，优选为C3-C6链，可选地包含杂原子或杂基团，如O或NH，并可选地取代为一个或多个羟基或氨基基团，-X-，相同或不同，是对离子。
• (METH)ACRYLATE PHOSPHONIC ESTERS AS ADHESION PROMOTERS
  申请人：Craciun Liliana

  公开号：US20100112362A1

  公开（公告）日：2010-05-06

  The invention is directed to compositions on a surface which comprise a) at least a (meth)acrylate prepolymer, b) an adhesion promoting monomer of formula (I) wherein Q, R 1 , R 2 , R 4 , R 5 , m and n are defined herein. Further the compositions may be used to improve the adhesion to surfaces, especially metallic surfaces and may include additional optional components such as adhesion promoting photoinitiators.

  本发明涉及一种表面组合物，其包括a) 至少一种（甲基）丙烯酸酯预聚物，b) 公式（I）中定义的增粘促进单体，其中Q、R1、R2、R4、R5、m和n在此被定义。此外，该组合物可用于提高对表面的附着力，特别是金属表面，并可包括其他可选组分，如增粘促进光引发剂。
• Immunoassay elements comprising polymers containing vanadium IV (V (+4)) ions
  申请人：Johnson & Johnson Clinical Diagnostics, Inc.

  公开号：EP0684473A2

  公开（公告）日：1995-11-29

  A dry immunoassay analytical element, for assaying a ligand, comprising in the following order: (a) a layer containing a labeled ligand; (b) a spreading layer ; (c) a receptor layer containing a fixed concentration of an immobilized receptor for the labeled ligand and the receptor is i) covalently bonded to polymeric beads having a diameter in the range of 0.1 to 5 µm and ii) dispersed in a polymeric binder and (d) a support; characterized in that the spreading layer contains a water soluble polymer containing vanadium IV (V+4) ions.

  一种干式免疫测定分析元件，用于测定配体，按以下顺序组成： (a) 含有标记配体的层； (b) 铺展层 (c) 受体层，含有固定浓度的标记配体固定受体，受体 i) 共价键合在聚合珠上，聚合珠直径在 0.1 至 5 微米之间，ii) 分散在聚合粘合剂中；以及 (d) 支持物； 其特征在于，铺展层含有含有钒 IV（V+4）离子的水溶性聚合物。
• FRICTION REGULATOR FOR LUBRICATING OIL AND LUBRICATING OIL COMPOSITION
  申请人：SANYO CHEMICAL INDUSTRIES, LTD.

  公开号：EP1489158A1

  公开（公告）日：2004-12-22

  The present invention provides    a friction modifier for a lubricating oil which comprises an oil-soluble copolymer (A) containing at least one unit of a monomer (a) represented by the general formula (1) and at least one unit of a monomer (b) represented by the general formula (2), and having a weight average molecular weight of 3,000 or more;         CH2=C(R1)-Q-(Z-A1)m-X     (1)         CH2=C(R3)-CO-(O-A2)n-OR4     (2)    a friction modifier composition comprising the above copolymer (A), and at least one species selected from the group consisting of a diluent and other additives; a lubricating oil composition comprising base oil, and the above friction modifier or friction modifier composition. These are excellent in the friction regulation effect, capable of reducing transmission shock, are high in the friction coefficient required for power transmission, and in addition, are excellent in wear resistance.

  本发明提供 一种用于润滑油的摩擦改进剂，它包含一种油溶性共聚物 (A)，该共聚物含有至少一个由通式 (1) 表示的单体 (a) 单元和至少一个由通式 (2) 表示的单体 (b) 单元，且其重量平均分子量大于等于 3,000； CH2=C(R1)-Q-(Z-A1)m-X (1) CH2=C(R3)-CO-(O-A2)n-OR4 (2) 摩擦改进剂组合物，包括上述共聚物（A）和至少一种从稀释剂和其他添加剂组成的组中选出的物质； 润滑油组合物，包括基础油和上述摩擦改进剂或摩擦改进剂组合物。这些产品具有出色的摩擦调节效果，能够减少传动冲击，具有较高的动力传输所需的摩擦系数，此外还具有出色的耐磨性。